三甲基氯硅烷水解物测定方法的对比分析

三甲基氯硅烷(trimethl chlorosiane)极易水解,水解产物主要是三甲基硅醇和六甲基二硅氧烷以及少量硅氧烷聚合物.本文将探讨液液萃取、静态项空、吹扫捕集三种方法对三甲基氯硅烷水解产物的测定.     

Phytoplankton production modelling in three marine ecosystems—static versus dynamic approach

Phytoplankton productivity is usually determined from water samples incubated at a number of irradiance levels during several hours. The resultant productivity-irradiance (P–E) curves are then used to estimate local and/or global phytoplankton production. However, there is growing evidence that these curves, referred as static, underestimate phytoplankton photosynthesis to a great deal, by assuming a stable response to light over the incubation period. One of the drawbacks of static P–E curves is the overestimation of photoinhibition.In this work, three one-dimensional vertically resolved models were developed as simply as possible, to investigate differences between static and dynamic phytoplankton productivity in three marine ecosystems: a turbid estuary, a coastal area and an open ocean ecosystem. The results show that, when photoinhibition development time is considered (dynamic model), the primary production estimates are always higher than when calculated with the static model. The quantitative importance of these differences varies with the type of ecosystem and it appears to be more important in coastal areas and estuaries (from 21 to 72%) than in oceanic waters (10%). Thus, these results suggest that primary production estimates, obtained under the assumption of a static behaviour response to light, may underestimate the real values of global phytoplankton primary production. Calculations suggest that the quantitative importance of this underestimation may be larger than the global missing carbon sink.     

Evaluation of the explosibility of malt grain dust based on static electrification during pneumatic transportation

The possibility of dust explosions by static electricity in a malt grain silo was investigated. Two kinds of experimental equipment were applied. One was to supply electrostatic charge in order to investigate the charge build up characteristics. The other was to transport the malt grain pneumatically in order to investigate the frictional charge accumulation in the transportation system.

The particle charge of the pulverized malt grain was in the order of 10⁻¹⁴ C. The particle charge of the malt grain was in the order of 10⁻⁹ C and the pipe charge in the transport system was also in the order of 10⁻⁹ C. The charge accumulated on both the pulverized particle and the grain particle were small in view of the incendiary potentiality. However, attention must be paid when the particles are dumped into isolated space. There might be a charge accumulation that will lead to the ignition of the dust cloud.     

Selecting the Best Compatible SVC Type in Power Systems for transient Stability

Considering the increased trend to use renewable energy to meet electrical energy demands, a reliable performance also should be adopted in transmitting the generated power through the stable transmission and subtransmission systems for which nowadays Flexible AC Transmission System (FACTS) controllers are used extensively. Transient stability is one of the most important issues in power system stability analysis. FACTS devices have confirmed their capabilities in various aspects in power networks. In this paper, to improve transient stability of power systems, a shunt connected FACTS devices have been introduced, i.e., Static VAR compensators (SVCs). The SVC has the most diversified branches among FACTS devices. The main aim of this work is to study and analyze the impact of eight branches of SVC on improvement of transient stability and to choose the best of them. Simulations are performed in MATLAB/SIMULINK environment.     

Monitoring and modelling of siloxanes in a sewage treatment plant in the UK

Monitoring of cyclic volatile methylsiloxanes (cVMS) carried out at Anglian Water’s Broadholme sewage treatment plant (STP) is described. The method deployed used headspace gas chromatography/mass spectrometry (HS-GC/MS) and the addition of isotopically labelled cVMS to correct for partitioning in samples containing high levels of particulate and dissolved organic carbon. The method was capable of measuring cVMS in raw sewage samples, with recoveries of 80%, 85% and 71% respectively, for D₄, D₅ and D₆. The limit of quantification was 0.2 μg L⁻¹ for all three substances. Recoveries close to 100% were observed for all cVMS spiked into treated effluent (LOQ = 0.01 μg L⁻¹). Despite the volatile nature of cVMS and its ubiquitous presence in the ambient atmosphere, the methods deployed showed excellent recoveries, reproducibility and quantification limits. A distinct diurnal variation in cVMS concentration, probably linked with the use of personal care products was observed for raw sewage but not in treated sewage effluent. The estimated per capita consumption of D₅ (∼2.7 mg cap⁻¹ d⁻¹) derived for the population served by this plant was significantly lower than that derived in the Environment Agency (UK) risk assessment (11.6 mg cap⁻¹ d⁻¹). The cVMS were highly removed during sewage treatment with efficiencies greater than 98%. The methods and findings of this pilot study can be used as the basis for future studies on the fate of cVMS substances in STPs.     

肘部张力对防静电无尘服功能的影响研究

本文模拟并计算了穿着状态下防静电无尘服肘部所受到的张力作用，以确定在穿用过程中服装受到的最大作用力。根据模拟计算结果，对在穿着状态下肘部张力对防静电服功能性的影响进行了实验研究，并对降低服装穿着时张力对性能的不良影响，提出了改进方法和建议。     

Headspace solid phase microextraction method for determination of triazine and organophosphorus pesticides in soil

A headspace solid phase microextraction method (HS-SPME) for simultaneous determination of five pesticides belonging to triazine and organophosphorus pesticide groups in soil samples was developed. Microextraction conditions, such as temperature, extraction time and sodium chloride (NaCl) content were investigated and optimized using 100 μ m polydimethyl-siloxane (PDMS) fiber. Detection and quantification were done by gas chromatography-mass spectrometry (GC-MS). Relative standard deviation (RSD) and recovery values for multiple analysis of soil samples fortified at 30 μ g kg^{? 1} of each pesticide were below 13 % and higher than 70 %, respectively. Limits of detection (LOD) for all the compounds studied were less than 3.2 μ g kg^{? 1}. The proposed method was applied in the analysis of some agricultural soil samples.     

Peroxidase activity,lignification and promotion of cell death in tobacco cells exposed to static magnetic field

Bio-effects of static magnetic fields on cell growth and cell death have been investigated in suspension-cultured tobacco cells as undifferentiated, embryonic plant cell model. The cells in their logarithmic growth phase were exposed to static magnetic field with the magnitudes of 10 mT and 30 mT for 5 h/day. Exposure to static magnetic field ceased the growth and caused an increase in cell death of exposed tobacco cells compared to those cells which were not treated with the field. Promotion of cell death was accompanied by a harmonized increase in the activity of peroxidase and increase of lignifcation of cell walls.     

顶空-气相色谱法测定水中溴乙烷

建立了顶空-气相色谱法测定环境中不同基质水样中溴乙烷的方法,分别考察了顶空平衡温度、平衡时间、离子强度对溴乙烷富集的影响,从而确定最佳方法参数。结果表明,溴乙烷在0. 10~10. 0μg/L范围内线性关系良好,相关系数(r)为0. 999 0,检出限为0. 012μg/L,测定下限为0. 048μg/L,加标回收率为86. 7%~104. 7%,相对标准偏差(RSD)为2. 9%~4. 8%。该方法准确度和精密度高、检出限低,能够满足环境中不同基质水样中溴乙烷的检测要求。     

尿中除草醚的测定

用甲苯直接萃取酸化后尿中的除草醚,以气相色谱法测定。方法的最低检测限为2μl/l;精密度为4.7％;回收率为95％。