全文获取类型
收费全文 | 8903篇 |
免费 | 1209篇 |
国内免费 | 5324篇 |
专业分类
安全科学 | 1747篇 |
废物处理 | 280篇 |
环保管理 | 813篇 |
综合类 | 8511篇 |
基础理论 | 1805篇 |
环境理论 | 2篇 |
污染及防治 | 1314篇 |
评价与监测 | 412篇 |
社会与环境 | 330篇 |
灾害及防治 | 222篇 |
出版年
2024年 | 48篇 |
2023年 | 399篇 |
2022年 | 560篇 |
2021年 | 623篇 |
2020年 | 621篇 |
2019年 | 629篇 |
2018年 | 503篇 |
2017年 | 463篇 |
2016年 | 537篇 |
2015年 | 623篇 |
2014年 | 528篇 |
2013年 | 962篇 |
2012年 | 972篇 |
2011年 | 1040篇 |
2010年 | 682篇 |
2009年 | 819篇 |
2008年 | 676篇 |
2007年 | 791篇 |
2006年 | 774篇 |
2005年 | 565篇 |
2004年 | 473篇 |
2003年 | 387篇 |
2002年 | 288篇 |
2001年 | 249篇 |
2000年 | 223篇 |
1999年 | 174篇 |
1998年 | 125篇 |
1997年 | 126篇 |
1996年 | 98篇 |
1995年 | 99篇 |
1994年 | 67篇 |
1993年 | 70篇 |
1992年 | 46篇 |
1991年 | 18篇 |
1990年 | 23篇 |
1989年 | 19篇 |
1988年 | 14篇 |
1987年 | 5篇 |
1986年 | 10篇 |
1985年 | 4篇 |
1984年 | 7篇 |
1983年 | 11篇 |
1982年 | 13篇 |
1981年 | 9篇 |
1980年 | 6篇 |
1979年 | 4篇 |
1978年 | 4篇 |
1973年 | 5篇 |
1972年 | 5篇 |
1971年 | 33篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
991.
Use of Descriptors of Ecosystem Functioning for Monitoring a National Park Network: A Remote Sensing Approach 总被引:1,自引:0,他引:1
Baseline assessments and monitoring of protected areas are essential for making management decisions, evaluating the effectiveness
of management practices, and tracking the effects of global changes. For these purposes, the analysis of functional attributes
of ecosystems (i.e., different aspects of the exchange of matter and energy) has advantages over the traditional use of structural
attributes, like a quicker response to disturbances and the fact that they are easily monitored through remote sensing. In
this study, we described the spatiotemporal patterns of different aspects of the ecosystem functioning of the Spanish national
parks and their response to environmental changes between 1982 and 2006. To do so, we used the NOAA/AVHRR-GIMMS dataset of
the Normalized Difference Vegetation Index (NDVI), a linear estimator of the fraction of photosynthetic active radiation intercepted
by vegetation, which is the main control of carbon gains. Nearly all parks have significantly changed during the last 25 years:
The radiation interception has increased, the contrast between the growing and nongrowing seasons has diminished, and the
dates of maximum and minimum interception have advanced. Some parks concentrated more changes than others and the degree of
change varied depending on their different environmental conditions, management, and conservation histories. Our approach
identified reference conditions and temporal changes for different aspects of ecosystem functioning, which can be used for
management purposes of protected areas in response to global changes. 相似文献
992.
海洋巨藻(Durvilaea potatorum)生物吸附剂对Hg~(2 )的吸附动力学研究 总被引:2,自引:0,他引:2
对经特殊的稳定化预处理所得的海洋巨藻 (Durvillaeapotatorum)生物吸附剂对Hg2 的吸附动力学进行了研究 ,报导了不同Hg2 初始浓度、温度以及生物吸附剂平均粒径下动态吸附量与时间的关系 .结果显示 ,各吸附动力学曲线呈优惠型 ;当生物吸附剂平均粒径为 0 .45mm时 ,Hg2 的半饱和时间tS均不超过 6 0min ;Hg2 初始浓度和生物吸附剂粒径越小 ,吸附温度越大 ,达到吸附平衡所需的时间越短 .在测试范围内 ,生物吸附剂的平衡吸附容量与粒径和温度无关 .同时考察了吸附过程中的传质效应并对液膜传质系数kL进行了关联 ,结果表明 :当吸附时间t≤tS时 ,Hg2 的吸附速率为液膜传质控制 ;在测试范围内 ,kL为 0 .0 40 7~ 0 .112cm/s.本研究结果为利用海洋巨藻 (Durvillaeapotatorum)生物吸附剂处理含汞废水的规模化应用提供了一定的依据 .图 5表 2参 11 相似文献
993.
pH、盐度对微生物还原硫酸盐的影响研究 总被引:2,自引:1,他引:1
采用厌氧生物处理工艺,研究了在不同盐度下pH连续降低对硫酸盐还原和有机物去除率的影响。实验结果表明,硫酸盐还原菌有很强的适应pH变化的能力,在pH值达到4以下仍有60%的硫酸盐去除率。NaCl浓度由4g/L增加到50g/L抑制了各厌氧菌的活性,导致硫酸盐和有机物去除率的下降,但硫酸盐还原菌耐受性高于产甲烷菌等其他厌氧菌,在NaCl浓度为50g/L下,硫酸盐去除率能达到50%,而有机物去除率则低于30%。qRT—PCR表明了系统菌落中SRB随着环境的变化情况与化学指标结果相一致,该反应器体系中SRB在整个厌氧菌群落中只占了很小部分。 相似文献
994.
Robert Kase Peter D. Hansen Birgit Fischer Werner Manz Peter Heininger Georg Reifferscheid 《Environmental science and pollution research international》2009,16(1):54-64
Background, aim, and scope The enzyme-linked receptor assay (ELRA) detects estrogenic and anti-estrogenic effects at the molecular level of receptor
binding and is a useful tool for the integrative assessment of ecotoxicological potentials caused by hormonally active agents
(HAA) and endocrine disrupting compounds (EDC). The main advantage of the ELRA is its high sample throughput and its robustness
against cytotoxicity and microbial contamination. After a methodological adaptation to salinity of the ELRA, according to
the first part of this study, which increased its salinity tolerance and sensitivity for 17-β-estradiol, the optimised ELRA
was used to investigate 13 native sediments characterised by different levels of salinity and chemical contamination. The
applicability of the ELRA for routine analysis in environmental assessment was evaluated. Salinity is often a critical factor
for bioassays in ecotoxicological sediment assessment. Therefore, salinity of the samples was additionally adjusted to different
levels to characterise its influence on elution and binding processes of receptor-binding substances.
Materials and methods The ELRA was carried out with the human estrogen receptor α (ER) in a 96-well microplate format using the experimental setup
known from the competitive immunoassay based on ligand–protein interaction. It is an important improvement that a physiologically
relevant receptor was used as a linking protein instead of an antibody. The microplates were coated with a 17-β-estradiol-BSA
conjugate, and dilution series of estradiol and of native sediment samples were added and incubated with the ER. After a washing
step, a biotinylated mouse anti-ER antibody was added to each well. Receptor binding to estradiol, agonistic and antagonistic
receptor binding, were determined by a streptavidin-POD-biotin complex with subsequent measurement of the peroxidase activity
at the wavelength of 450 nm using a commercial ELISA multiplate reader. The sediment elutriates and pore water samples of
sediments were tested in a dilution series to evaluate at which dilution step the receptor-binding potential ends. In the
elution process (see Section 2.1 to 2.2), a method was developed to adjust the salinity to the levels of the reference testings, which offers an appropriate option
to adjust the salinity in both directions. Statistical evaluation was made with a combination of the Mann–Whitney U test and the pT-method.
Results This part of the study characterised the environmental factor ‘salinity’ for prospective applications of the ELRA. Using reference
substances such as 17-β-estradiol, the ELRA showed sigmoid concentration-effect relations over a broad range from 0.05 μg/l
to 100 μg/l under physiological conditions. After methodological optimisation, both sensitivity and tolerance of the assay
against salinity could be significantly raised, and the ELRA became applicable under salinity conditions up to concentrations
of 20.5‰. The mean relative inter-test error (n = 3) was around 11% with reference substances and below 5% for single sediments elutriates in three replicates each. For
sediment testings, the pore water and different salinity-adjusted elutriates of 13 sediments were used. A clear differentiation
of the receptor-binding potential could be reached by application of the pT-method. Thereby, pT-values from one to six could
be assigned to the sediments, and the deviation caused by the different salinity conditions was one pT-value. The mean standard
deviation in the salinity adaptation procedure of the elutriates was below 5%.
Discussion Although the ELRA has already been used for assessments of wastewater, sludge and soil, its applicability for samples to different
salinity levels has not been investigated so far. Even if the ELRA is not as sensitive as the E-screen or the YES-assay, with
regard to reference substances like 17-β-estradiol, it is a very useful tool for pre-screening, because it is able to integrate
both estrogenic as well as anti-estrogenic receptor-binding effects. According to the results of sediment testing, and given
the integrative power to detect different directions of effects, the ELRA shows sufficient sensitivity and salinity tolerance
to discriminate receptor-binding potentials in environmental samples.
Conclusions The optimised ELRA assay is a fast, cost-effective, reliable and highly reproducible tool that can be used for high-throughput
screening in a microplate format in detecting both estrogenic and anti-estrogenic effects. Additionally, the ELRA is robust
against microbial contaminations, and is not susceptible towards cytotoxic interferences like the common cell-culture methods.
The general applicability and sufficient sensitivity of the ELRA was shown in freshwater environments. Marine and brackish
samples can be measured up to salinity levels of 20.5‰.
Recommendations and perspectives In view of the proven sensitivity, functionality and the fastness of the ELRA, it is recommendable to standardise the test
method. At the moment, no adequate in vitro test procedure exists which is standardised to DIN or ISO levels. The E-screen
and the yeast estrogen/androgen screens (YES/YAS) sometimes underlie strong cytotoxic effects, as reported in the first part
of this study. Further development of an ELRA assay using human androgen receptors appears to be very promising to gain information
about androgenic and anti-androgenic effects, too. This would offer a possibility to use the ELRA as a fast and reliable pre-screening
tool for the detection of endocrine potentials, thus minimising time and cost-expensive animal experiments. 相似文献
995.
武钢三烧区域改建了二台大连三洋蒸汽型双效溴化锂吸收式制冷机。叙述了该改建项目的主机选型、参数选定、设计特点等。 相似文献
996.
997.
998.
Removal of Pb(II) ions from aqueous solution using activated tea waste: Adsorption on a fixed-bed column 总被引:1,自引:0,他引:1
An inexpensive and effective adsorbent was developed from waste tea leaves for the dynamic uptake of Pb(II). Characterization of the adsorbents showed a clear change between physico-chemical properties of activated tea waste and simply tea waste. The purpose of this work was to evaluate the potential of activated tea waste in continuous flow removal of Pb(II) ions from synthetic aqueous effluents. The performance of the system was evaluated to assess the effect of various process variables, viz., of bed height, hydraulic loading rate and initial feed concentration on breakthrough time and adsorption capacity. The shape of the breakthrough curves was determined for the adsorption of Pb(II) by varying different operating parameters like hydraulic loading rate (2.3–9.17 m3/h m2), bed height (0.3–0.5 m) and feed concentration (2–10 mg/l). An attempt has also been made to model the data generated from column studies using the empirical relationship based on the Bohart–Adams model. There was an acceptable degree of agreement between the data for breakthrough time calculated from the Bohart–Adams model and the present experimental study with average absolute deviation of less than 5.0%. The activated tea waste in this study showed very good promise as compared with the other adsorbents available in the literature. The adsorbent could be suitable for repeated use (for more than four cycles) without noticeable loss of capacity. 相似文献
999.
《Disasters》1999,23(3):271-276
Books reviewed:
Tim Dyson, Population and Food: Global Trends and Future Prospects
R. S. J. Sparks, M. I. Bursik, S. N. Carey, J. S. Gilbert, L. S. Glaze, H. Sigurdsson and A. W. Woods, Volcanic Plumes
Jasper Becker, Hungry Ghosts: Mao's Secret Famine
Dali L. Yang, Calamity and Reform in China: State, Rural Society and Institutional Change Since the Great Leap Forward 相似文献
Tim Dyson, Population and Food: Global Trends and Future Prospects
R. S. J. Sparks, M. I. Bursik, S. N. Carey, J. S. Gilbert, L. S. Glaze, H. Sigurdsson and A. W. Woods, Volcanic Plumes
Jasper Becker, Hungry Ghosts: Mao's Secret Famine
Dali L. Yang, Calamity and Reform in China: State, Rural Society and Institutional Change Since the Great Leap Forward 相似文献
1000.
Ashok Kumar Pandey Shri Dhar Pandey Virendra Misra P. N. Viswanathan 《Chemistry and Ecology》1999,16(4):269-282
In order to investigate the role of functional groups present in humic acid(s) (HA) during complex formation, water soluble complexes between HA isolated from soil and metals (Pb, Ca, As, Ni, Cr, Co, Cu, Cd, Fe, Mn, Mg and Zn) were prepared and subjected to infrared (IR) spectroscopy. the IR data revealed the involvement of the - OH group of humic acid in complex formation with all metals except copper and arsenic, whereas the - COOH group of HA was found to be the preferred site of binding for all the metals. the significance of findings in relation to detoxification of environmental pollutants is discussed in this paper. 相似文献