Study of lead phytoavailability for atmospheric industrial micronic and sub-micronic particles in relation with lead speciation

Particles from channelled emissions of a battery recycling facility were size-segregated and investigated to correlate their speciation and morphology with their transfer towards lettuce. Microculture experiments carried out with various calcareous soils spiked with micronic and sub-micronic particles (1650 ± 20 mg Pb kg⁻¹) highlighted a greater transfer in soils mixed with the finest particles. According to XRD and Raman spectroscopy results, the two fractions presented differences in the amount of minor lead compounds like carbonates, but their speciation was quite similar, in decreasing order of abundance: PbS, PbSO₄, PbSO₄·PbO, α-PbO and Pb⁰. Morphology investigations revealed that PM_2.5 (i.e. Particulate Matter 2.5 composed of particles suspended in air with aerodynamic diameters of 2.5 μm or less) contained many Pb nanoballs and nanocrystals which could influence lead availability. The soil-plant transfer of lead was mainly influenced by size and was very well estimated by 0.01 M CaCl₂ extraction.     

基于微观仿真的同站台换乘站客流疏散研究

旨在对同站台换乘站的客流行为和规律,以及对车站乘客疏散时的情况进行分析和研究。通过建立同站台换乘站的微观疏散仿真模型,利用微观仿真软件VISSIM对某即将建成使用的同站台换乘站的仿真模拟,直观地对客流的疏散过程和疏散人群分布状况进行动态观察,通过改变模型的参数设置,考察不同情况下换乘站的换乘效率,得出提高换乘效率的措施和建议,并最终为换乘站的设施设计和运营管理提供辅助设计与决策支持。     

基于F-AHP的产业转移后可持续发展评价模型构建与实证研究

本着系统思想， 运用F AHP法，依据现有相关数据和多位专家意见，从产业自身发展、产业与区域经济发展、产业与区域社会发展、产业与区域资源环境发展4个模块30个指标构建产业转移后可持续发展评价指标体系，建立包含指标间模糊关系矩阵和面向参评产业的模糊评价矩阵的评价模型。通过模型评价了2006～2009年江苏苏北各市转移产业的可持续发展水平和能力。模型结果表明：苏北五市近年来承接的产业已获得较好的生存能力和可持续发展能力，但从可持续发展度的分值来看，苏北各市转移产业的可持续发展水平还不高；相比于传统产业，各市目前转移产业的可持续发展水平普遍较高，但苏北五市承接的产业有较大的同构性。因此，苏北各市下一阶段应优先发展比较优势产业，错位承接转移产业并考虑其可持续发展能力的培育     

北京入境旅游流西向扩散与省域经济联系研究——以西部三大典型区为例

北京是我国经济、政治和文化中心,也是我国最重要的入境口岸之一。入京旅游流西向的扩散转移对省域之间旅游经济联系强度具有极大的直接促进作用,转移态是反映旅游流流向和流量的重要指标。在对我国西部三大典型旅游区界定的基础上,利用转移态指数模型和旅游经济联系强度模型对入京旅游流向西转移态及其与西部三大典型旅游区的经济联系强度进行了相关性分析,得出入京旅游流西向转移态对西部典型区经济的影响程度为:成渝泛西安云贵,在此基础上分析了原因,并对西部三大典型旅游区如何更好地吸引北京入境旅游"二手客源",以促进旅游业更快发展提出了相应对策与建议。     

乌鲁木齐冬季雾天可吸入颗粒物透射电子显微镜研究

利用透射电子显微镜(TEM)对乌鲁木齐冬季雾天采集的可吸入颗粒物(PM_2.5、PM_2.5~10)的形貌特征和集聚状态进行分析。将乌鲁木齐大气可吸入颗粒物分为烟尘集合体、飞灰、矿物颗粒、硫酸盐和有机颗粒等5种单颗粒类型,并讨论了其来源。TEM分析表明,PM_2.5中烟尘集合体占14%,飞灰占7.4%,矿物颗粒占24%,硫酸盐占16.7%,有机颗粒占20.4%;PM_2.5~10 中烟尘集合体没有观察到,飞灰占4.9%,矿物颗粒占26.8%,硫酸盐占12.2%,有机颗粒占58.5%。     

双负载双金属催化剂催化有机卤化物水相脱卤研究

通过把起相转移作用的聚乙二醇链固载在硅胶上（SiO2-PEG600），再将聚乙稀吡咯烷酮（PVP）络合双金属Pd-Cu(PVP-PdCl2-CuCl2)后负载其中，制成一种新型双负载双金属水相脱卤催化剂PVP－PdCl2-CuCl2/SiO2-PEG600。以甲酸钠为氢转移试制，在水相中催化有机卤化物脱卤，研究结果表明：反应温度为800℃，Pd∶Cu=2∶1（摩尔比），反应介质pH≈11.7左右时，该催化剂对芳香氯化物及α－氯代酮、酯具有良好的催化脱氯和重复使用性能。     

污泥转移SBR工艺处理低浓度生活污水

污泥转移SBR工艺是一种通过内部污泥回流实现污泥在不同SBR隔室间转移,从而增加污泥利用效率,提高系统除污效能的新工艺。以设计规模为240 m3/d、处理低浓度生活污水的工艺系统为对象,研究了新工艺在不同泥转移量(污泥回流比)下的除污性能,并与系统以传统SBR方式运行的情况进行了对比。结果表明,新工艺可以有效提高SBR反应器的容积利用率;采用30%的污泥回流比进行污泥转移,新工艺的处理能力比传统SBR工艺提高近1/2,除磷效率从46%提升至85%。出水各项水质指标均能达到国家排放标准的要求。     

Evaluation of food chain transfer of the antibiotic oxytetracycline and human risk assessment

There has been recent concern regarding the possibility of antibiotics entering the aquatic food chain and impacting human consumers. This work reports experimental results of the bioconcentration of the antibiotic oxytetracycline (OTC) by the Asian watermeal plant (Wolffia globosa Hartog & Plas) and bioaccumulation of OTC in watermeal and water by the seven-striped carp (Probarbus jullieni). They show, for the first time, the extent to which OTC is able to transfer from water to plant to fish and enter the food chain. The mean bioconcentration factor (dry weight basis) with watermeal was 1.28 × 10³ L kg⁻¹. Separate experiments were undertaken to characterize accumulation of OTC by carp from water and watermeal. These showed the latter pathway to be dominant under the conditions employed. The bioconcentration and biomagnification factors for these processes were 1.75 L kg⁻¹ and 2 × 10⁻⁴ kg g⁻¹ respectively. Using an aqueous concentration range of 0.34–3.0 μg L⁻¹, hazard quotients for human consumption of contaminated fish of 1.3 × 10⁻² to 1.15 × 10⁻¹ were derived.     

原子吸收法直接测量土壤中的汞含量

实验采用DMA-80自动测汞仪直接测定土壤中的汞含量，详细介绍了土壤样品中汞分析条件的选择，方法在0．4—400ng范围内，线性良好，其检出限为0．2ug／kg。     

COMPARISON OF REGRESSION AND TIME-SERIES METHODS FOR SYNTHESIZING MISSING STREAMFLOW RECORDS1

ABSTRACT: Regression and time-series techniques have been used to synthesize and predict the stream flow at the Foresta Bridge gage from information at the upstream Pohono Bridge gage on the Merced River near Yosemite National Park. Using the available data from two time periods (calendar year 1979 and water year 1986), we evaluated the two techniques in their ability to model the variation in the observed flows and in their ability to predict stream flow at the Foresta Bridge gage for the 1979 time period with data from the 1986 time period. Both techniques produced reasonably good estimates and forecasts of the flow at the downstream gage. However, the regression model was found to have a significant amount of autocorrelation in the residuals, which the time-series model was able to eliminate. The time-series technique presented can be of great assistance in arriving at reasonable estimates of flow in data sets that have large missing portions of data.