首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   906篇
  免费   74篇
  国内免费   198篇
安全科学   220篇
废物处理   48篇
环保管理   140篇
综合类   491篇
基础理论   50篇
污染及防治   154篇
评价与监测   47篇
社会与环境   21篇
灾害及防治   7篇
  2024年   2篇
  2023年   11篇
  2022年   23篇
  2021年   39篇
  2020年   28篇
  2019年   24篇
  2018年   15篇
  2017年   26篇
  2016年   48篇
  2015年   35篇
  2014年   48篇
  2013年   71篇
  2012年   67篇
  2011年   59篇
  2010年   58篇
  2009年   79篇
  2008年   48篇
  2007年   62篇
  2006年   81篇
  2005年   64篇
  2004年   34篇
  2003年   54篇
  2002年   29篇
  2001年   22篇
  2000年   24篇
  1999年   26篇
  1998年   22篇
  1997年   11篇
  1996年   9篇
  1995年   14篇
  1994年   12篇
  1993年   3篇
  1992年   6篇
  1991年   3篇
  1990年   1篇
  1989年   4篇
  1987年   4篇
  1986年   1篇
  1984年   1篇
  1982年   3篇
  1981年   1篇
  1976年   1篇
  1973年   3篇
  1972年   1篇
  1970年   1篇
排序方式: 共有1178条查询结果,搜索用时 11 毫秒
61.
为了确定危险品道路运输安全容量,保障危险品道路运输安全,基于风险理念,使用对比研究方法,提出危险品道路运输个人风险基准,建立改进的危险品道路运输定量风险评估模型。结合提出的风险基准,提出危险品运输安全容量确定方法,解决了单一类别和多种类别危险品运输安全容量确定问题。研究结果表明:在某城市化工集聚区的实例应用该方法,能够大幅度降低危险品道路运输潜在生命损失,有助于保障危险品道路运输安全。  相似文献   
62.
危险废物处理技术进展及若干建议   总被引:1,自引:0,他引:1  
较系统地论述了国内固体废物的目前状况、产量,分析了一些典型危险废物处理过程中存在的主要问题和解决方法,提出了深人开展危险废物处理与资源化研究的方向,并给出了环保部门应对危险废物进行处理的建议。  相似文献   
63.
垃圾填埋场渗出液中有害成分的研究   总被引:9,自引:0,他引:9  
研究垃圾填埋场渗出液中的有害成分。渗出液样品用适当的方法处理后 ,用气相色谱 -质谱联用方法和原子发射光谱法进行定性分析。然后用原子吸收分光光度法和反相高效液相色谱法定量测定样品中微量的 Cu、Zn、Pb、Cr、Cd、Hg、苯酚、对甲苯酚、萘、蒽  相似文献   
64.
Composting was investigated as a means for safe disposal of organic waste containing bacteria that carry transgenes in recombinant plasmids. To generate model recombinant plasmids, a mobile IncQ plasmid, RSF1010, and a non-mobile plasmid, pGFP, were genetically modified to carry a DNA segment encoding both green fluorescent protein and kanamycin resistance and were designated as RSF1010-GFPK and pGFPK. Escherichia coli (E. coli) C600 harboring these plasmids were inoculated into chicken manure specimens that were placed in compost at 20 and 60 cm from the bottom of a 1.0-m high compost bin. Control specimens were held at ambient temperature. By day 10, compost temperatures at the lower and upper levels of the bin had reached 45.3 and 61.5°C, respectively, and at both levels the target E. coli had been inactivated and the plasmids had lost their capacity to be transformed or mobilized. Furthermore, based on real time Polymerase chain reaction (PCR), the transgene fragments along with the host chromosomal DNA fragment from specimens at the upper level had been degraded beyond the detection limit. However, at the lower level where temperatures remained below 48°C these fragment persisted to day 21. At ambient temperatures (0–8°C), the E. coli, plasmids and the transgene fragments persisted in manure specimens throughout the 21 day test period. The study showed the potential for composting as a safe procedure for disposal of bacteria carrying transgenes in recombinant plasmids.  相似文献   
65.
A novel sorbent based on 2% grape stalk wastes encapsulated in calcium alginate beads was investigated for the removal of Cr(VI) and Cr(III) from aqueous solutions. The sorbent proved to be efficient for chromium removal in both hexavalent and trivalent forms from aqueous solution at pH 3.0. In binary mixtures, the presence in solution of one of the forms enhances the sorption of the other which results in an increase of the amount of total chromium removed. This study suggests that the proposed sorbent can be used for the removal of chromium from wastewaters through a cost-effective and environmentally friendly process.  相似文献   
66.
区域(城市)水体中主要有机毒物的筛选   总被引:1,自引:0,他引:1  
本研究发展了区域(或城市)水体中主要有毒化学品的筛选方法。 在城市下游采集大体积水样,用CH_2Cl_2洗脱,再用有机溶剂萃取,用硅胶柱把有机物分成许多馏分,馏分最终变为水溶液。每个馏分中有机物浓度比原水大1000倍。用这种馏分水溶液进行溞的急性毒性试验和Ames试验。只对毒性大的馏分进行色谱/质谱/数据系统的鉴定和定量分析,然后根据各个化合物的急性毒性、降解难易和“三致”物质的资料及原水样中有机物的浓度资料,就可筛选出一个区域(城市)水体中的主要有毒化学品。  相似文献   
67.
水泥窑协同处置过程中Pb、Cd的挥发特性   总被引:4,自引:0,他引:4  
对铅、镉2种重金属的氧化物开展了热重实验、熟料煅烧以及熟料消解实验,以重金属的挥发率为主要指标,研究了水泥窑协同处置过程中铅、镉在等温条件下随时间的挥发特性。结果表明,2种重金属的挥发率均是随温度的升高,时间的增加而增大。Pb的挥发率为96%,Cd的挥发率达到98%,根据等温动力学及阿累尼乌斯方程,对Pb,Cd的挥发率随时间变化的规律进行动力学模拟,得到较好的线性拟合效果,其中,Pb挥发反应的表观活化能E为88.73 kJ/mol,Cd挥发反应可以分2个部分:1 200℃以下的表观活化能E为61 kJ/mol;1 250℃以上的表观活化能E为184.6 kJ/mol。  相似文献   
68.
Solid phase microextraction (SPME) is a fast, cheap and solvent free methodology widely used for environmental analysis. A SPME methodology has been optimized for the analysis of VOCs in a range of matrices covering different soils of varying textures, organic matrices from manures and composts from different origins, and biochars. The performance of the technique was compared for the different matrices spiked with a multicomponent VOC mixture, selected to cover different VOC groups of environmental relevance (ketone, terpene, alcohol, aliphatic hydrocarbons and alkylbenzenes). VOC recovery was dependent on the nature itself of the VOC and the matrix characteristics. The SPME analysis of non-polar compounds, such as alkylbenzenes, terpenes and aliphatic hydrocarbons, was markedly affected by the type of matrix as a consequence of the competition for the adsorption sites in the SPME fiber. These non-polar compounds were strongly retained in the biochar surfaces limiting the use of SPME for this type of matrices. However, this adsorption capacity was not evident when biochar had undergone a weathering/aging process through composting. Polar compounds (alcohol and ketone) showed a similar behavior in all matrices, as a consequence of the hydrophilic characteristics, affected by water content in the matrix. SPME showed a good performance for soils and organic matrices especially for non-polar compounds, achieving a limit of detection (LD) and limit of quantification (LQ) of 0.02 and 0.03 ng g−1 for non-polar compounds and poor extraction for more hydrophilic and polar compounds (LD and LQ higher 310 and 490 ng g−1). The characteristics of the matrix, especially pH and organic matter, had a marked impact on SPME, due to the competition of the analytes for active sites in the fiber, but VOC biodegradation should not be discarded in matrices with active microbial biomass.  相似文献   
69.
Lead, one of the earliest metals recognized and used by humans, has a long history of beneficial use. However, it is now recognized as toxic and as posing a widespread threat to humans and wildlife. Treatment of lead from polluted water and wastewater has received a great deal of attention. Adsorption is one of the most common technologies for the treatment of lead-polluted water. This technique was evaluated here, with the goal of identifying innovative, low-cost adsorbent. This study presents experiments undertaken to determine the suitable conditions for the use of peach and apricot stones, produced from food industries as solid waste, as adsorbents for the removal of lead from aqueous solution. Chemical stability of adsorbents, effect of pH, adsorbents dose, adsorption time and equilibrium concentration were studied. The results reveal that adsorption of lead ions onto peach stone was stronger than onto apricot stone up to 3.36% at 3 h adsorption time. Suitable equilibrium time for the adsorption was 3–5 h (% Pb adsorption 93% for apricot and 97.64% for peach). The effective adsorption range for pH in the range was 7–8. Application of Langmuir and Freundlich isotherm models show high adsorption maximum and binding energies for using these adsorbents for the removal of lead ions from contaminated water and wastewater.  相似文献   
70.
Several animal (lamb, poultry and swine) fatty wastes were pyrolyzed under nitrogen, in a laboratory scale fixed-bed reactor and the main products (liquid bio-oil, solid bio-char and syngas) were obtained. The purpose of this study is to produce and characterize bio-oil and bio-char obtained from pyrolysis of animal fatty wastes. The maximum production of bio-oil was achieved at a pyrolysis temperature of 500 °C and a heating rate of 5 °C/min. The chemical (GC–MS analyses) and spectroscopic analyses (FTIR analyses) of bio-oil showed that it is a complex mixture consisting of different classes of organic compounds, i.e., hydrocarbons (alkanes, alkenes, cyclic compounds…etc.), carboxylic acids, aldehydes, ketones, esters,…etc. According to fuel properties, produced bio-oils showed good properties, suitable for its use as an engine fuel or as a potential source for synthetic fuels and chemical feedstock. Obtained bio-chars had low carbon content and high ash content which make them unattractive for as renewable source energy.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号