全文获取类型
收费全文 | 953篇 |
免费 | 114篇 |
国内免费 | 155篇 |
专业分类
安全科学 | 150篇 |
废物处理 | 30篇 |
环保管理 | 177篇 |
综合类 | 536篇 |
基础理论 | 104篇 |
环境理论 | 5篇 |
污染及防治 | 74篇 |
评价与监测 | 82篇 |
社会与环境 | 43篇 |
灾害及防治 | 21篇 |
出版年
2024年 | 3篇 |
2023年 | 21篇 |
2022年 | 17篇 |
2021年 | 30篇 |
2020年 | 25篇 |
2019年 | 32篇 |
2018年 | 31篇 |
2017年 | 38篇 |
2016年 | 39篇 |
2015年 | 36篇 |
2014年 | 71篇 |
2013年 | 72篇 |
2012年 | 74篇 |
2011年 | 98篇 |
2010年 | 71篇 |
2009年 | 72篇 |
2008年 | 51篇 |
2007年 | 68篇 |
2006年 | 53篇 |
2005年 | 49篇 |
2004年 | 26篇 |
2003年 | 35篇 |
2002年 | 33篇 |
2001年 | 33篇 |
2000年 | 18篇 |
1999年 | 26篇 |
1998年 | 18篇 |
1997年 | 11篇 |
1996年 | 12篇 |
1995年 | 11篇 |
1994年 | 11篇 |
1993年 | 13篇 |
1992年 | 7篇 |
1991年 | 3篇 |
1990年 | 6篇 |
1989年 | 1篇 |
1988年 | 3篇 |
1987年 | 1篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1222条查询结果,搜索用时 31 毫秒
71.
72.
73.
74.
J. Roger McHenry Jerry C. Ritchie Frank R. Schiebe 《Journal of the American Water Resources Association》1977,13(1):81-92
ABSTRACT: The total suspended sediment loads of four north Mississippi reservoirs were determined from measurements of concentrations of suspended sediment in a vertical profile at several locations on each reservoir made during the year. These data were combined with the stage-height and known stage-volume relationships for each reservoir in a numerical integration to determine the total suspended sediment in the water body. Total suspended sediments were estimated using the product of the suspended sediment concentration in the surface water by the appropriate reservoir volume. The averaged ratios of the estimated to measured suspended sediment loads for each reservoir exceeded 0.90. Since the concentration of suspended sediments in surface waters of north Mississippi reservoirs has been shown as highly correlated with spectral reflectance, estimating the total suspended sediment of these reservoirs using remotely sensed spectral reflectance data is possible. 相似文献
75.
I. Vigano T. Rckmann R. Holzinger A. van Dijk F. Keppler M. Greule W.A. Brand H. Geilmann H. van Weelden 《Atmospheric environment (Oxford, England : 1994)》2009,43(35):5637-5646
Recent experiments have shown that dry and fresh leaves, other plant matter, as well as several structural plant components, emit methane upon irradiation with UV light. Here we present the source isotope signatures of the methane emitted from a range of dry natural plant leaves and structural compounds. UV-induced methane from organic matter is strongly depleted in both 13C and D compared to the bulk biomass. The isotopic content of plant methoxyl groups, which have been identified as important precursors of aerobic methane formation in plants, falls roughly halfway between the bulk and CH4 isotopic composition. C3 and C4/CAM plants show the well-established isotope difference in bulk 13C content. Our results show that they also emit CH4 with different δ13C value. Furthermore, δ13C of methoxyl groups in the plant material, and ester methoxyl groups only, show a similar difference between C3 and C4/CAM plants. The correlation between the δ13C of emitted CH4 and methoxyl groups implies that methoxyl groups are not the only source substrate of CH4.Interestingly, δD values of the emitted CH4 are also found to be different for C3 and C4 plants, although there is no significant difference in the bulk material. Bulk δD analyses may be compromised by a large reservoir of exchangeable hydrogen, but no significant δD difference is found either for the methoxyl groups, which do not contain exchangeable hydrogen. The δD difference in CH4 between C3 and C4 plants indicates that at least two different reservoirs are involved in CH4 emission. One of them is the OCH3 group, the other one must be significantly depleted, and contribute more to the emissions of C3 plants compared to C4 plants. In qualitative agreement with this hypothesis, CH4 emission rates are higher for C3 plants than for C4 plants. 相似文献
76.
《环境科学学报(英文版)》2023,35(7):202-212
The excessive accumulation of potentially toxic metals (Pb and Cd) in coastal wetlands is among the main factors threatening wetland ecosystems. However, the effects of water table depth (WTD) on the risk and binding mechanisms of potentially toxic metals in sediments remain unclear. Here, sediments from different WTD obtained from a typical coastal wetland were evaluated using a newly developed strategy based on chemical extraction methods coupled with high-resolution spectroscopy. Our findings indicated that the WTD of the coastal wetland fluctuates frequently and the average enrichment factor for Pb was categorized as minor, whereas Cd enrichment was categorized as moderate. High-resolution spectroscopy techniques also demonstrated that organic functional groups and partly inorganic compounds (e.g., Fe-O/Si-O) played a vital role in the binding of Pb and Cd to surface sediments. Additionally, mineral components rather than organic groups were mainly bound to these metals in the bottom sediments. Collectively, our findings provide key insights into the potential health effects and binding characteristics of potentially toxic metals in sediments, as well as their dynamic behavior under varying sediment depths at a microscale. 相似文献
77.
Excessive inter-contamination with heavy metals hampers the application of biological treatment products derived from mixed or mechanically-sorted municipal solid waste (MSW). In this study, we investigated fine particles of < 2 mm, which are small fractions in MSW but constitute a significant component of the total heavy metal content, using bulk detection techniques. A total of 17 individual fine particles were evaluated using synchrotron radiation-based micro-X-ray fluorescence and micro-X-ray diffraction. We also discussed the association, speciation and source apportionment of heavy metals. Metals were found to exist in a diffuse distribution with heterogeneous intensities and intense hot-spots of < 10 μm within the fine particles. Zn-Cu, Pb-Fe and Fe-Mn-Cr had significant correlations in terms of spatial distribution. The overlapped enrichment, spatial association, and the mineral phases of metals revealed the potential sources of fine particles from size-reduced waste fractions (such as scraps of organic wastes or ceramics) or from the importation of other particles. The diverse sources of heavy metal pollutants within the fine particles suggested that separate collection and treatment of the biodegradable waste fraction (such as food waste) is a preferable means of facilitating the beneficial utilization of the stabilized products. 相似文献
78.
Ozonation and ionizing radiation are both advanced oxidation processes (AOPs) without chemical addition and secondary pollution. Also, the two processes'' efficiency is determined by different pH conditions, which creates more possibilities for their combination. Importantly, the combined process of ozonation and ionizing radiation could be suitable for treating wastewaters with extreme pH values, i.e., textile wastewater. To find synergistic effects, the combined process of ozonation and ionizing radiation mineralization was investigated for degradation of polyvinyl alcohol (PVA) at different pH levels. A synergistic effect was found at initial pH in the range 3.0–9.4. When the initial pH was 3.0, the combined process of ozonation and ionizing radiation gave a PVA mineralization degree of 17%. This was 2.7 times the sum achieved by the two individual processes, and factors of 2.1 and 1.7 were achieved at initial pH of 7.0 and 9.4, respectively. The combined process of ozonation and ionizing radiation was demonstrated to be a feasible strategy for treatment of PVA-containing wastewater. 相似文献
79.
核磁共振作为一种分析手段广泛应用于物理、化学、生物、医疗等领域.本文从核磁共振原理出发,分析核磁共振成像仪主要环境影响,结合环评现状,分析环评管理存在的主要问题,结合相关法规条文,查找存在这些问题的主要原因,结合目前核磁共振仪的建设情况和使用条件,从切合实际角度出发,提出核磁共振成像仪建设项目环评管理建议. 相似文献
80.
目的 研究毫米波引信近炸探测器超宽带(Ultra-wideband,UWB)电磁脉冲防护加固措施,提高引信的电磁防护能力。方法 利用超宽带辐照试验平台,开展辐照试验,通过测试,确定受损探测器的损伤部位,明确辐照效应机理,并提出针对性加固措施。结果 超宽带电磁脉冲可使探测器出现死机或硬损伤的现象,受试探测器的效应场强阈值在50~80 kV/m。死机可在重启后恢复,而硬损伤为不可恢复现象。结论 毫米波引信近炸探测器对超宽带电磁脉冲较为敏感,锁相环回路是探测器的敏感部位。探测器暴露在辐照场下的射频电路和天线窗口是超宽带能量的主要耦合通道。采取改进元器件布局、更换器件和屏蔽线等加固措施后,探测器超宽带的防护能力有较大提升,证明了加固措施的有效性。 相似文献