全文获取类型
收费全文 | 111篇 |
免费 | 16篇 |
国内免费 | 47篇 |
专业分类
安全科学 | 15篇 |
废物处理 | 9篇 |
环保管理 | 7篇 |
综合类 | 83篇 |
基础理论 | 31篇 |
污染及防治 | 26篇 |
评价与监测 | 1篇 |
灾害及防治 | 2篇 |
出版年
2023年 | 2篇 |
2022年 | 3篇 |
2021年 | 8篇 |
2020年 | 3篇 |
2019年 | 7篇 |
2018年 | 7篇 |
2017年 | 12篇 |
2016年 | 7篇 |
2015年 | 6篇 |
2014年 | 10篇 |
2013年 | 19篇 |
2012年 | 7篇 |
2011年 | 8篇 |
2010年 | 3篇 |
2009年 | 4篇 |
2008年 | 5篇 |
2007年 | 11篇 |
2006年 | 10篇 |
2005年 | 5篇 |
2004年 | 4篇 |
2003年 | 4篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 6篇 |
1999年 | 3篇 |
1998年 | 2篇 |
1997年 | 1篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 1篇 |
1993年 | 1篇 |
排序方式: 共有174条查询结果,搜索用时 187 毫秒
71.
Yun Ma Zhiwei Li Mei Yuan Linhua Chen Shanshan Zhou 《Journal of environmental science and health. Part. B》2017,52(11):796-801
In this study, a bacterial strain, CH-1, capable of degrading 3-bromocarbazole (3-BCZ) was isolated from a polluted soil. Based on its physio-biochemical characteristics and 16S rRNA genes, strain CH-1 was identified as a Stenotrophomonas sp. Strain CH-1 was able to degrade 70% of 50 mg/L 3-BCZ within 8 d at pH 7.0 and 30°C in mineral salt medium (MSM). During the process, the main intermediate metabolite was identified as (2E, 4Z)-6-(2-amino-5-bromophenyl)-2-hydroxy-6-oxhexa-2, 4-dienoic by gas (2E, 4Z)-6-(2-amino-5-bromophenyl)-2-hydroxy-6-oxhexa-2,4-dienoic via gas chromatograph-mass spectrometry (GC-MS) analysis. The metabolite disappeared after 14 d, suggesting that the metabolite can also be degraded by strain CH-1. 3-BCZ is a new persistent organic pollutant. This is the first report of the biodegradation of 3-BCZ. The results indicated that strain CH-1 may be a promising bacterial candidate for the bioremediation of environments polluted with polyhalogenated carbazoles (PHCs). 相似文献
72.
73.
Ni,Fe氧化物对吐氏酸废水催化臭氧化研究 总被引:7,自引:0,他引:7
用浸渍法和附着沉淀法制备了6种以Ni、Fe为活性组分,γAl2O3载体的国型催化剂,催化臭经处理难生物降解的典型染料中间体废水-吐氏酸废水。初始CODc浓度为1500mg/L左右的废水,当臭氧投加量为0.8g/L时,在活性最高的催化剂作用下,CODCr去除率大于50%,而没有催化剂作用时小于30%。 相似文献
74.
Fenton氧化-生化组合工艺处理染料中间体废水 总被引:9,自引:4,他引:9
针对染料中间体废水具有COD高、BOD5/COD低和具有生物毒性的特性,采用Fenton氧化-水解酸化-好氧组合工艺进行染料中间体生产废水的处理试验,试验结果表明:废水经Fenton氧化及水解酸化工序后,废水的BOD5/COD值由0.03升高至0.48,经好氧生化工序处理后的出水COD和BOD5浓度分别达122.6 mg/L和54.6 mg/L,符合《污水综合排放标准》(GB8978-1996)二级标准,该组合工艺COD总去除率达94%. 相似文献
75.
代谢产物积累对二氯甲烷生物降解的影响 总被引:1,自引:0,他引:1
研究了代谢调节产物(NaCl)浓度积累对生物法降解二氯甲烷效率的影响。试验表明,一定浓度的NaCl对二氯甲烷降解菌(GD11)的生长有不同程度的抑制作用。摇瓶试验中NaCl对二氯甲烷降解菌的抑制浓度为35.1g/L;当空塔气速91.7m/h、二氯甲烷进口浓度2.02g/m3、温度28.5℃、循环液流量0.06m3/h、pH值6.5~7.5时,生物滴滤塔中NaCl对二氯甲烷降解菌的抑制浓度为23.4g/L,两者相比有一定差异。NaCl浓度对生物膜的厚度有一定影响,这从侧面反映了NaCl浓度对微生物活性的影响。 相似文献
76.
Haifeng Zhang Klaus Guenther Sebastian Zuehlke 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1904-1910
The degradation of a chiral nonylphenol isomer, 4-(1-ethyl-1,4-dimethylpentyl)phenol (NP112), in two agricultural soils from Monheim and Dortmund, Germany has been studied. The degradation of NP112 and the formation of a nitro-nonylphenol metabolite were determined by means of GC-MS analysis. The degradation followed bi-exponential order kinetics, with half-life of less than 5 days in both soils. The nitro-metabolite was found at different concentration levels in the two soils. The nitro-metabolite of NP112 was more persistent than its parent compound. After 150 days about 13% of the initially applied NP112 remained in the Monheim soil as its nitro-metabolite. Results of the E-screen assay revealed that the nitro-NP112 has oestrogenic potency of 85% of that of NP112. Furthermore, the results of chiral GC-MS analysis revealed that no chiral degradation of NP112 occurred in this study. 相似文献
77.
Hong Li Yuli Yuan Chensi Shen Yuezhong Wen Huijun Liu 《Journal of environmental science and health. Part. B》2013,48(4):288-292
Enantioselectivity in the toxicity and degradation of the herbicide dichlorprop-methyl (2,4-DCPPM) in algal cultures was studied. Enantioselectivity was clearly observed in the toxicity of racemic 2,4-DCPPM and its two enantiomers. R-2,4-DCPPM showed low toxicity to Chlorella pyrenoidosa and Chlorella vulgaris, but higher toxicity to Scenedesmus obliquus. The observed toxicity was ranked: R-2,4-DCPPM > S-2,4-DCPPM ? Rac-2,4-DCPPM; the toxicity of R-2,4-DCPPM was about 8-fold higher than that of Rac-2,4-DCPPM. Additionally, 2,4-DCPPM was quickly degraded, in the initial 12 h, and different algae cultures had different enantioselectivity for the 2,4-DCPPM enantiomers. There was no significant enantioselectivity for 2,4-DCPPM in Chlorella vulgaris in the initial 7 h. However, racemic 2,4-DCPPM was degraded by Scenedesmus obliquus quickly, in the initial 4 h, much quicker, in fact, than the S- or R-enantiomers (racemate > R- > S-), indicating that the herbicide 2,4-DCPPM was absorbed enantioselectively by Scenedesmus obliquus. The rapid formation of 2,4-DCPP suggested that 2,4-DCPPM adsorbed by algal cells was catalytically hydrolyzed to the free acid, a toxic metabolite. The production rates of 2,4-DCPP were as follows: Scenedesmus obliquus > Chlorella pyrenoidosa > Chlorella vulgaris, consistent with the degradability of 2,4-DCPPM. Scenedesmus obliquus had quick, but different, degradative and uptake abilities for R-, S-, and Rac-2,4-DCPPM. The R- and S- enantiomers were not hydrolyzed in the first 12 h, while both enantiomers were hydrolyzed slowly after that. These results indicate that some physical and chemical properties of compounds are of importance in determining their enantioselective toxicity and degradation. The ester and its metabolite likely played an important role in enantioselective toxicity to the three algae. 相似文献
78.
79.
80.
Kevin C. Gough Shila Jarvis Ben C. Maddison 《Journal of environmental science and health. Part. B》2013,48(7):581-589
This paper describes the isolation of monoclonal antibodies and the development of competitive immunoassays to pesticide metabolites of the fungicides imazalil, carbendazim and thiabendazole. The metabolite specific hydroxyl residues were used as the reactive group with which to link the metabolite to the carrier proteins Keyhole Limpet Haemocyanin (KLH) and Bovine Serum Albumin (BSA). In each case immune responses in mice were raised and monoclonal antibodies were produced. Antibodies were developed into competitive ELISAs to the appropriate metabolite. The antibody raised to a metabolite of imazalil was optimised into a competitive ELISA format which had an assay IC50 of 7.5 μg/L and a limit of detection (LOD) of 1.1 μg/L. A single antibody isolated against the metabolite of carbendazim had assay IC50s of 3.2 and 2.7 μg/L for the metabolites of carbendazim and thiabendazole respectively with an LOD of 0.38 μg/L for both. These sensitive immunoassays may have application in the monitoring of human exposure to these fungicide residues either by occupational or non-occupational routes. 相似文献