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101.
本文对乌鲁木齐市大气环境质量及其发展趋势作了简要的分析,说明目前市大气属煤烟-沙尘型污染区,氮氧化物和二氧化硫随着国民经济能耗的增加有发展的趋势,其它污染物仍稳定在目前水平,或稍有下降. 相似文献
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T. Colombo R. Santaguida A. Capasso F. Calzolari F. Evangelisti P. Bonasoni 《Atmospheric environment (Oxford, England : 1994)》2000,34(29-30)
The study concerning carbon dioxide measurements taken during the 1997, 1998 and 1999 summer campaigns at two different altitude stations and biospheric conditions are presented. The higher station (Mt. Cimone, 2165 m a.s.l.) is characterised by 360° free horizon and is located on a rocky mountain while the lower (Ninfa lake, 1550 m a.s.l.) is located inside the red spruce and beech forest. The different behaviour of CO2 at the two mountain stations has been registered. It shows the strong effect of nighttime soil emission and vegetation respiration on CO2 mixing ratio increases and of diurnal vegetative activity on CO2 concentration decreases at the lower measurement site. The baseline character of the higher measurement site has been confirmed by comparison of CO2 diurnal amplitudes recorded at the two stations. 相似文献
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西安市大气和水污染对人群健康损害的经济价值损失研究 总被引:3,自引:0,他引:3
环境污染对人群健康造成损害的经济价值评价一直是学术界讨论的热点.采用不同的价值评估方法-VPLL潜在寿命损失年法、VSL统计生命价值法、WTP支付意愿法对西安市1996—2003年的大气和水污染对人群健康造成的经济损失进行评价。结果表明:1996—2003年。西安市大气和水污染健康损失年平均为228792万-434237万元,占GDP的3.69%-7%。对居民健康有显着影响。 相似文献
107.
《环境科学学报(英文版)》2023,35(4):321-332
Sludge is the by-product of wastewater treatment process. Multisource sludge can be defined as sludge from different sources. Based on the sludge properties of five typical cities in the Yangtze River basin, including Jiujiang, Wuhu, Lu'an, Zhenjiang and Wuhan, this study investigated and summarized the characteristic variations and distribution differences of multiple indicators and substances from municipal sludge, dredged sludge, and river and lake sediments. The results demonstrated pH of multisource sludge was relatively stable in the neutral range. Organic matter and water content among municipal sludge were high and varied considerably between different wastewater treatment plants. Dredged sludge had an obviously higher sand content and wider particle distribution, which could be considered for graded utilization depending on its size. The nutrients composition of river and lake sediments was usually stable and special, with lower nitrogen and phosphorus content but higher potassium levels. The sources of heavy metals and persistent organic pollutants in multisource sludge were correlated, generally much higher among municipal sludge than dredged sludge and river and lake sediments, which were the most important limitation for final land utilization. Despite various properties of multisource sludge, the final fate and destination have some overall similarities, which need to be supplemented and improved by standards and laws. The study provided a preliminary analysis of suitable technical routes for municipal sludge, dredged sludge, river and lake sediments based on their different characteristics respectively, which was of great significance for multisource sludge co-treatment and disposal in the future of China. 相似文献
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《环境科学学报(英文版)》2023,35(7):139-151
This study investigated the enhancement effects of dissolved carbonates on the peroxymonosulfate-based advanced oxidation process with CuS as a catalyst. It was found that the added CO32− increased both the catalytic activity and the stability of the catalyst. Under optimized reaction conditions in the presence of CO32−, the degradation removal of 4-methylphenol (4-MP) within 2 min reached 100%, and this was maintained in consecutive multi-cycle experiments. The degradation rate constant of 4-MP was 2.159 min−1, being 685% greater than that in the absence of CO32− (0.315 min−1). The comparison of dominated active species and 4-MP degradation pathways in both CO32−-free and CO32−-containing systems suggested that more CO3•−/1O2 was produced in the case of CO32−deducing an electron transfer medium, which tending to react with electron-rich moieties. Meanwhile, Characterization by X-ray photoelectron spectroscopic and cyclic voltammetry measurement verified CO32− enabled the effective reduction of Cu2+ to Cu+. By investigating the degradation of 11 phenolics with different substituents, the dependence of degradation kinetic rate constant of the phenolics on their chemical structures indicated that there was a good linear relationship between the Hammett constants σp of the aromatic phenolics and the logarithm of k in the CO32−-containing system. This work provides a new strategy for efficient removal of electron-rich moieties under the driving of carbonate being widely present in actual water bodies. 相似文献
109.
成本低廉和无二次污染的"绿色"合成纳米材料是发展原位纳米环境修复技术的前沿研究课题之一.本文以绿茶提取液为还原剂和稳定剂进行"绿色"合成纳米铁,探讨在不同的气氛下"绿色"合成的纳米铁颗粒的主要成分,以期为调控合成纳米铁系材料提供基础研究.首先,利用扫描电子显微镜(SEM)、X射线能谱(EDS)、X射线光电子能谱分析(XPS)和傅里叶变换红外光谱(FTIR)等表征手段对不同反应气氛下合成的纳米铁颗粒的表面微观形貌、尺寸和价态结构进行分析.结果发现,在通入N2情况下,合成的纳米铁颗粒粒径为(84.7±11.5)nm,其主要成分以纳米零价铁为主;在通入空气情况下,合成的纳米铁粒径为(117.8±26.2)nm,其主要成分是纳米零价铁、氧化铁和四氧化三铁的混合物;通入O2时,合成的纳米铁粒径为(141.2±26.3)nm,其主要成分以四氧化三铁为主.其次,评价在不同气氛条件下合成纳米铁颗粒对去除亚甲基蓝(MB)的反应活性.结果表明,在反应温度313 K下降解初始浓度为50 mg·L-1的MB溶液,反应5 min时已达到平衡,通入N2合成的纳米铁降解MB,去除率高达98.7%,而通入O2合成的纳米铁反应效率低,对MB的去除率仅为65.3%.最后,从以上发现提出不同气氛下可以调控"绿色"合成的铁系纳米材料成分,从而导致不同的纳米修复环境中污染物的能力. 相似文献
110.
以氯化血红素为原料,制备了磁负载的硝基锌卟啉光催化剂.同时,利用热重分析仪(TG)、透射电子显微镜(TEM)、扫描电子显微镜(SEM)和振动磁强计(VSM)对催化剂进行了表征,发现制备的催化剂负载率为32.06%,催化剂为粒径均一的球形壳-核结构,具有良好的磁性.其次,研究了催化剂的催化降解性能.结果表明,磁负载硝基锌卟啉光催化剂在可见光下,对水中的双酚A(BPA)、对硝基苯酚(PNP)等均有90%以上的去除率;对于活性红染料废水的降解也取得了83.67%的降解率.自由基捕获实验证明,电子(e-)、羟基自由基(·OH)、空穴(h+)和氧自由基(O-·2)是降解反应中重要的活性物种.最后通过GC-MS等手段对降解机理进行了研究. 相似文献