Purification and characterization of Al13 species in coagulant polyaluminum chloride

Nano-Al₁₃ was separated and purified by four methods to investigate its characteristic, and was analyzed by Al-Ferron timed complexation spectrophotometer,²⁷ Al-NMR (nuclear magnetic resonance), and transmission electron microscopy (TEM). Coagulation efficiency of nano-Al₁₃, polyaluminum chloride (PAC), and AlCl₃ in synthetic water were also investigated by jar test. The dynamic process and aggregation state of kaolin suspensions coagulating with nano-Al₁₃, PAC, and AlCl₃ were also investigated. The experimental results indicated that the efficiency of gel column chromatography method was the highest for separating PAC solution with low Al concentration. Ethanol and acetone method was simple and could separated PAC solution with different Al concentrations, while silicon alkylation white block column chromatography method could separate PAC solution only with low Al concentration. The SO₄²−/Ba²⁺ displacement method could separate PAC solution with high Al concentration, but extra inorganic cation and anion could be introduced into the solution during the separation. The coagulation efficiency and dynamic experimental results showed that nano- Al₁₃ with a high positive-charged species was the main species of electric neutralization in coagulation process, and it could reduce the turbidity and increase the effective particles collision rate efficiently in coagulation process. Its coagulation speed and the particle size of coagulant formed were of greatest value in this study.     

动力扰动作用下充填体的力学响应研究

稳定的充填体是二步骤矿房回采的安全保障。在采矿动力作用下实现充填体的稳定性预测,是二步开采的安全控制关键。为了研究不同扰动幅值下充填体的动力响应规律,以某矿山工程为研究对象,采用Midas/GTS与FLAC3D数值模拟技术,建立了充填体动力稳定性分析的三维数值模型并进行了数值模拟分析。研究结果表明:动力扰动作用下,充填体暴露面的破坏区域由四周逐渐向中心扩展,并随着动力扰动幅值的增加,充填体暴露面破坏区域逐渐增大直至贯通破坏;充填体暴露面质点峰值振动速度随着动力扰动峰值的增加而增加,并得出了适用于该矿充填体暴露面振动峰值速度与动力扰动幅值之间的函数关系。距动力加载面越远,充填体内部质点峰值振动速度越小,且距动力加载面0~12 m处,质点峰值振动速度衰减较慢,从12~20 m质点峰值振动速度下降趋势最为明显。     

煤巷顶板沉积岩体钻进动力响应特性试验研究

为了探究煤巷顶板锚固孔钻进动力响应指标（钻速和转速）与顶板岩石物理特性（普氏系数）间的关系,采用实验室及数值试验研究方法对煤巷顶板沉积岩体进行模拟钻进。结果表明,锚固孔的钻进动力响应指标整体上均随顶板岩石普氏系数的增加而减小,大致呈负指数关系。实验室试验数据拟合曲线与数值模拟分析所得结果较为相似,但也存在一定的差别。据此可实现对顶板岩层的初步判别,对煤巷顶板锚杆支护参数的优化和冒顶事故的预防有重要的指导意义;为实验室研究岩石的钻进试验提供了一种可行的方法,也为岩石可钻性与顶板岩层探测仪器的深入研究提供了一定的参考价值。     

基于Isograph的地铁车载ATP系统动态故障树分析

针对传统的可靠性分析方法在具有动态特性的地铁车载ATP系统可靠性分析中的不足,提出动态故障树分析法。在引用可用度、平均失效时间和平均修复时间等可靠性指标的基础上,结合Isograph软件改进动态故障树分析法,建立基于Isograph的动态故障树分析模型,并通过对车载ATP系统的结构与功能分析以及历史故障数据的统计分析确定车载ATP系统的关键部件,使用 Isograph软件预计关键部件的可靠性参数,对地铁车载ATP系统的可靠性进行评估。结果表明:采用该方法求解的系统可靠性指标均满足系统需求,并且精确度较高,运用此方法能够对具有顺序相关、资源共享、可修复以及冷、热备份等特性的系统进行可靠性建模,达到快速以及准确分析动态特性系统可靠性的目的。     

超临界CO2气爆致裂规律实验研究

针对我国低渗透性煤层增透困难的现状,研发了可控超临界二氧化碳气爆发生装 置,对不同强度的模拟煤体进行了不同温压条件下的超临界CO2气爆实验,结合孔内窥 镜观测和外观测量手段,对爆后宏观裂隙数目和长度等爆破响应信息进行统计分析。结 果表明:气爆裂纹起裂所需的最小爆破压力与介质的抗拉强度呈指数式增长的关系,主 要是固体材料在动力载荷作用下强度增大引起的;超临界二氧化碳气爆后产生宏观裂隙 的数目和累计长度与爆破压力满足Logistic函数关系,是裂隙面积超线性增加所消耗能 量也超线性增加的结果;超临界CO2对温压条件敏感,爆破有降温作用,是良好的物理 爆破原料,使用超临界二氧化碳作为爆破原料的爆破效果优于空气爆破效果。     

Integration of different environmental valuation methods to estimate forest degradation in arid and semi-arid regions

Many factors are aggravating desertification and degradation of forests such as urbanization, droughts, exploitation of natural resources and climate change. The study aims at estimating and assessing the degradation of forests in arid and semi-arid regions. This task however is complicated since the impact of the degradation will be in different forms such as loss of wood, soil erosion and lost recreational areas. Nevertheless the dynamic impact of the degradation is increasing the complexity of analysis since forest once lost is a reduction of value for all subsequent years. This study is considering the value of damages over time and it is using the concept of three environmental valuation methods to estimate the whole impact of the degradation: the habitat equivalency analysis (HEA), the productivity method and the benefit transfer method. The methods were applied to specific values of forests, depending on the best applicability, and the results combined to an overall value loss. The costs are calculated based on the year 2014 with two time horizons: 30 and 100 years. To apply the valuation approach, Jordan as an arid and semi-arid country is chosen. The result shows that the annual costs of environmental degradation of Jordanian forest areas equal about 0.14% of GDP in 2013, proving the enormous value lost to forest degradation or deforestation. The valuation approach can be transferred to other arid or semi-arid areas and stimulate forest conservation activities to prevent further degradation and to save the forest ecosystem services for the future.     

Trends in Deforestation and Forest Degradation after a Decade of Monitoring in the Monarch Butterfly Biosphere Reserve in Mexico

We used aerial photographs, satellite images, and field surveys to monitor forest cover in the core zones of the Monarch Butterfly Biosphere Reserve in Mexico from 2001 to 2012. We used our data to assess the effectiveness of conservation actions that involved local, state, and federal authorities and community members (e.g., local landowners and private and civil organizations) in one of the world's most iconic protected areas. From 2001 through 2012, 1254 ha were deforested (i.e., cleared areas had <10% canopy cover), 925 ha were degraded (i.e., areas for which canopy forest decreased), and 122 ha were affected by climatic conditions. Of the total 2179 ha of affected area, 2057 ha were affected by illegal logging: 1503 ha by large‐scale logging and 554 ha by small‐scale logging. Mexican authorities effectively enforced efforts to protect the monarch reserve, particularly from 2007 to 2012. Those efforts, together with the decade‐long financial support from Mexican and international philanthropists and businesses to create local alternative‐income generation and employment, resulted in the decrease of large‐scale illegal logging from 731 ha affected in 2005–2007 to none affected in 2012, although small‐scale logging is of growing concern. However, dire regional social and economic problems remain, and they must be addressed to ensure the reserve's long‐term conservation. The monarch butterfly (Danaus plexippus) overwintering colonies in Mexico—which engage in one of the longest known insect migrations—are threatened by deforestation, and a multistakeholder, regional, sustainable‐development strategy is needed to protect the reserve. Tendencias en la Deforestación y la Degradación de Forestal después de una Década de Monitoreo en la Reserva de la Biósfera de la Mariposa Monarca en México     

不同生态系统管理情景下资源环境承载力动态仿真研究

环境问题与社会经济发展关系机理错综复杂,研究环境承载力状态对实现区域可持续发展具有重要意义.基于资源环境复合系统原理,构建"经济-资源-环境"系统动力学模型,通过生态系统评估的4种情景时间序列动态仿真,探索经济社会发展的优化方案.结果表明：全球协同和技术家园更适合福州市自身发展需求,为保持福州市经济发展的可持续性,应优先选用全球协同发展模式,后期可逐步向技术家园发展模式转变.福州市作为生态文明思想重要实践地,在提高经济发展水平的同时,需更好地保护生态环境,实现经济-资源-环境协同发展.研究结果在一定程度上可为经济社会发展模式提供科学依据.     

流域水生态空间管控下生境监测方法概述

生境被认为是区域内为水环境中生物提供生存和生长环境的物理、化学和生物特征,是水生态空间中支持和维持生物及其生态功能的重要空间.生境特征对阐释流域生态系统的结构和功能具有重要意义.然而,生境具有空间和时间尺度的异质性以及空间自相关性,尤其是大时空尺度下其生态功能的维持具有更加复杂的机制和过程.这决定了表征和阐释生境特征是极其困难的,特别是表征大时空尺度下的特征.尽管现有研究提出诸多涉及不同尺度的生境监测方法,但对实现长期跟踪多尺度下流域生境整体变化仍缺少成熟的方法.本文从生境的概念、生境监测的目的和意义引出生境的特点及生境监测对流域水生态环境管控的重要性,归纳了主流生境监测方法的特点及主要差异,综述了生境监测中关键的科学问题（如空间尺度、区域范围、特征参数和数据信息获取方法等）,提出我国现阶段生境监测核心内容的建议,以期为流域生态空间管控下生境监测的应用和研究提供借鉴.     

基于多因素模式识别的煤与瓦斯突出预测研究

采煤工作面煤与瓦斯突出是由煤层自然条件和工程扰动共同作用决定的,充分考虑煤层原始赋存条件和人类工程活动对煤与瓦斯突出的影响,建立多因素模式识别准则和方法,应用VBA技术完成了工作面煤与瓦斯突出危险性动态预测系统开发。以平顶山十矿己15-24080工作面为研究对象,将瓦斯含量、瓦斯压力、采动应力等因素作为工作面煤与瓦斯突出的主要影响因素,运用多因素模式识别方法实现了对工作面煤与瓦斯突出危险性分单元概率预测,且能够随着工作面不断推进进行动态预测和分级管理。研究结果表明:突出危险性预测结果与现场实况有较好的一致性,对煤矿安全开采具有良好的指导作用。