生物法处理低浓度有机废气的填料选择研究

采用不锈钢环、瓷环、陶粒、塑料环、海藻石、轻质陶块、煤渣等作为填料的试验研究，结果表明七种填料的净化性能顺序为：海藻石＞轻质陶块＞陶粒＞瓷环＞不锈钢环＞煤渣＞塑料环。     

Microbial cycling of iron and sulfur in acidic coal mining lake sediments

Lakes caused by coal mining processes are characterized by low pH, low nutrient status, and high concentrations of Fe(II) and sulfate due to the oxidation of pyrite in the surrounding mine tailings. Fe(III) produced during Fe(II) oxidation precipitates to the anoxic acidic sediment, where the microbial reduction of Fe(III) is the dominant electron-accepting process for the oxidation of organic matter, apparently mediated by acidophilic Acidiphilium species. Those bacteria can reduce a great variety of Fe(III)-(hydr)oxides and reduce Fe(III) and oxygen simultaneously which might be due to the small differences in the redox potentials under low pH conditions. Due to the absence of sulfide, Fe(II) formed in the upper 6 cm of the sediment diffuses to oxic zones in the water layer where itcan be reoxidized by Acidithiobacillus species. Thus, acidic conditions are stabilized by the cycling of iron which inhibits fermentative and sulfate-reducing activities. With increasing sediment depth, the amount of reactive iron decrease, the pH increases above 5, and fermentative and as yet unknown Fe(III)-reducing bacteria are also involved in the reduction of Fe(III). Sulfate is reduced apparently by the activity of spore-forming sulfate reducers including new species of Desulfosporosinus that have their pH optimum similar to in situconditions and are not capable of growth at pH 7. However, generation of alkalinity via sulfate reduction is reduced by the anaerobic reoxidation of sulfide back to sulfate. Thus, the microbial cycling of iron at the oxic-anoxic interface and the anaerobic cycling of sulfur maintains environmental conditions appropriate for acidophilic Fe(III)-reducing and acid-tolerant sulfate-reducing microbial communities.     

McCaffrey等估计轰燃前火灾温度方法的改进

在估计室内轰燃前火灾温度的多种方法中，McCaffrey等人提出的方法比较典型。该文根据内衬材料的热惯性对室内火灾的重要影响，在大量实验数据的基础上，对McCaffrey等人提出的这一方法进行了初步和理论上的改进；结合室内火灾的控制因素，对有机玻璃火灾的回归结果进行了进一步改进，提出了估计室内轰燃前火灾温度的新方法。     

Polymeric Complexes from Casein and Starch Phosphate: Characteristics and Enzyme Susceptibility

Novel biodegradable materials were prepared from potato starch enriched in phosphato moieties (DS 0.018 and 0.033) and casein in defatted milk. The components were blended in proportions providing starch: casein ratios of 2:1, 1:1, and 1:2 and were then precipitated with hydrochloric acid. Aqueous solubility, water-binding capacity, infrared spectra, and thermal analysis (thermogravimetry[7] and differential thermogravimetry of the precipitates revealed that they were not simple physical mixtures of the components. The components interacted with one another electrostatically with involvement of the phosphate groups of starch and the peptide bond of casein, as documented by infrared spectra. Because of insolubility in 7 M aqueous urea solution, they might also be considered as complexes in which the components were chemically bound.     

五大连池老黑山火山的两次喷发活动

老黑山是五大连池火山群中最年轻的火山.通过对老黑山火山锥体结构及其形态分析指出,老黑山火山并非单锥,而是由先、后不同时期形成的两个锥体叠加组成的复合锥,表明它有两次喷发活动.通过对新发掘出的史料的分析,进一步指出,老黑山火山的第一次喷发时间为1720(不是1719年)-1721年,第二次可能为1776年.两次喷发活动的确认为研究老黑山火山喷发历史、喷发过程、喷发危险性评价和灾害预测等提供了新依据.     

超高强度钻杆低温断裂性能及裂纹扩展特征研究

超高强度钻杆在冬季低温环境下容易发生脆性断裂事故,为了从断裂力学角度揭示其冷脆现象的本质,采用ZBC2302-D型示波冲击试验机,获得了不同温度下超高强度钢在冲击断裂过程中的力-位移曲线,并对比分析了冲击功、起裂功和裂纹扩展功之间的变化关系。采用国家标准GB 4161—2007中的计算公式,计算了冲击试样的裂纹扩展量Δa和阻抗应力强度因子K_R;同时,引入K_R阻力曲线,得到超高强度钻杆在不同温度下的剩余强度图。结果表明,当冲击试样开始出现裂纹时,随温度降低,钻杆的初始起裂应力有所增加,出现硬化现象。当钻杆出现一定长度的裂纹时,随温度降低,阻抗应力强度因子越来越小,而且降低速度越来越快,剩余强度也表现出相同的变化趋势。随温度降低,材料抵抗裂纹扩展的能力逐渐下降,表明钻杆在低温下更容易断裂。     

酸性矿井水中和沉淀法除铁优化

针对山西某煤矿高矿化度、高铁酸性矿井水除铁效果差、出水容易返色等问题,采用NaOH中和调pH、曝气及化学氧化等处理工艺进行酸性矿井水中和沉淀法除铁优化实验研究。结果表明,采用NaOH中和沉淀法除铁时,投加中和剂使出水pH达6.7以上时,出水中铁含量低于10 mg/L,满足排放要求。对于本实验废水NaOH所需投加量为2.8 g/L,铁的去除率可达到99.75%;以H2O2对原水进行氧化处理,可迅速将Fe(Ⅱ)氧化成Fe(Ⅲ),其用量与原水中Fe(Ⅱ)的含量成正比。当其用量为1.6 mL/L时,可将原水中的Fe(Ⅱ)完全转化为Fe(Ⅲ),投加中和剂使出水pH达到4.5以上时,能使出水中铁含量满足排放要求。对于实验废水所需的NaOH投加量为2.0 g/L,比直接中和沉淀所需的NaOH用量要节省28.6%。曝气处理对原水中Fe(Ⅱ)的氧化效果不明显。     

Leaching behaviour of different scrap materials at recovery and recycling companies: Full-, pilot- and lab-scale investigation

Scrap material recovery and recycling companies are confronted with waste water that has a highly fluctuating flow rate and composition. Common pollutants, such as COD, nutrients and suspended solids, potentially toxic metals, polyaromatic hydrocarbons and poly chlorinated biphenyls can exceed the discharge limits. An analysis of the leaching behaviour of different scrap materials and scrap yard sweepings was performed at full-scale, pilot-scale and lab-scale in order to find possible preventive solutions for this waste water problem. The results of these leaching tests (with concentrations that frequently exceeded the Flemish discharge limits) showed the importance of regular sweeping campaigns at the company, leak proof or covered storage of specific scrap materials and oil/water separation on particular leachates. The particulate versus dissolved fraction was also studied for the pollutants. For example, up to 98% of the polyaromatic hydrocarbons, poly chlorinated biphenyls and some metals were in the particulate form. This confirms the (potential) applicability of sedimentation and filtration techniques for the treatment of the majority of the leachates, and as such the rainwater run-off as a whole.     

金属冶炼进口物料的固体废物鉴别方法

建立了金属冶炼进口物料的固体废物鉴别方法,并利用该方法对海关查扣的3种金属冶炼进口物料进行了固体废物鉴别。鉴别结果显示:物料1、2和3的自然属性分别为砷含量超标铜精矿、锰阳极泥、回转窑氧化锌,产生来源分别为有害物质超标的产品、污染控制设施产生的物质、有意识加工的目标产物;物料1和2属于我国禁止进口的固体废物,物料3不属于固体废物。本文建立的固体废物鉴别方法可行,可为金属冶炼进口物料的固体废物鉴别和监管提供参考。     

拜耳法赤泥粒径分级预处理的研究

赤泥是从铝土矿中提取氧化铝的过程中产生的工业废渣.分析了拜耳法赤泥的粒径分布,以及主要化学组成和矿物组成在不同粒径赤泥中的变化规律.在此基础上,提出先将赤泥粒径分级预处理,然后根据粗细粒径赤泥的差异分别进行回收利用的思路.研究结果表明,赤泥中粒径大于0.075 mm的粗颗粒以铁、硅、钙为主,实践证明可以通过磁选或重选工...