海域岩土工程勘察施工工艺

海域岩土工程勘察因受风浪、潮汐、定位等因素影响,与陆地勘察相比,施工工艺差异较大。本文以深圳西港区(位于珠江口)某航道工程为例,详细介绍其施工工艺,以期对海域勘察工程实施有一定的参考意义。     

鞍山市双岭水泥厂污染状况调查及环境影响防治对策

通过对鞍山市双岭水泥厂污染源及周边环境的调查监测，搞清污染物的主要来源、厂区周边空气环境的质量，并评价了该厂对周边环境的影响。     

油品罐区安全隐患分析及防范

通过对炼油厂油品罐区消防、安全设施进行分析和改进，消除其对罐区的危害；对油罐主体腐蚀及加热器泄漏进行深入分析并提出实用的改进措施；完善生产与安全双重控制系统，为油品罐区标准化改造创造条件。     

浅谈水体中硫化物保存、分离和测定方法的选择

水体中的硫化物是环境监测和工厂验收监测的一个重要参数.由于水中硫化物的不稳定性和水体中的干扰物质较多,保存常用技术为醋酸锌-氢氧化钠保存技术,但由于测定的手段不同,可根据不同的测定方法选用不同的保存和分离技术.比色法和碘量法时选用锌盐保存技术,分离技术有吹气分离、负压抽气分离或酸性溶液加锌产生氢气分离,选用不同的吸收液后测量;用间接测定技术时,可选用不同的金属盐进行沉淀后测定金属离子;选用电化学方法测定时,可选用使用于电化学的保存技术.为了准确地测定水体中的硫化物,宜选择最好的保存技术、分离技术和测定方法,并且必须使保存技术和测定方法相匹配,获得完善的监测技术和准确的监测结果.     

扩散器近区稀释扩散模型试验研究

通过模型试验，全面研究扩散器的水平方位角、射流角度、长度、环境水深、射流速度等主要设计参数对污水近区稀释扩散的影响。为扩散器设计提供技术支持和参考依据。     

Synergistic effect of F and triggered oxygen vacancies over F-TiO2 on enhancing NO ozonation

Oxidation-absorption technology is a key step for NO_x removal from low-temperature gas. Under the condition of low O₃ concentration (O₃/NO molar ratio = 0.6), F-TiO₂ (F-TiO₂), which is cheap and environmentally friendly, has been prepared as ozonation catalysts for NO oxidation. Catalytic activity tests performed at 120°C showed that the NO oxidation efficiency of F-TiO₂ samples was higher than that of TiO₂ (about 43.7%), and the NO oxidation efficiency of F-TiO₂-0.15 was the highest, which was 65.3%. Combined with physicochemical characteristics of catalysts and the analysis of active species, it was found that there was a synergistic effect between F sites and oxygen vacancies on F-TiO₂, which could accelerate the transformation of monomolecular O₃ into multi-molecule singlet oxygen (¹O₂), thus promoting the selective oxidation of NO to NO₂. The oxidation reaction of NO on F-TiO₂-0.15 follows the Eley-Rideal mechanism, that is, gaseous NO reacts with adsorbed O₃ and finally form NO₂.     

Distribution characteristics of ammonia-oxidizing bacteria in the Typha latifolia constructed wetlands using fluorescent in situ hybridization(FISH)

A molecular biology method, fluorescent in situ hybridization（FISH）, in which the pre-treatment was improved in allusion to the media of the constructed wetlands（CW）, e.g. the soil and the grit, was used to investigate the vertical distribution characteristics of ammonia-oxidizing bacteria（AOB） quantity and the relation with oxidation-reduction potential（ORP） in the Typha latifolia constructed wetlands under three different Ioadings in summer from May to September. Results showed that the quantity of the AOB decreased in the Typha latifolia CW with the increase of vertical depth. However, the AOB quantity was 2-4 times the quantity of the control in the root area. Additionally, ORP in the rhizosphere was found to be higher than other areas, which showed that Typha latifolia CW was in an aerobic state in summer when using simulated non-point sewage at the rural area of Taihu Lake in China and small town combined sewage.     

PO4^3-和柠檬酸对稀土元素在小麦体内积累和分异的影响

基于营养液培养,添加外源稀土和ICP-MS分析技术,研究了无机配体PO43-(Pi)及有机配体柠檬酸(Cit)对小麦器官中稀土元素积累和分异的影响.结果表明,不同Pi水平对小麦根中的稀土总含量(∑REE)影响较小,但显著降低叶中∑REE含量;而不同Cit水平对小麦根、叶中∑REE含量都有明显降低作用.对照植物(无Pi、Cit添加)中,稀土元素在小麦根中具有中稀土(MREE)富集及M-型四重效应分布特征,叶中有重稀土(HREE)富集及W-型四重效应分布特征.不同Pi处理对四重效应无明显作用,但进一步加强HREE在小麦叶片中的富集.添加柠檬酸使对照植物根和叶中的分异有逐渐减弱的趋势,在高浓度处理时(Cit≥150μmol.L-1),小麦根和叶中出现轻稀土(LREE)富集.     

海水中氰化物测定方法探讨

对应用异烟酸 吡唑啉酮分光光度法测定海水中氰化物的方法进行了补充和改进,提高了海水氰化物测定方法的精密度和准确度。     

取代苯类化合物的二维息定量结构-活性相关研究

为了预测非反应性麻醉型化合物对发光菌的发光半抑制浓度,评价该类化合物的毒性效应,采用独特的二维HQSAR分析方法,根据分子碎片的类型,将分子结构转变成具有特征的分子指纹,并用数字进行标记。这些标记出的数字作为QSAR的描述符,经过偏最小二乘法计算,建立起化合物结构与生物毒性之间的相关关系,由此所获得的HQSAR预测值与实测值之间也存在较好的相关性,即-1g_(pre)EC_(50)=0.311 0.929(-1g_(exp)EC_(50))(n=13,r=0.964)。这一模型的预测效果明显优于传统的二维QSAR模型,其结果可以为定量评估同类化合物的生物毒性提供可靠依据。