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71.
72.
Thermal cracking of oils from waste plastics 总被引:2,自引:0,他引:2
Toshiro?TsujiEmail author Koji?Hasegawa Takao?Masuda 《Journal of Material Cycles and Waste Management》2003,5(2):102-106
Thermal cracking of decomposed waste plastic oil produces a good yield of olefins. The solvent extraction of such waste plastic oil seems to be efficient for increasing gas yields and recycling monomers. To assess the potential of monomer recovery from municipal waste plastics, the oils were cracked using a laboratory-scale quartz-tube reactor. The waste plastic oils were provided by two commercial plants of the Sapporo Plastic Recycle Co. and the Dohoh Recycle Center Co. in Japan. A model waste plastic oil made in a laboratory was also examined. Yields of ethene, propene, and other products were measured at different temperatures. Two-step pyrolysis reduces coking compared with the direct thermal degradation of plastics. The raffinates from waste plastic oils extracted by sulfolane were also cracked. The primary products were almost the same as those from nontreated oils. The maximum total gas yield was 78wt%–85wt% at 750°C, an increase of about 20wt% compared with that of nonextracted oil. Solvent extraction removes stable aromatic hydrocarbons such as styrene, which is more coked than cracked. 相似文献
73.
黄腐酸的萃取和性质研究 总被引:3,自引:0,他引:3
黄腐酸是腐植酸中最具活力的组成部分,蕴藏量丰富,萃取方法简便。研究了从红原1#泥炭中萃取黄腐酸和降解物。它的分子量较小,易溶于水,抗絮凝性能好,分子内含有较多的活性官能团,具有很高的化学活性和生物活性,用途广泛。 相似文献
74.
Bohan Liao Zhaohui Guo Qingru Zeng Anne Probst Jean-Luc Probst 《Water, Air, & Soil Pollution: Focus》2007,7(1-3):151-161
Leaching experiments of rebuilt soil columns with two simulated acid rain solutions (pH 4.6–3.8) were conducted for two natural
soils and two artificial contaminated soils from Hunan, south-central China, to study effects of acid rain on competitive
releases of soil Cd, Cu, and Zn. Distilled water was used in comparison. The results showed that the total releases were Zn>Cu>Cd
for the natural soils and Cd>Zn≫Cu for the contaminated soils, which reflected sensitivity of these metals to acid rain. Leached
with different acid rain, about 26–76% of external Cd and 11–68% external Zn were released, but more than 99% of external
Cu was adsorbed by the soils, and therefore Cu had a different sorption and desorption pattern from Cd and Zn. Metal releases
were obviously correlated with releases of TOC in the leachates, which could be described as an exponential equation. Compared
with the natural soils, acid rain not only led to changes in total metal contents, but also in metal fraction distributions
in the contaminated soils. More acidified soils had a lower sorption capacity to metals, mostly related to soil properties
such as pH, organic matter, soil particles, adsorbed SO4
2−, exchangeable Al3+ and H+, and contents of Fe2O3 and Al2O3. 相似文献
75.
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77.
在单因素试验、Plackett-Burman设计试验基础上,采用Box-Behnken响应面法对养殖水体中炔雌醇(EE2)的固相萃取条件进行优化。结果表明,洗脱液体积、洗脱液组成和淋洗液体积是影响EE2固相萃取回收率的3个主要因素;EE2的最佳固相萃取条件为:水样pH值为3,进样流量为3.0 mL/min,淋洗液为体积分数为10%的甲醇水溶液,淋洗液体积7.0 mL,洗脱液为乙酸乙酯-正己烷混合溶液(体积比为9∶1),洗脱液体积12.0 mL。该条件下养殖水样中EE2固相萃取回收率为81.6%~86.7%。 相似文献
78.
Abstract This paper describes the development of apparatus suitable for direct supercritical fluid extraction of organics from water. Results are presented for the extraction of pentachlorophenol present in water at concentrations of the order of 0.1 ppm. The effect of changes in apparatus design and supercritical fluid flow rate on recovery are discussed. 相似文献
79.
M. Humayoun Akhtar Louise G Croteau 《Journal of environmental science and health. Part. B》2013,48(1):117-133
Abstract A rapid, accurate, environmentally friendly and cost‐effective microwave extraction technique was developed for the extraction of spiked and incurred salmomycin from chicken tissues (kidney, liver, muscle, ovarian yolk and fat). Extraction of salinomycin from various tissues was achieved by irradiating the sample in absolute ethanol and 2‐propanol (15+2) for 9 sec. in a common household microwave oven. The extract was analysed without further cleanup by HPLC on a C18 column (5 μm) and detected at 592 nm via post‐column reaction with 4‐dimethylaminobenzaldehyde (DMABA) in a heated reactor coil at 86° C. Recoveries of salinomycin from spiked tissues at 30 ng/g level ranged between 87 and 100%. The limit of quantitation was found to be 10 ng/g. The developed method was applied for the analysis of incurred tissues and ovarian yolk of laying chickens given sodium salinomycin in feed at different levels for 14 consecutive days followed by withdrawal periods. Residues were detected in all tissues and ovarian yolk at 0 withdrawal time but declined during the withdrawal period. Highest residue were found in fat and ovarian yolk. 相似文献
80.
采用泄漏检测与维修( LDAR)技术进行了全面检测和统计分析,分析泄漏的原因并通过维修减少泄漏。结果表明:芳烃抽提装置容易泄漏的元件主要为连接件和阀门,主要分布在泵区;SV≥5000μmol/mol的泄漏密封点占总密封点数的0.57%,对总泄漏量的贡献达到了82%,是造成泄漏排放的主要部分。设备管阀件泄漏造成的加工损失率为0.0009%,泄漏点停工维修修复率为83%,停工维修后整体泄漏率为0.03%;VOCs减排率为71%。 相似文献