Experimental and theoretical studies on NO selective catalytic oxidation over α-MnO2

Based on the experimental and theoretical methods, the NO selective catalytic oxidation process was proposed. The experimental results indicated that lattice oxygen was the active site for NO oxide over the $\mathrm{\alpha }$-MnO₂(110) surface. In the theoretical study, DFT (density functional theory) and periodic slab modeling were performed on an $\mathrm{\alpha }$-MnO₂(110) surface, and two possible NO oxidation mechanisms over the surface were proposed. The non-defect $\mathrm{\alpha }$-MnO₂(110) surface showed the highest stability, and the surface O_s (the second layer oxygen atoms) position was the most active and stable site. O₂ molecule enhanced the joint adsorption process of two NO molecules. The reaction process, including O₂ dissociation and O=N-O-O-N=O formation, was calculated to carry out the NO catalytic oxidation mechanism over $\mathrm{\alpha }$-MnO₂(110). The results showed that NO oxidation over the $\mathrm{\alpha }$-MnO₂(110) surface exhibited the greatest possibility following the route of O=N-O-O-N=O formation. Meanwhile, the formation of O=N-O-O-N=O was the rate-determining step.     

东昆仑五龙沟金矿床Ⅲ矿段原生晕特征及模式

五龙沟金矿床Ⅲ矿段呈现以Au、As、Ag为主 ,伴有Pb、Zn、Cu、Bi、Sb等多元素的综合原生晕 ,其中Au、Ag、As为典型矿致异常元素组合 ,其次为Hg、Sb、Bi;Ag、As、Sb等元素为远程指示元素 ,也为矿体前缘晕和上部特征元素 ;Hg、Bi、Pb为矿体上部和中上部原生晕特征元素组合 ,也为中远程指示元素 ;Cu、Zn为矿体中部和中下部原生晕特征指示元素 ;Au在整个原生晕中均是特征直接指示元素 ;原生晕轴向分带序列为As-Sb-Ag-Bi-Pb-Hg-Au-Zn -Cu,横向分带序列为 ,矿体上部原生晕 :Au -Zn -Ag -Bi-As-Hg -Cu-Sb -Pb ;中下部原生晕 :Zn -Cu-Au -Ag -Hg-As-Pb -Sb -Bi。矿致原生晕特征为Au原生晕发育 ,平均强度大于 1 60× 1 9-9;原生晕组合复杂 ,Au、Ag、As、Sb、Hg、Bi、Zn原生晕连续性好 ,范围大于构造带 ,有内中外或外中浓度带 ,各指示元素原生晕吻合性好 ;一般在矿体 (带 )受中度剥蚀深度 (或矿体已露出 )断面上 ,Au -Ag和Au -As具正相关表现 ,相关性较好。这些特点或指标 ,可作为以蚀变岩型为主要类型金矿床的地球化学信息标志     

灾害区划研究的现状,存在问题与发展趋势

着重分析了灾害区划的现状、存在问题和发展趋势，对灾害区划的目标、原理、方法、类型及指标体系进行了深入探讨。     

Mechanical Properties with the Functional Group of Additives for Starch/PVA Blend Film

This paper deals with the mechanical properties and degree of swelling (DS) of starch/PVA blend film with the functional groups i.e., hydroxyl and carboxyl group, of additives. Starch/PVA blend films were prepared by using the mixing process. Glycerol (GL) with 3 hydroxyl group, sorbitol (SO) with 6 hydroxyl group, succinic acid (SA) with 2 carboxyl group, malic acid (MA) with 1 hydroxyl and 2 carboxyl group, tartaric acid (TA) with 2 hydroxyl and 2 carboxyl group and citric acid (CA) with 1 hydroxyl and 3 carboxyl group were used as additives. The results of measured tensile strength (TS) and elongation (%E) verified that both hydroxyl and carboxyl group as a functional groups increased the flexibility and strength of the film. Values of DS for GL-added and SA-added films were low. However, DS values of the films added MA, TA or CA with both hydroxyl and carboxyl group were comparatively high. When the film was dried at low temperature, the properties of the films were evidently improved. The reason is probably because the hydrogen bonding was activated at low temperature.     

中国洪水灾害风险区划及其成因分析

洪水灾害风险区划是洪水风险管理的基本依据.长期以来,受数据收集以及分辨率的影响,中国一直缺乏可以指导相关部门进行洪水风险控制及洪水保险的洪灾风险区划.本文利用地理信息系统软件的空间分析模块,基于高分辨率（90m）的全国降雨、地形坡度、河流湖泊缓冲区、人均GDP、人口密度、道路密度和耕地密度等影响水灾发生的风险因子图,采用水灾成因分析法和经验系数法,得到洪水的潜在危险区和经济易损区,进而得到中国洪水灾害风险区划.在此基础上,采用逐步回归法,逐步剔除各影响因子后,对引发洪灾的主要外在驱动力进行了分析.     

昆明-楚雄-大理-丽江地区地震软风险区划实例

应用云南省昆明市、楚雄州、大理州、丽江市1900—2000年这100年内M≥5．0的地震记录资料，对该地区的地震灾害软风险区划进行了实例分析。结果表明，软风险区划图是以带有“层”结构的地图形式表述风险评估结果的，而“层”是根据可能性水平来划分的。因此，软风险区划图对分析结果的表述，不仅能对风险分析提供更多的信息，而且能提供风险值可信度的信息，从而使风险图“服务信息”丰富化。     

自然灾害风险区划图的一个潜在发展方向

由于自然灾害系统的复杂性及数据资料的不完备性,人们不可能精确估计任何自然灾害发生的概率,"概率值估不准"是现有超越概率风险区划图的致命弱点.简要回顾了针对这一问题已进行的提高估计精度和进行模糊风险计算的有关研究,并将模糊风险研究引入风险区划图的编制,给出了自然灾害软风险区划图的定义和一个初步的样式.讨论了这种风险图在体现风险值估不准方面,以及在为用户提供更多风险信息,为决策者提供调整余地等方面的优点.研究结果表明,软风险区划图是自然灾害风险区划图的一个潜在发展方向.为推进这一研究领域的发展,对今后的工作提出了一些建议.     

Trait space of rare plants in a fire‐dependent ecosystem

The causes of species rarity are of critical concern because of the high extinction risk associated with rarity. Studies examining individual rare species have limited generality, whereas trait‐based approaches offer a means to identify functional causes of rarity that can be applied to communities with disparate species pools. Differences in functional traits between rare and common species may be indicative of the functional causes of species rarity and may therefore be useful in crafting species conservation strategies. However, there is a conspicuous lack of studies comparing the functional traits of rare species and co‐occurring common species. We measured 18 important functional traits for 19 rare and 134 common understory plant species from North Carolina's Sandhills region and compared their trait distributions to determine whether there are significant functional differences that may explain species rarity. Flowering, fire, and tissue‐chemistry traits differed significantly between rare and common, co‐occurring species. Differences in specific traits suggest that fire suppression has driven rarity in this system and that changes to the timing and severity of prescribed fire may improve conservation success. Our method provides a useful tool to prioritize conservation efforts in other systems based on the likelihood that rare species are functionally capable of persisting.