全文获取类型
收费全文 | 4185篇 |
免费 | 428篇 |
国内免费 | 2266篇 |
专业分类
安全科学 | 172篇 |
废物处理 | 132篇 |
环保管理 | 326篇 |
综合类 | 3740篇 |
基础理论 | 1282篇 |
污染及防治 | 649篇 |
评价与监测 | 411篇 |
社会与环境 | 137篇 |
灾害及防治 | 30篇 |
出版年
2024年 | 34篇 |
2023年 | 135篇 |
2022年 | 201篇 |
2021年 | 210篇 |
2020年 | 216篇 |
2019年 | 214篇 |
2018年 | 221篇 |
2017年 | 250篇 |
2016年 | 284篇 |
2015年 | 364篇 |
2014年 | 361篇 |
2013年 | 587篇 |
2012年 | 441篇 |
2011年 | 409篇 |
2010年 | 339篇 |
2009年 | 339篇 |
2008年 | 331篇 |
2007年 | 346篇 |
2006年 | 323篇 |
2005年 | 214篇 |
2004年 | 190篇 |
2003年 | 161篇 |
2002年 | 119篇 |
2001年 | 110篇 |
2000年 | 71篇 |
1999年 | 69篇 |
1998年 | 62篇 |
1997年 | 48篇 |
1996年 | 57篇 |
1995年 | 39篇 |
1994年 | 23篇 |
1993年 | 22篇 |
1992年 | 25篇 |
1991年 | 13篇 |
1990年 | 8篇 |
1989年 | 3篇 |
1988年 | 8篇 |
1987年 | 9篇 |
1986年 | 2篇 |
1985年 | 4篇 |
1984年 | 2篇 |
1983年 | 2篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1980年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 3篇 |
1973年 | 1篇 |
1972年 | 1篇 |
排序方式: 共有6879条查询结果,搜索用时 15 毫秒
91.
研究了4种成片分布的典型岩性(页岩、石灰岩、花岗岩、黄土)区域沉积物金属元素(Li、Na、K、Ca、Sr、Ba、Ti、V、Cr、Mn、Fe、Co、Ni、Cu、Zn、Al等共16种)总量与形态特征.结果表明:这4种岩性区域沉积物金属元素含量与形态均有显著的差别.与其它岩性相比,黄土地区易迁移元素含量高,而重金属含量显著较低;其金属元素残渣态含量高,而有机态、铁锰氧化物态和可交换态含量低.石灰岩地区重金属含量较高,而易迁移元素如Na,Sr等含量则较低;其重金属元素残渣态含量不偏低,表明经风化作用释放出来的重金属参与了次生矿物的形成过程而得以富集.花岗岩地区重金属含量居中,而Fe和Al含量较高;其金属元素残渣态含量不偏高则与风化作用较强有关.页岩地区元素含量与形态均居中,代表了各种岩性的平均水平. 相似文献
92.
With the advent of more stringent controls on wastewater treatment, sewage sludge production in Europe and many parts of the world is increasing. With this increase comes the problem of sludge disposal, and recycling to land arguably offers an economically and environmentally sustainable option. However, a major limitation of sewage sludge reuse is the potential release of heavy metals from the sludge and heavy metal accumulation to toxic levels in topsoils. The properties of the sludge play a crucial role in determining the initial release and subsequent availability of heavy metals in amended soils. Bioavailable forms of heavy metals in recently amended soils are most likely to be those that are bioavailable in the sewage sludge. In this paper, published research on the importance of sewage sludge characteristics on metal release and bioavailability will be reviewed and contrasted with original research. A selection of sludges from around Australia has been collected for this purpose. Through the use of incubation studies, isotope dilution techniques, ion-selective electrode measurements and 13C-NMR spectroscopy, the importance of a range of sludge properties on heavy metal behaviour in sludges and sludge-amended soils is addressed. 相似文献
93.
R Burt M.A WilsonT.J Keck B.D Dougherty D.E StromJ.A Lindahl 《Advances in Environmental Research》2003,8(1):51-67
Long-term copper smelting in the Anaconda and Deer Lodge Valley area of Montana has resulted in an extensive area of trace element contamination. Aerial extent of contamination is generally established, but total analysis of soils does not correlate to relative degree of impact on vegetation growth. Three pedons (Beaverell, Cetrack and Judco) were analyzed by routine soil characterization methods, aqua regia microwave digestion, sequential chemical extraction, and X-ray diffraction analysis with the objective of providing a better understanding of chemical forms and potential reactivity of selected trace elements (Cd, Co, Cr, Cu, Hg, Mn, Ni, P, Pb). Surface horizons of soils are more acidic than subsoils, with pH for all horizons ranging from 4.0 to 8.7. Beaverell is the most contaminated in the upper 20 cm with the sum of total extractable (SUMTE) trace elements by microwave digestion ranging from 1836 to 3605 mg kg−1, largest H2O-soluble (WS) and exchangeable (EX) fractions (e.g. 1.6 and 9.3%, respectively), and smallest residual (RES) fraction (e.g. 14.3%). Cetrack has greater SUMTE elements than Judco, though a lower WS+EX fraction due to the effects of alkaline pH, carbonates and high P. Oxide (OX), organic matter/sulfide (OM/S), and RES fractions predominate over WS, EX, and specially-sorbed/carbonate-bound fractions (SS/CAR) for all horizons. Copper, Zn, Pb and Cd are elevated in surface over subsurface horizons in these latter fractions, indicating these elements were anthropogenic additions. X-ray data indicate that Pb, Cu, Cr and Cd partially exists as both OX and sulfide mineral forms. 相似文献
94.
研究了杭州市城郊文教居民区、风景旅游区、市郊农业区、市内商业区和市郊工业区等5种土地利用背景下的32个土样中8个重金属元素(Cd、Co、Cr、Cu、Ni、Pb、Zn、Mn)的含量和形态。结果表明,杭州市城郊土壤已受重金属的明显污染,其中以Pb的污染最为严重。污染程度为:市郊工业区>市内商业区>风景旅游区>文教居民区>市郊农业区。用连续提取方法对重金属分级表明,Cd、Co、Cr和Ni主要以残余态为主,平均占总量的60%以上,而Cu、Pb、Zn和Mn主要以酸可提取态、氧化物结合态和有机结合态存在,有较大的释放潜力和生物有效性。 相似文献
95.
通过连续提取法对电镀废水污染区和对照区农田土壤中的重金属元素Cu、Cr、Ni、Pb和Mn形态进行了研究.结果显示,污染区土壤中多种形态的Cu、Cr和Ni含量都显著高于对照区,尤其以它们的有机结合态差异最为显著.污染区较对照区土壤中Mn的总量虽无显著差异,但可交换态Mn的含量显著增加(分别为98.68mg/kg和40.75mg/kg).污染区与对照区土壤中的Pb的交换态、碳酸盐结合态、Fe-Mn氧化物结合态、有机结合态和残留态均无显著差异.电镀废水的污染使得农田土壤中Cu、Cr和Ni含量和生物有效性显著升高,Mn的化学形态改变,移动性和生物有效性增加. 相似文献
96.
97.
98.
重金属在牡蛎(Crassostrea virginica)中的生物积累及其影响因素的研究 总被引:11,自引:0,他引:11
牡蛎软体,贝壳和沉积物中Cd、Cr、Cu、Fe、Mn、Pb和Zn等重金属元素被同步分析研究,研究结果表明,重金属在牡蛎中的生物积累是牡自身的新陈代谢、重金属元素的地球化学性质和环境诸因素综合影响的结果,其中牡蛎斩生理作用对重金属在软体中的积累产生的影响尤为重要,而贝壳中重金属的积累对来自环境的影响更为敏感。 相似文献
99.
Tan Zhiqun 《环境科学学报(英文版)》1996,8(2):191-195
plane decaying leaves have been found capable of removing chromium and nickel ions from aqueous solutions. The removal efficiency depends upon the pH conditions, ions components and concentrations, and concentrations of leaves in media. The maximum removal for unique Cr6+ is about 7.5-8.0g/kg leaves at pH 4. 0, for unique Ni2+ about 2. 6g/kg at the region of PH5. 0-5.5. Under the described conditions nickel increases chromium uptake by plane decaying leaves from solution. 相似文献
100.
Mao Meizhou Liu Zihui Dong Huiru Liu Jingyi Kathe K. Bertines Minoru Koide Edward D. Goldberg 《环境科学学报(英文版)》1991,3(1):109-116
The fluxes of heavy metals and magnetite, a fly-ash component, from coal burning, to sediments of the Kunming Lake in Beijing have increased measurably over the last fifty years. Ages were introduced to the sediment strata through Pb-210 geochronologies. Even with a doubling of coal usage by the year 2000, the anthropogenic metal fluxes will still be less than those recorded in metropolitan Tokyo and U.S. lakes. 相似文献