脉冲电晕放电治疗有机废气的研究—放电反应器结构

对脉冲电晕法治理甲苯有机废气进行了实验，考察了放电反应器结构及参数对其性能的影响。结果表明，对线－筒式反应器，当直径较小时，去除率较高，但易发生火花放电，实验条件下直径２０ｍｍ的反应器效果较好。若采用陶瓷管反应器，其效果较金属管明显提高，脉冲峰值电压Ｖｐ为４２ｋＶ时，可使甲苯的去除率由４０％提高到６１％左右。对线－板式反应器，放电间隙越大，甲苯的去除率越低，使用陶瓷板反应器可使甲苯去除率明显提高，     

复合碳纤维混凝土的结构安全监测方法

提出了一个利用碳纤维混凝土与普通混凝土进行复合,实现结构安全监测的技术方法。根据普通混凝土与碳纤维混凝土之间良好的亲和能力,将碳纤维混凝土浇铸在结构承载的薄弱部分,利用碳纤维混凝土的压敏特性,可以对该部分的服役状态进行监测,获得结构的变形情况;另一方面,利用碳纤维混凝土的基本特性,还可以适当改善结构的承载强度。笔者所提出的复合结构既具有普通混凝土结构的基本特征,又赋予了结构的自我监测功能,比较有效地克服了全碳纤维混凝土结构建造所面临的电阻率波动、骨料石子影响和建设成本等几个方面的技术问题。     

Structure and thermal stability of toxic chromium(VI) species doped onto TiO2 powders through heat treatment

Chromium(VI)-containing sorbents in the form of sludge or solid residue from treatment processes are often landfilled or used as fill materials, therefore the long-term stability of metal binding is important. The reduction of Cr(VI)–Cr(III) through heat treatment may be a useful detoxification method. After heating at 500, 900, 1000, and 1100 °C for 4 h, the transformation of chemical states of chromium on 105 °C-dried, 7.9% Cr(VI)-doped TiO₂ powders was studied on the basis of surface area measurements, scanning electron microscopy (SEM) images, X-ray diffraction (XRD), and extended X-ray absorption fine structure (EXAFS) spectra. It was shown that Cr(VI) was reduced to Cr(III) in the Cr(VI)-doped samples after heating within 500–900 °C. The present results also suggested that the chromium octahedral was bridged to the titanium tetrahedral and was incorporated in TiO₂ minerals formed after 1000 °C treatment.     

低碳经济背景下我国产业结构升级对策研究

为了实现我国经济的平稳发展,改变以"高消耗、高增长、高污染"的传统经济增长方式,解决资源的过度消耗和温室气体的过量排放等问题,文章从我国产业及内部结构、产业的碳排放量和产业节能率三个方面进行了分析,提出了在低碳经济背景下实现我国产业结构升级的对策。     

流域景观格局对大型底栖动物群落结构的影响研究——以太子河山区段为例

为研究太子河山区段大型底栖动物群落结构与陆地景观因子之间的相互关系,以水生态调查和遥感解译数据为基础,采用主成分分析和回归分析的方法分析了景观格局指数与大型底栖动物群落结构指数的关系,结果表明:大型底栖动物的物种数、EPT科级分类单元数(蜉蝣目、襀翅目、毛翅目)和ASPT指数与景观聚集度指数、最大斑块指数、连通度指数呈显著正相关,与景观香农多样性指数、分离度指数、景观形状指数呈显著负相关。研究结果反映了流域景观斑块的破碎化和人为干扰会对底栖动物群落结构产生负面影响,可以指导以保护河流大型底栖动物群落为目标的流域景观格局优化。     

高温(70℃)玉米秸秆水解液产氢行为及群落结构

考察了高温条件下(70℃)牛粪堆肥、土壤、厌氧污泥、腐烂秸秆种接种物利用玉米秸秆水解液的产氢行为。结果表明:牛粪堆肥接种时达到最大的产气量(1355.7mL/L)和氢气产量(608.4mL/L),随后依次为腐烂秸秆、厌氧污泥和土壤。修改的Gompertz方程可以较好描述产氢量随时间变化趋势(R2>0.99)。牛粪堆肥接种时达到最大的产氢潜力(676.0mL/L),而土壤接种时的迟滞时间最小(9.8h)。DGGE图谱显示:不同接种物对应不同的微生物群落结构。Bacillus thermozeamaize,Enterobacter sp.JDM-19和Thermoanaerobacterium polysaccharolyticum strain,KMTHCJT和可能分别是牛粪堆肥,厌氧污泥和腐烂秸秆接种条件下的关键产氢微生物。     

The structure of the fire fighting foam surfactant Forafac®1157 and its biological and photolytic transformation products

For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by ¹H, ¹³C and ¹⁹F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility.     

Pathways of system transformation: Strategic agency to support regime change

There is a well-recognised need to transform existing systems of production and consumption towards a more sustainable orientation. However, there is much uncertainty about how to achieve sustainability transitions in practice, and what transition advocates and actors can do to catalyse and steer regime transformation. We therefore need evidence of how transitions are operationalised, in order to better understand the on-ground dynamics of regime change. To address this gap, this research paper examines three contemporary cases of transformational change in the Australian urban water sector and the dominant strategic approach to change adopted in each city. It focuses on the strategic behaviour of actors, in particular examining how agents navigate and respond to the opportunities and constraints of their context, and what initiatives (or combination thereof) can facilitate innovation diffusion and regime transformation. The results reveal three distinct patterns of change, each of which favour particular strategic interventions by transition proponents.In order to incubate transformational change, the results suggest that actors may be best served by initially employing strategies that are immediately compatible with their existing context. However, examination of the strengths and weaknesses of each pattern confirm that no single strategic approach is in itself sufficient, and in order to embed a novel innovation and bring about regime change, actors will eventually need to broaden the range of interventions used. The results also reveal the possibility of a ‘pattern-dependence’ that actors need to deliberately work to overcome in order to fully mainstream the desired change. These findings therefore provide insight into the links between regime transformation, patterns of change and actor strategies while also offering practical guidance that can be used to inform the design and implementation of regime transformation agendas and programs.     

污水土地处理CAD系统设计

针对污水土地处理设计实际，以提高设计速度和质量为目标，结合计算机辅助设计技术和软件技术的发展，采用成熟而先进的参数化设计技术及ADS开发工具，对土地处理设计中的几个关系问题进行了探讨。     

Temporal scales of landscape change following storms on a human-altered coast,New Jersey,USA

Cycles of storm destruction and rebuilding of human facilities are as much a part of a predictable cycle of shoreline change as destruction and re-establishment of landforms and wildlife habitat by natural processes. An evaluation of the human-induced and natural geomorphic responses to three storms in two vulnerable developed areas in New Jersey reveals that storms can have limited effect in re-establishing a natural coastal resource base of lasting significance. Reconstruction of coastal landscapes by human action may be more rapid than natural restoration, decreasing the likelihood for geomorphic features to develop based on natural processes. Reliance on storm processes to create new natural habitat in locations where there is human investment in buildings and support infrastructure is not realistic unless a proactive stance is taken to include naturally-functioning characteristics of the coastal system in reconstruction efforts. By striving to control construction of shorefront buildings to reduce their potential for damage, managers may be taking attention away from the separate but critical issue of ensuring that post-storm reconstruction effort include the potential for replacing loss of natural geomorphic features and wildlife habitat.