EFFECTS OF FOREST HERBICIDE APPLICATIONS ON STREAMWATER CHEMISTRY IN SOUTHWESTERN BRITISH COLUMBIA1

ABSTRACT: The herbicide glyphosate was applied to portions of two watersheds in southwestern British Columbia to kill vegetation that was competing with Pseudotsuga menziesii (Douglas-fir) plantations. This application had little significant effect on streamwater chemistry (K⁺, Na²⁺, Mg²⁺, Ca²⁺, Cl^-, NOs₃^-, NH₄⁺, PO4^3-, SO₄⁼, and SiO₂ concentrations, electrical conductivity, and pH) when vegetation cover in a watershed was reduced by 4%, but had significant (P>0.05) effects, which lasted for at least five years, when cover was reduced by 43%. In this case, most parameters increased in value following the application, with K⁺ and Mg²⁺ concentrations and pH values exhibiting the most prolonged increases and NO₃^- concentrations exhibiting the greatest percentage increases. Sulphate and dissolved SiO₂ concentrations decreased following the application. Streamwater chemical fluxes showed similar trends to concentrations except that changes in fluxes were less significant and no decreases were observed. Forest management induced losses of NO₃-N in streamwater during the first five post-treatment years in the study area decreased in the order: herbicide application (approximately 40 kg/ha) < clearcutting and slashburning (approximately 20 kg/ha) < clearcutting (approximately 10 kg/ha). In watersheds similar to those of the study area, herbicide application is likely to have a greater impact on streamwater chemistry, in general, than would clearcutting or clearcutting followed by slashburning.     

THE EFFECTS OF DEICING SALTS ON WATER CHEMISTRY IN PINHOOK BOG,INDIANA1

ABSTRACT: A five-year study was conducted to identify the effects of road salt intrusion on the water chemistry of Pinhook Bog following operation of an uncovered salt storage pile adjacent to the bog for ten years. A distinct pattern of elevated salt concentrations was observed in the interstitial waters of the surface peat that corresponded to observed alterations in the bog vegetation. Yearly mean salt concentrations as high as 468 mg/l sodium and 1215 mg/l chloride were recorded in the plant root zone of the peat mat. The salt concentrations decreased significantly each year from 1979 to 1981 throughout the impacted area. Some increases of a lesser magnitude occurred in 1982 and 1983. Analysis of salt movements suggested that vertical transport by water movement was responsible for concentration changes. The major declines in salt levels occurred in the spring following snowmelt and heavy precipitation events. Evapotranspiration during periods of drought resulted in the gradual increases in surface peat salt concentrations. Diverted highway runoff was shown to be the major continuing source of sodium chloride contamination and was the likely source of the elevated calcium, magnesium, potassium, bicarbonate, and pH levels also observed in the impacted area.     

EFFECT OF “WHITING” ON OPTICAL PROPERTIES AND TURBIDITY IN OWASCO LAKE,NEW YORK1

ABSTRACT: The effects “whiting” (CaCO₃ precipitate) had on the optical properties and turbidity of the epilimnion of Owasco Lake, New York, were studied during the summer of 1985. Turbidity was partitioned according to “whiting” and non-“whiting” components utilizing a simple acidification procedure. Diffuse light attenuation was partitioned according to the attenuating processes of absorption and scattering. “Whiting” was present most of the summer. Two major “whiting” events occurred that caused major increases in turbidity and the attenuation of light. “Whiting” was the principle regulator of turbidity during the study; it caused increases in light attenuation by increasing light scattering. “Whiting” events can easily be mistaken by the public for phytoplankton blooms.     

IMPACT OF WATERSHED URBANIZATION ON STREAM INSECT COMMUNITIES1

ABSTRACT: The impact of urbanization on stream insect communities was determined by sampling 22 sites in northern Virginia representing a range of human population densities. Watershed development had little effect on the total insect numbers (no./m²), but shifted the taxonomic composition markedly. Relative abundance of Diptera (mainly chironomids) increased at more highly urbanized sites, while most other insect orders including Ephemeroptera (mayflies), Coleoptera (bettles), Megaloptera (dobsonflies), and Plecoptera (stone-flies) decreased. Trichoptera (caddisfiles) exhibited a variable response. Genus diversity and richness (number of genera) were significantly higher in less urbanized streams. Two genera of chironomids were positively correlated with increased urbanization, while 14 other genera (scattered through several orders) were negatively related to human population density. Principal components analysis demonstrated a gradient from more urbanized to less urbanized stations based on generic and order level biological data. Results of this study indicate that watershed urbanization has a major impact on benthic insect communities even in the absence of point source discharges.     

ASPECTS OF THE UNDERWATER LIGHT FIELD OF EIGHT CENTRAL NEW YORK LAKES1

ABSTRACT: The underwater light field of eight central New York lakes, which represent a wide range of trophic state, was characterized through paired measurements of Sechi disc transparency (SD, m) and diffuse light attenuation (K_d, m^?1). A total of 90 paired measurements are included in the data base. Substantial variability in the K_d SD product with time within individual systems, and amongst systems, was observed, which indicates differences in the relative contributions of absorption and scattering to attenuation. More than 50 percent of the temporal variability in K_d was attributable to attendant variations in chlorophyll a (C, mg m^?3) in only two of the lakes. Estimates of the adsorption (a, m^?1) and scattering (b, m^?1) coefficients based on paired K_d and SD measurements compared well with more precise determinations available for one of the lakes. Determinations of a and b for the eight lakes, from SD and K_d measurements, indicated great system-specificity and temporal variability in these characteristics. The temporal variability in relative contributions of a and b to K_d is consistent with covariation of different attenuating components and the lack of correlation between C and K_d in most of the study lakes.     

A PRELIMINARY STUDY OF THE EFFECTS OF DRAINAGE AND HARVESTING ON WATER QUALITY IN OMBROTROPHIC BOGS NEAR SEPT-ILES,QUEBEC1

ABSTRACT: Runoff and ground-water samples were collected from four ombrotrophic bogs, representing undisturbed and drained/harvested conditions, at two-week intervals during the summer of 1984. Analyses of samples for water quality parameters revealed significant (P < 0.05 level) increases in specific conductance, NH4⁺-N, total dissolved P, Mg, K, and Na and a decrease in the E₄:E₆ ratio (suggesting increased proportions of humic acid) associated with drainage. There were no significant changes in dissolved organic carbon, Ca concentrations, or pH. Comparison of samples collected before, during, and after ditching showed increases in the dissolved organic carbon, NH₄⁺-N, total dissolved P, K, and Na and a decrease in the E₄:E₆ ratio, but these changes were short lived; water quality returned to preditching values after about a week. The observed changes in water quality are small, probably because the peat is very acid (pH 3.0 to 4.5).     

DETECTABILITY OF STEP TRENDS IN THE RATE OF ATMOSPHERIC DEPOSITION OF SULFATE1

A method is presented to assist policy makers in determining the combination of number of sampling stations and number of years of sampling necessary to state with a given probability that a step reduction in atmospheric deposition rates of a given magnitude has occurred at a pre-specified time. This pre-specified time would typically be the time at which a sulfate emission control program took effect, and the given magnitude of reduction is some percentage change in deposition rate one might expect to occur as a result of the emission control. In order to determine this probability of detection, a stochastic model of sulfate deposition rates is developed, based on New York State bulk collection network data. The model considers the effect of variation in precipitation, seasonal variations, serial correlation, and site-to-site (cross) correlation. A nonparametric statistical test which is well suited to detection of step changes in such multi-site data sets is developed. It is related to the Mann-Whitney Rank-Sum test. The test is used in Monte Carlo simulations along with the stochastic model to derive statistical power functions. These power functions describe the probability of detecting (α=0.05) a step trend in deposition rate as a function of the size of the step-trend, record length before and after the step-trend, and the number of stations sampled. The results show that, for an area the size of New York State, very little power is gained by increasing the number of stations beyond about eight. The results allow policy makers to determine the tradeoff between the cost of monitoring and time required to detect a step-trend of a given magnitude with a given probability.     

CHEMICAL COMPOSITION OF SOFTWATER FLORIDA LAKES AND THEIR SENSITIVITY TO ACID PRECIPITATION1

ABSTRACT: Based on alkalinity data for 596 lakes, 31 percent of Florida's 7300 lakes have < 100 μeq/l alkalinity and are sensitive to acid depostion. More than two-thirds of the lakes in 12 northern Florida counties fit this criterion. Increasing aluminum and decreasing nutrient and chlorophyll a concentrations were observed with decressing pH in a survery of 20 softwater lakes. Maximum measured aluminum values (100-150 μg/L) are below levels asociated with fish toxicity. Factor analysis showed that lake chemistry was related to three principal factors, representing three major processes: watershed weathering, acidification, and nutrient inputs. An acidification index defined as the difference between excess SO₄^2- and excess (Ca²⁺+Mg²⁺) accounted for 74 percent of the variance in lake pH. Comparison of historical (late 1950a) and present data for pH, alkalinity, and excess SO₄^2- indicated loss of alkalinity (>25 μeq/L) and increase in excess SO₄^2- (16-34 μeq/L) in several softwater lakes.     

ATMOSPHERIC CONTRIBUTIONS TO FOREST NUTRIENT CYCLING1

The atmosphere is a significant source of plant nutrients that partially replenishes losses due to timber harvesting. The relative importance of wet and dry deposition depends upon the specific nutrient and site. Nitrogen in bulk precipitation (wetfall and dryfall) is equivalent to at least 70 percent of the nitrogen incorporated annually in above-ground woody tissues of some temperate hardwood forests. Atmospheric sources of calcium and potassium supply between 20 and 40 percent of the nutrients sequestered in woody increments. Annual nutrient inputs in bulk precipitation can exceed removals associated with sawiog harvest over a rotation period. Atmospheric inputs of nitrogen are only slightly less than hydrologic losses immediately after timber harvesting. The deposition of nutrients is highly variable in both time and space; interpretations of nutrient inputs and forest management impacts require quantification of inputs for a variety of ecosystems over long periods of time.     

ECOSYSTEM MANAGEMENT AND THE CONSERVATION OF AQUATIC BIODWERSITY AND ECOLOGICAL INTEGRITY1

ABSTRACT: Ecologically effective ecosystem management will require the development of a robust logic, rationale, and framework for addressing the inherent limitations of scientific understanding. It must incorporate a strategy for avoiding irreversible or large-scale environmental mistakes that arise from social and political forces that tend to promote fragmented, uncritical, short-sighted, inflexible, and overly optimistic assessments of resource status, management capabilities, and the consequences of decisions and policies. Aquatic resources are vulnerable to the effects of human activities catchment-wide, and many of the landscape changes humans routinely induce cause irreversible damage (e.g., some species introductions, extinctions of ecotypes and species) or give rise to cumulative, long-term, large-scale biological and cultural consequences (e.g., accelerated erosion and sedimentation, deforestation, toxic contamination of sediments). In aquatic ecosystems, biotic impoverishment and environmental disruption caused by past management and natural events profoundly constrain the ability of future management to maintain biodiversity and restore historical ecosystem functions and values. To provide for rational, adaptive progress in ecosystem management and to reduce the risk of irreversible and unanticipated consequences, managers and scientists must identify catchments and aquatic networks where ecological integrity has been least damaged by prior management, and jointly develop means to ensure their protection as reservoirs of natural biodiversity, keystones for regional restoration, management models, monitoring benchmarks, and resources for ecological research.