全文获取类型
收费全文 | 1235篇 |
免费 | 130篇 |
国内免费 | 698篇 |
专业分类
安全科学 | 180篇 |
废物处理 | 120篇 |
环保管理 | 96篇 |
综合类 | 1113篇 |
基础理论 | 210篇 |
污染及防治 | 294篇 |
评价与监测 | 42篇 |
社会与环境 | 5篇 |
灾害及防治 | 3篇 |
出版年
2024年 | 2篇 |
2023年 | 19篇 |
2022年 | 58篇 |
2021年 | 66篇 |
2020年 | 59篇 |
2019年 | 58篇 |
2018年 | 64篇 |
2017年 | 72篇 |
2016年 | 73篇 |
2015年 | 111篇 |
2014年 | 124篇 |
2013年 | 124篇 |
2012年 | 159篇 |
2011年 | 123篇 |
2010年 | 99篇 |
2009年 | 127篇 |
2008年 | 69篇 |
2007年 | 117篇 |
2006年 | 112篇 |
2005年 | 60篇 |
2004年 | 61篇 |
2003年 | 59篇 |
2002年 | 43篇 |
2001年 | 35篇 |
2000年 | 29篇 |
1999年 | 31篇 |
1998年 | 21篇 |
1997年 | 17篇 |
1996年 | 20篇 |
1995年 | 9篇 |
1994年 | 16篇 |
1993年 | 7篇 |
1992年 | 2篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 4篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1979年 | 2篇 |
1978年 | 1篇 |
排序方式: 共有2063条查询结果,搜索用时 250 毫秒
901.
采用酸浸法处理高硅铁尾矿,制备工业原料Fe2O3和SiO2微粉.最佳工艺条件为:反应温度100℃,反应时间90 min,铁尾矿中位粒径6.19 μm,盐酸体积分数60%.在上述最佳条件下,制备的SiO2产率(所得产品中SiO2的质量占原铁尾矿中SiO2质量的比例,下同)达98.2%,品质达到YB/T 115-2004《... 相似文献
902.
903.
复杂山区地形高含硫气井安全防护距离研究 总被引:2,自引:1,他引:1
通过对国内某重大高含硫井喷事故进行调查,采用大涡模拟方法对3口井井喷气体扩散进行模拟,计算不同风速风向在事故中造成的灾难后果,得出地形因素对于灾难的影响。通过计算不同浓度下的扩散距离,提出分析及计算安全防护距离的方法。根据计算结果的综合分析可以看到,其浓度扩散的最远距离位于带状分布以内。 相似文献
904.
《环境科学学报(英文版)》2023,35(3):544-552
Ammonia nitrogen (NH4+-N) is a ubiquitous environmental pollutant, especially in offshore aquaculture systems. Electrochemical oxidation is very promising to remove NH4+-N, but suffers from the use of precious metals anodes. In this work, a robust and cheap electrocatalyst, iron single-atoms distributed in nitrogen-doped carbon (Fe-SAs/N-C), was developed for electrochemical removal of NH4+-N from in wastewater containing chloride. The Fe-SAs/N-C catalyst exhibited superior activity than that of iron nanoparticles loaded carbon (Fe-NPs/N-C), unmodified carbon and conventional Ti/IrO2-TiO2-RuO2 electrodes. And high removal efficiency (> 99%) could be achieved as well as high N2 selectivity (99.5%) at low current density. Further experiments and density functional theory (DFT) calculations demonstrated the indispensable role of single-atom iron in the promoted generation of chloride derived species for efficient removal of NH4+-N. This study provides promising inexpensive catalysts for NH4+-N removal in aquaculture wastewater. 相似文献
905.
Po Neng Chiang Ming Kuang Wang Pan Ming Huang Jeng Jong Wang 《Journal of environmental radioactivity》2010,101(6):472-481
The dynamics of Cs and Sr sorption by soils, especially in the subtropics and tropics, as influenced by soil components are not fully understood. The rates and capacities of Cs and Sr sorption by selected subtropical and tropical soils in Taiwan were investigated to facilitate our understanding of the transformation and dynamics of Cs and Sr in soils developed under highly weathering intensity. The Langmuir isotherms and kinetic rates of Cs and Sr sorption on the Ap1 and Bt1 horizons of the Long-Tan (Lt) and the A and Bt1 horizons of the Kuan-Shan (Kt), Mao-Lin (Tml) and Chi-Lo (Cl) soils were selected for this study. Air-dried soil (<2 mm) samples were reacted with of 7.5 × 10−5 to 1.88 × 10−3 M of CsCl (pH 4.0) or 1.14 × 10−4 to 2.85 × 10−3 M of SrCl2 (pH 4.0) solutions at 25 °C. The sorption maximum capacity (qm) of Cs by the Ap1 and Bt1 horizons of the Lt soil (62.24 and 70.70 mmol Cs kg−1 soil) were significantly (p < 0.05) higher than those by the A and Bt1 horizons of the Kt and Cl soils (26.46 and 27.49 mmol Cs kg−1 soil in Kt soil and 34.83 and 29.96 mmol Cs kg−1 soil in Cl soil, respectively), however, the sorption maximum capacity values of the Lt and Tml soils did not show significant differences. The amounts of pyrophosphate extractable Fe (Fep) were correlated significantly with the Cs and Sr sorption capacities (for Cs sorption, r2 = 0.97, p < 1.0 × 10−4; for Sr sorption, r2 = 0.82, p < 2.0 × 10−3). The partition coefficient of radiocesium sorbed on soil showed the following order: Cl soil ? Kt soil > Tml soil > Lt soil. It was due to clay minerals. The second-order kinetic model was applied to the Cs and Sr sorption data. The rate constant of Cs or Sr sorption on the four soils was substantiality increased with increasing temperature. This is attributable to the availability of more energy for bond breaking and bond formation brought about by the higher temperatures. The rate constant of Cs sorption at 308 K was 1.39-2.09 times higher than that at 278 K in the four soils. The activation energy of Cs and Sr sorbed by the four soils ranged from 7.2 to 16.7 kJ mol−1 and from 15.2 to 22.4 kJ mol−1, respectively. Therefore, the limiting step of the Cs+ or Sr2+ sorption on the soils was diffusion-controlled processes. The reactive components, which are significantly correlated with the Langmuir sorption maxima of Cs and Sr by these soils, substantially influenced their kinetic rates of Cs and Sr sorption. The data indicate that among components of the subtropical and tropical soils studied, short-range ordered sesquioxides especially Al- and Fe-oxides complexed with organics play important roles in influencing their capacity and dynamics of Cs and Sr sorption. 相似文献
906.
5种铁氧化物去除As(V)性能的比较研究 总被引:8,自引:1,他引:7
为了从铁氧化物中筛选得到潜在经济有效的除砷材料,对5种铁氧化物去除As(V)的性能进行了比较研究。吸附实验结果表明,其吸附容量依次为施氏矿物四方纤铁矿水铁矿赤铁矿针铁矿,其吸附过程均符合准二级动力学,约24 h时吸附达到平衡。其中,pH=5时,施氏矿物的吸附容量达到83 mg/g。分别投加500 mg/L和300 mg/L的施氏矿物,可将含砷1.484 mg/L和0.850 mg/L、高TOC含量和高pH特征的模拟配水砷浓度降至0.01 mg/L以下。鉴于施氏矿物良好的吸附除砷性能,进一步通过SEM、FTIR和电位滴定对其表面特性进行了深入研究,结果显示,本研究中制备的施氏矿物存在结构性或表面吸附的SO42-,其(质子)表面位密度约为4.32个/nm2,表面质子化常数pK1为4.60,pK2为-8.98。 相似文献
907.
The aims of this study were (a) to evaluate the degradation of acetamiprid with the use of Fenton reaction, (b) to investigate the effect of different concentrations of H2O2 and Fe2+, initial pH and various iron salts, on the degradation of acetamiprid and (c) to apply response surface methodology for the evaluation of degradation kinetics. 相似文献
908.
研究Fe/Cr6+比值和不同浓度的NO3-、Cl-和SO42-对金属铁去除Cr6+效果的影响。结果表明,金属铁对水中Cr6+有很好的还原去除效果;当金属铁的使用量为Cr6+量的1/2 000时,铁对Cr6+的去除效果较差且易失去活性,而当金属铁的使用量为Cr6+量的8 000倍时,铁对Cr6+的去除效果较好且其活性的持续性较强;3种阴离子(NO3-、Cl-和SO42-)均能提高金属铁对重金属Cr6+去除率,但在反应初期,3种阴离子对金属铁去除水中Cr6+影响的差异性不显著,随着反应时间的增加,SO24-对金属铁去除水中Cr6+的促进作用逐渐强于Cl-和NO3-,3种阴离子对金属铁去除Cr6+效率促进作用的大小顺序为SO24-〉Cl-〉NO3-。 相似文献
909.
910.
铁碳布空气阴极微生物燃料电池的产电性能 总被引:1,自引:1,他引:0
使用铁代替铂作为阴极催化剂,制作含铁碳布空气阴极并构建单室MFC(Fe-C-ACMFC)。以乙酸钠为燃料,通过稳态放电法和循环伏安测试等测试手段,分析了不同铁含量对Fe-C-ACMFC产电性能的影响以及性能最优Fe-C-ACM-FC的连续运行稳定性。结果表明,随着铁含量的增加,Fe-C-ACMFC启动期开路电压(OCV)逐步提高,达到峰值后,随着铁含量的增加而降低;同样,Fe-C-ACMFC极化性能和功率密度等产电性能也随铁含量的增加先升高再降低;当铁含量为0.7 mg/cm2时,MFC的产电性能最优,最大开路电压为593 mV,表观内阻为89Ω,最大功率密度达到12 907 mW/m3,并且经循环伏安测试,电池放电容量几乎没有变化,表明Fe-C-ACMFC的性能比较稳定,能够长期运行。由于铁催化剂价格远远低于铂催化剂,因此,铁碳布空气阴极MFC更利于推广应用。 相似文献