全文获取类型
收费全文 | 1967篇 |
免费 | 308篇 |
国内免费 | 717篇 |
专业分类
安全科学 | 163篇 |
废物处理 | 139篇 |
环保管理 | 273篇 |
综合类 | 1468篇 |
基础理论 | 228篇 |
污染及防治 | 258篇 |
评价与监测 | 54篇 |
社会与环境 | 95篇 |
灾害及防治 | 314篇 |
出版年
2024年 | 12篇 |
2023年 | 66篇 |
2022年 | 89篇 |
2021年 | 108篇 |
2020年 | 94篇 |
2019年 | 98篇 |
2018年 | 71篇 |
2017年 | 98篇 |
2016年 | 119篇 |
2015年 | 137篇 |
2014年 | 142篇 |
2013年 | 197篇 |
2012年 | 235篇 |
2011年 | 266篇 |
2010年 | 146篇 |
2009年 | 135篇 |
2008年 | 99篇 |
2007年 | 135篇 |
2006年 | 125篇 |
2005年 | 92篇 |
2004年 | 66篇 |
2003年 | 47篇 |
2002年 | 57篇 |
2001年 | 65篇 |
2000年 | 50篇 |
1999年 | 29篇 |
1998年 | 34篇 |
1997年 | 38篇 |
1996年 | 11篇 |
1995年 | 34篇 |
1994年 | 21篇 |
1993年 | 31篇 |
1992年 | 16篇 |
1991年 | 12篇 |
1990年 | 5篇 |
1989年 | 3篇 |
1984年 | 1篇 |
1983年 | 1篇 |
1982年 | 1篇 |
1981年 | 2篇 |
1980年 | 2篇 |
1974年 | 1篇 |
1967年 | 1篇 |
排序方式: 共有2992条查询结果,搜索用时 328 毫秒
101.
Formic acid was used for the nitrate reduction as a reductant in the presence of Pd:Cu/γ-alumina catalysts. The surface characteristics of the bimetallic catalyst synthesized by wet impregnation were investigated by SEM, TEM-EDS. The metals were not distributed homogeneously on the surface of catalyst, although the total contents of both metals in particles agreed well with the theoretical values. Formic acid decomposition on the catalyst surface, its influence on solution pH and nitrate removal efficacy was investigated. The best removal of nitrate (50 ppm) was obtained under the condition of 0.75 g/L catalyst with Pd:Cu ratio (4:1) and two fold excess of formic acid. Formic acid decay patterns resembled those of nitrate removal, showing a linear relationship between kf (formic acid decay) and k (nitrate removal). Negligible amount of ammonia was detected, and no nitrite was detected, possibly due to buffering effect of bicarbonate that is in situ produced by the decomposition of formic acid, and due to the sustained release of H2 gas. 相似文献
102.
Electrochemical and spectroscopic characteristics of dissolved organic matter in a forest soil profile 总被引:2,自引:0,他引:2
Dissolved organic matter (DOM) represents one of the most mobile and reactive organic compounds in ecosystem and plays an important role in the fate and transport of soil organic pollutants, nutrient cycling and more importantly global climate change. Electrochemical methods were first employed to evaluate DOM redox properties, and spectroscopic approaches were utilized to obtain information concerning its composition and structure. DOM was extracted from a forest soil profile with five horizons. Differential pulse voltammetry indicated that there were more redox-active moieties in the DOM from upper horizons than in that from lower horizons. Cyclic voltammetry further showed that these moieties were reversible in electron transfer. Chronoamperometry was employed to quantify the electron transfer capacity of DOM, including electron acceptor capacity and electron donor capacity, both of which decreased sharply with increasing depth. FT-IR, UV-Vis and fluorescence spectra results suggested that DOM from the upper horizons was enriched with aromatic and humic structures while that from the lower horizons was rich in aliphatic carbon, which supported the findings obtained by electrochemical approaches. Electrochemical approaches combined with spectroscopic methods were applied to evaluate the characteristics of DOM extracted along a forest soil profile. The electrochemical properties of DOM, which can be rapidly and simply obtained, provide insight into the migration and transformation of DOM along a soil profile and will aid in better understanding of the biogeochemical role of DOM in natural environments. 相似文献
103.
系统分析了辽河流域近十年社会经济和水污染物排放之间的关系,基于污染物排放强度和人均GDP指标,建立辽河流域COD和氨氮环境学习曲线;结合情景分析法预测在现有治污水平下,辽河流域未来水污染物排放趋势及水环境压力。结果表明,辽河流域水环境压力巨大。根据辽河流域污染治理中存在的实际问题,提出新时期的污染治理模式。 相似文献
104.
污泥的处理与处置已成为国内外污水处理厂的沉重负担,污泥减量成为解决此问题的重要途径。针对污泥处理处置过程中的环境问题和经济效益,在隐性生长、代谢解偶联、微型动物捕食作用等方面阐述了在水处理方面污泥减量化技术的研究进展,综述了污泥减量技术的研究应用现状,同时探讨了各技术存在的问题及其重点发展方向。 相似文献
105.
以碳布为阴阳极材料构建一种新型的生物电化学系统(BES),研究该系统在不曝气条件下对城市污水的处理效果,并与传统的厌氧和好氧处理方法进行比较。结果表明,该BES处理城市污水是可行的,与传统曝气法相比能够显著降低能耗。在进水CODcr,为350mg/L、NH3-N为15mg/L、水力停留时间(HRT)为24h时,电化学强化生物处理系统对CODcr和NH3-N的去除率达84%和80%,优于同等条件下的厌氧、好氧生物处理方法。BES的输出电压最高为211mV。 相似文献
106.
107.
108.
109.
氧气热处理的TiO2纳米管阵列光电催化降解亚甲基蓝的研究 总被引:1,自引:0,他引:1
采用原位阳极氧化法在Ti基底上制备了高度有序的TiO2纳米管阵列薄膜,SEM图像表明TiO2纳米管定向排列整齐,分布均匀,其管径范围在70~100 nm.XRD结果证明,阳极氧化法制备的TiO2纳米管为无定型晶型,经退火后为具有良好光催化活性的锐钛矿型.以亚甲基蓝(methylene blue)为目标物研究了TiO2纳米管光电催化性能及影响因素,结果表明,以0.1 mol/L NaCl为电解质,在氧气热处理气氛下,外加偏压为0.5 V、pH=3.25、光照强度为1 000μW/cm2、纳米管薄膜表面积为2 cm×2 cm且MB初始浓度为10 mg/L的条件下,TiO2纳米管阵列薄膜光电催化降解MB的降解效率可达99.56%.电化学阻抗谱分析显示,光电催化降解过程的速控步骤均为表面反应步骤,外加偏压减小了界面电荷转移阻抗,提高了光生载流子的分离效率. 相似文献
110.