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61.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献
62.
J. J. Jesudason R. H. Marchessault T. Saito 《Journal of Polymers and the Environment》1993,1(2):89-98
The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity. 相似文献
63.
根据周至国家级自然保护区的实际情况,从3个准则、24个基层指标因子出发,运用定性和定量相结合的德尔菲法、模糊数学法以及层次分析相结合的综合方法进行评价。其中,运用对称贴近度进行各个指标因子排序比较;运用非对称贴近度评价出生态质量、有效管理质量、社会经济价值分别处于较好、较差、较好水平,同时得出周至自然保护区综合水平较好。 相似文献
64.
安徽省区域经济差异的时空特征分析 总被引:1,自引:1,他引:1
在建立安徽省市域经济差异衡量指标体系的基础上,以安徽省17个地市为研究单元,采用层次分析法和ArcView GIS技术,探讨了安徽省市域经济差异变化的时间特征、空间格局及其发展变化过程,并对当前安徽省各市经济发展水平进行了分类。 相似文献
65.
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67.
以人为本是现代安全管理的重要原则 ,在生产经营活动中 ,保障人的生命更安全、更健康 ,生活更幸福 ,既是安全管理的重要目的 ,也是人类生活的必然需求。但是 ,人民提高生命质量的安全需求是多方面的、复杂的。通过对人类生存、繁衍和发展的历史进行深入分析发现 ,人的安全需求与马斯洛的层次需求理论有相似之处 ,虽然内涵不同 ,但需求总是由低层次向高层次发展 ,当一种低层需求得到满足后 ,更高层次的需求就占据支配地位 ,成为人的行为激励因素。笔者从人性化的角度对安全需求层次类型、每一层次的特征、发展规律进行了探讨 ,其结果有助于安全管理有针对性、科学性、时效性地进行宏观决策和微观调控 ,也有助于更好地增加安全投入 ,从而提高安全生产水平。把握人性化需求规律 ,对保护人们在生产过程中的安全和健康 ,处理好人的生命价值与安全生产、经济效益、社会效益之间的关系 ,有重要的现实意义。 相似文献
68.
安全工程的专业课程设置中存在的问题与研究 总被引:3,自引:0,他引:3
笔者首先指出了我国高校安全工程的专业课程设置和课程内容安排中存在的较为普遍的问题:课程设置与课程内容安排缺乏可操作性强的理论指导;在教学中同名专业课程,不同学校采用不同教材,教师讲授的内容,都存在较大差别和分歧。其次,从学科知识体系的层次结构的角度,将安全工程学科的专业知识划分为两大层次(包含6个小层次)。在此基础上,笔者将安全工程专业课程体系分为学科基础课程和横向展开课程;提出了安全工程的专业课程设置与课程内容安排应遵循的完备性和系统性原则;同时,给出了支持具体操作的表格。通过实践,对安全工程专业课程设置的新思路的合理性与可行性进行了检验。 相似文献
69.
70.
Gregory M. Ames Wade A. Wall Matthew G. Hohmann Justin P. Wright 《Conservation biology》2017,31(4):903-911
The causes of species rarity are of critical concern because of the high extinction risk associated with rarity. Studies examining individual rare species have limited generality, whereas trait‐based approaches offer a means to identify functional causes of rarity that can be applied to communities with disparate species pools. Differences in functional traits between rare and common species may be indicative of the functional causes of species rarity and may therefore be useful in crafting species conservation strategies. However, there is a conspicuous lack of studies comparing the functional traits of rare species and co‐occurring common species. We measured 18 important functional traits for 19 rare and 134 common understory plant species from North Carolina's Sandhills region and compared their trait distributions to determine whether there are significant functional differences that may explain species rarity. Flowering, fire, and tissue‐chemistry traits differed significantly between rare and common, co‐occurring species. Differences in specific traits suggest that fire suppression has driven rarity in this system and that changes to the timing and severity of prescribed fire may improve conservation success. Our method provides a useful tool to prioritize conservation efforts in other systems based on the likelihood that rare species are functionally capable of persisting. 相似文献