Synthesis and pesticidal activity of new N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines

A series of novel N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines were synthesized as potential new agents to control pests. Their structures were confirmed on the basis of IR, NMR and elemental analyses. Six new N-alkyl-N-[1-(2-hydroxyphenyl) ethyl]amines were prepared by reduction of corresponding Schiff bases using sodium borohydride in 80–87 % yields. These compounds were tested for their antifungal activity against two pathogenic fungi viz., Rhizoctonia bataticola ITCC 0482 and Sclerotium rolfsii ITCC 5226 and for insecticidal activity against insects of stored grain pest Callosobruchus analis. Fungicidal bioassay revealed that compound N-Decyl-N-[1-(2-hydroxyphenyl)ethyl]amine, was highly effective against R. bataticola (ED₅₀ 6.86 mg L^?1) which was comparable with that of commercial fungicide hexaconazole (ED₅₀ 6.35 mg L^?1). Also compounds N-Heptyl-N-[1-(2-hydroxyphenyl)ethyl]amine, N-Octyl-N-[1-(2-hydroxyphenyl)ethyl]amine and N-Nonyl-N-[1-(2-hydroxyphenyl)ethyl]amine displayed promising fungitoxicity against same pathogen. However, compound N-Heptyl-N-[1-(2-hydroxyphenyl)ethyl]amine was also found to be effective against S. rolfsii (ED₅₀ 4.92 mg L^?1 as against 1.27 mg L^?1 for hexaconazole). Compound N-Hexyl-N-[1-(2-hydroxyphenyl)ethyl]amine was most effective as insecticide followed by compound N-Octyl-N-[1-(2-hydroxyphenyl)ethyl]amine. LC₅₀ values for these compounds were 155.0 and 275.0 mg L^?1 respectively as against 36.70 mg L^?1 for commercial insecticide dichlorovos. The results obtained from bioassays indicate that this class of compounds can be utilized for the design of new substances endowed with pesticidal activities.     

航空装备研制风险的综合赋权-双基点法评估

为实现对航空预研项目技术风险的定量评估,建立技术风险评价指标体系,建立基于综合赋权和双基点方法的综合评估模型,采用层次分析法(AHP)求得主观权重,熵值赋权法求得客观权重,运用线性规划方法求得对2类权重加权的权值,构造综合权重;使用正负理想点间的投影距离代替传统的相对欧式距离对TOPSIS方法进行改进;实例分析中,通过对某航空预研项目5种不同的方案进行风险评估,得出各方案的优劣度,选出了较为优化的技术方案,该方法可用于指导其他装备研制风险的评估。     

废旧混凝土用作水泥稳定基层的实验研究

随着城市建设的发展,城市道路改建时产生的大量的废弃混凝土块的有效利用成了一个亟待解决的问题。结合宜昌市东山大道改建项目,将废弃的混凝土面板加工形成再生集料用作水泥稳定碎石基层,达到节约资源和保护环境的目的。实验分析了再生集料的颗粒级配、压碎值、针片状颗粒含量、表观密度和吸水率等工程性质指标,同时对水泥稳定再生碎石的级配、最佳水泥掺量进行了设计,并对水泥稳定再生碎石的无侧限抗压强度指标进行了研究。研究表明,废旧混凝土经加工形成的再生集料具有良好的路用性能,其颗粒级配、压碎值以及主要指标均达到了路面基层材料的要求;掺3%、5%和7%水泥稳定再生集料7 d浸水抗压强度均达到路面基层的要求,水泥稳定再生集料用作路面基层是可行的;掺3%水泥稳定的再生集料可以用在公路的底基层,掺5%及7%水泥稳定的再生集料可以分别用作路面下基层和上基层。     

基于离线采集模式的高低温低气压试验箱校准技术的研究

针对高低温低气压箱校准技术展开研究,分析了传统校准方案的不足之处,提出了一种基于离线采集模式的高低温低气压试验箱温度、压力校准方案,并结合虚拟仪器、数据库与MATLAB,完成了该方案的设计与实现。最后通过实验验证了该方案的可靠性与可行性,并应用到环境与可靠性工作中。     

Review on the study of mercury/silver ions-pyrimidine base pairs in DNA duplexes and their application in detection technology北大核心CSCD

Nucleic acids and their analogues are getting more and more attention. Metal-mediated base pairs as a kind of simple and functionalized nucleic acids in special positions have widened the scope of application of functional nucleic acids and their analogues. In this type of base pairs, the representative is the interaction between metal ions and pyrimidine bases, especially the research on thymine-Hg2+-thymine (T-Hg2+-T) and cytosine-Ag+-cytosine (C-Ag+-C) base pairs. This review summarizes the structure and mechanism of metal-mediate pyrimidine base pairs as well as the application in the biochemical analysis. It explores the mode and ratio of coordination between metal ions and base pairs, the effects on the stability of DNA helical structure, the related crystal structure and the three-dimensional configuration information in the DNA helix. The analytical application mainly includes various probes of metal ions, small molecules, protein and the detection of single nucleotide polymorphism. Among them the most widely used metal ions detection, and its combination with spectrum technology, visualization and amplification technology greatly promoted the rapid development of sensitive detection technology. In further studies, it is necessary to reveal the mechanism of interaction between T-Hg2+-T and C-Ag+-C, and more attention should be paid to combining of T-Hg2+-T and C-Ag+-C base pairs with other new technologies. The scope of practical application should also be further extended.     

杭州市典型共站移动通信基站周围电磁环境影响调查与研究

在4G基站快速增加的背景下,基站共站已成为较为普遍的架设方式.根据移动通信基站的发展趋势和工作原理,选取典型共站的移动通信基站,按照测量规范进行布点,了解基站周围电场强度的大小、楼顶架设基站的建筑物内部电场强度,以及周围建筑物室内的电场强度垂直方向的变化规律.分析结果表明,只要基站选址合理,天线面板角度与高度能尽量避开周围环境保护目标的方向,共站的基站运营时周围环境的电磁辐射水平可以满足相应的评价标准,不会对周围的环境造成明显的影响.     

“城市矿产”示范基地——我国再生资源产业化的发展方向

以前三批29个国家＂城市矿产＂示范基地为研究对象,对示范基地的回收利用规模、重点项目覆盖范围、示范基地类型做了概括性梳理,总结了示范基地建设的成功经验,分析了妨碍示范基地健康发展的问题,并提出一些预测性意见,供行业同仁参考。     

温州红壤的酸沉降临界负荷研究

本文简要介绍了以碱总量守恒为基础建立的兼能描述钙质与非钙质土壤长期酸化过程的动态模型（ＬＴＳＡＭ），并利用该模型讨论了温州红壤的酸沉降临界负荷。结果表明，以硫沉降即酸沉降的硫沉降非酸沉降两观点分别来确定红壤的临界负荷，其值依次为３．９１与１．８４ｇ·ｍ＾－２·ａ＾－１，后者仅是前者的４７％，差异显著应加以区别。     

寿王坟铜矿通风阻力测定与安全性分析

矿井通风阻力测定是通风技术管理工作的重要内容之一，掌握矿井通风系统阻力的分布情况对矿井通风日常安全管理十分重要。本文介绍了几种通风阻力的测定方法，根据寿王坟铜矿的实际情况选用基点法对其进行了通风阻力测定，计算通风阻力测定数据并运用最小二乘法进行平差处理，使校正后的结果满足克希荷夫第一、第二平衡定律，为今后进行通风系统改造，提供了有参考价值的基础数据资料。最后依据测定结果对寿王坟铜矿通风系统安全性进行了分析。     

武进区花卉苗木基地产业生态化建设方案研究

苏南地区的快速城市化在带动地方经济大发展的同时，却给农村环境造成了巨大的压力，如何实现农村环境与经济协调发展是亟待研究的任务。江苏省常州市武进区花卉苗木基地的实践表明，对区域做出科学的生态经济区划，在严格保护基本农田的基础上，充分利用其它类型的土地资源因地制宜地发展花卉苗木生态产业，成为农村生态环境建设的优化途径之一。武进花木基地环境建设包括：(1)优化生态经济区划，将整个基地划分为平原水网和漏湖圩田两个生态经济区；(2)根据各生态经济区的不同特点采取相应的生态产业布局和实施方案；(3)发展具有“水乡、花卉、休闲”特色的生态旅游产业。