离子液体对废旧印刷线路板中铜、锌、铅的浸出规律

以离子液体1-丁基磺酸-3-甲基咪唑三氟甲烷磺酸盐([BSO_3HMIm]OTf)为浸出剂,初步研究了WPCBs浸铜过程中锌和铅浸出率的影响因素。实验结果表明:铜、锌的浸出率随着WPCBs粒径的减小、H_2O_2溶液加入量的增大而增大,铜的浸出率随浸出温度的升高先增大后减小,锌的浸出率受浸出温度影响不大;铅的浸出率受5种因素影响不大,且总体处于较低水平。在WPCBs粒径为0.100~0.250 mm、离子液体加入量为60.0%(φ)、H_2O_2溶液加入量为7.5%(φ)、固液比为1∶15、浸出温度为50℃的条件下,铜、锌、铅的浸出率分别为99.84%,93.25%,22.46%。     

西洋河流域污染的特征研究

随着卢龙县工业及畜牧业的发展及人口的增加，西洋河水域污染日益严重，水质功能已达到Ⅳ类，生态环境遭到严重的破坏。西洋河流域地表污染源主要有工业企业废水、畜禽养殖污水、甘薯淀粉加工废水和农业生产废水等。本文分析了西洋河流域地表水质污染的现状，在严格排查污染源的基础上对其水质特征进行了科学分析。     

北京大气中异戊二烯的季变化、日变化形式及影响因素研究

对2005年北京大气中异戊二烯进行了一年的观测分析。结果表明,异戊二烯体积分数年平均值为0.58×10^-9,月平均值为0.1×10^-9～1.8×10^-9,7月最高,1月最低。春、秋、冬三季,异戊二烯日变化形式呈三峰形,分别在14:00、18:00、02:00;18:00、02:00、08:00;02:00、10:00、16:00出现峰值;夏季异戊二烯体积分数日变化呈现白天高夜晚低且在14:00出现峰值。夏季异戊二烯源排放主要由生物排放控制,其日变化形式受温度、辐射影响大;春季和秋季异戊二烯源排放受汽车尾气和生物排放共同控制,其日变化形式受汽车尾气影响大,温度、辐射也有一定影响;冬季异戊二烯源排放主要由汽车尾气控制,其日变化形式主要受汽车尾气影响。不同季节北京大气中的异戊二烯体积分数日变化形式与PM_2.5浓度日变化形式大致相同。     

石油石化企业温室气体清单编制简析

文章通过简要阐述石油石化企业温室气体清单的编制全过程,确定石油石化企业温室气体排放种类、识别主要温室气体排放源、列举重点生产过程中温室气体排放量的核算方法,为石油石化企业实现温室气体减排和控制工作、为完成国务院规定的到2020年我国单位国内生产总值二氧化碳排放强度比2005年下降40%~45%的约束性指标,奠定数据理论基础。     

Ionic dye adsorption by zinc oxide nanoparticles

The adsorption behaviour of Basic Red 12, Acid Orange 7 and Acid Blue 1 on zinc oxide nanoparticles (ZNP) has been investigated to understand the physicochemical process involved and to explore the possible use of nanoparticles in the treatment and management of textile waste matter. The dye removal capacity of ZNP towards Basic Red 12, Acid Orange 7 and Acid Blue 1 was found to be 15.64, 6.78 and 6.38 mg g^?1, respectively. The adsorption process was pH dependent and optimum pH values of 9.0, 2.0 and 4.0 were obtained for Basic Red 12, Acid Orange 7 and Acid Blue 1, respectively. Equilibrium was established after 1.0 h for all dyes. Langmuir, Freundlich and Temkin isotherm models were applied to the system. The adsorbent ZNP was characterised using scanning electron microscopy (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) and Fourier transform infrared (FTIR) techniques. SEM analysis revealed the noticeable nanoporous morphology of the material. The results of FTIR spectroscopy showed that the process is driven by an electrostatic complexation mechanism. XRD studies revealed the nanocrystalline structure of ZNP. BET surface area measurement suggested a high pore volume and large surface area for the adsorbent. The kinetic measurements suggested pseudo-second-order kinetic processes with high regression coefficients and smaller standard error of estimate values and lower residual sum of squares. The thermodynamic measurements suggested that all processes were exothermic and accompanied by negative values for Δ G⁰, Δ S⁰ and Δ H⁰.     

基于MapX的污染源普查GIS软件开发实例

污染源普查数据面广量大,且含有准确的地理信息,但国家统一开发的普查数据应用软件中没有集成GIS分析功能。东台市环保局在对污染源普查数据的应用中,以Delphi为编程工具,调用污染源普查数据库,基于MapX实现了一款简易的污染源普查GIS应用软件,介绍了MapX特点及其应用、数据接口方法及系统的实现等。     

Importance of Sediment–Water Interactions in Coeur d’Alene Lake,Idaho, USA: Management Implications

A field study at Coeur dAlene Lake, Idaho, USA, was conducted between October 1998 and August 2001 to examine the potential importance of sediment–water interactions on contaminant transport and to provide the first direct measurements of the benthic flux of dissolved solutes of environmental concern in this lake. Because of potential ecological effects, dissolved zinc and orthophosphate were the solutes of primary interest. Results from deployments of an in situ flux chamber indicated that benthic fluxes of dissolved Zn and orthophosphate were comparable in magnitude to riverine inputs. Tracer analyses and benthic-community metrics provided evidence that solute benthic flux were diffusion-controlled at the flux-chamber deployment sites. That is, effects of biomixing (or bioturbation) and ground-water interactions did not strongly influence benthic flux. Remediation efforts in the river might not produce desired water-quality effects in the lake because imposed shifts in concentration gradients near the sediment–water interface would generate a benthic feedback response. Therefore, development of water-quality models to justify remediation strategies requires consideration of contaminant flux between the water column and underlying sediment in basins that have been affected by long-term (decadal) anthropogenic activities.     

新疆城市集中饮用水源地水质状况调查评价

随着经济社会的发展和人民生活水平的提高,人们对饮用水水质要求也日益关注,但目前城市饮水中普遍存在着水源不足、水污染、安全保障措施薄弱、应急能力低等诸多问题,加强城市饮用水水源地环境保护已经刻不容缓.对饮用水水源地水质状况调查评价为进一步查清我区城市水源地的水质现状、水源保护区内存在的环境问题以及污染源现状,科学制定饮用水水源地保护和管理对策和保障措施提供依据,并为后续饮用水源地环境保护规划工作奠定基础.     

新疆能源消费领域节能潜力分析

以2005年为基准年,根据统计数据和发展目标分析了“十一五”期间新疆能源消费领域的节能潜力.结果显示,新疆万元GDP、万元工业增加值能耗均远高于全国水平,能源消费领域节能潜力为4 557.33×10^4t标准煤;石油加工、炼焦及核燃料加工业,石油和天然气开采业,电力、热力的生产和供应业,黑色金属冶炼及压延加工业,非金属矿物制品业,建筑节能,化学原料及化学制品制造业是新疆节能潜力较大的领域,且节能潜力依次减小,总节能潜力达3 348.48×10^4t标准煤;上述这些行业和领域内能耗均较高,建筑节能在节约资源的同时减少城市大气污染,是节能的优先领域.     

煤矿危险源辨识与多层评价分级研究

根据煤炭系统生产的复杂特点,提出了采用系统科学的方法,对煤炭生产进行系统的单元划分,采用安全系统科学辨识的方法对危险源进行辨识.在此基础上,提出利用层次分析法和模糊动态评判的方法对危险源进行初次分级,根据危险源的耦合特性,提出二次动态分级的方法,对初次分级进行调整,确定危险源科学、合理的级别,并提出了进一步现实性评价的建议.