垃圾填埋场渗出液中有害成分的研究

研究垃圾填埋场渗出液中的有害成分。渗出液样品用适当的方法处理后 ,用气相色谱 -质谱联用方法和原子发射光谱法进行定性分析。然后用原子吸收分光光度法和反相高效液相色谱法定量测定样品中微量的 Cu、Zn、Pb、Cr、Cd、Hg、苯酚、对甲苯酚、萘、蒽     

Preliminary air pollution monitoring in San Miguel, Buenos Aires

Passive diffusion samplers were employed in San Miguel(Buenos Aires Metropolitan Area) for a preliminary airpollution monitoring. The highest loads were observedin downtown, compared with an urban background site.Total suspended particulate matter (TSPM) varied from0.257 to 0.033 mg cm^-2 month^-1; dust was examinedfor particle nature and size distribution. A similartrend was observed for nitrogen dioxide (NO₂) andTSPM spatial distribution, suggesting that traffic isthe major pollution source. Sulphur dioxide (SO₂)values were low and rather homogeneous. Levels for theinvestigated pollutants are below EPA's guide linevalues. Geographic (flat area, near to Rio de LaPlata) and climatologic factors (rainfalls andvariable wind directions) contribute to disperse pollutants.     

A Global Overview of Atmospheric Acid Deposition Fluxes

This paper presents a summary of globalacid deposition flux data taken from a globalassessment report on acid deposition prepared forUNEP/WMO (Whelpdale and Kaiser, 1996). There is a largevariation in the spacial coverage and reliability ofmonitoring around the world. Many more stationsmeasure wet deposition than collect appropriate datafor estimating dry deposition. The widespread regionswith highest precipitation concentrations anddeposition fluxes of sulphate and nitrate coincideclosely with the regions of highest density ofSO₂ and NO_x precursor emissions occurringprimarily in the mid-latitude, northern hemispherebelt where a large fraction of the worlds fossilfuels is consumed. Organic acids in precipitation makea minor contribution to acidity (<20%) inindustrial regions, but in the rest of the world theyare of same order, or even exceed, inorganic acids.Less is known about dry deposition, but it appears topredominate near strong emission sources with wetdeposition predominating farther downwind. The molarratio of the N/S contribution to acidic deposition isclose to 1.0 over large areas of Europe and NorthAmerica, but is highly variable elsewhere, beinghighest in equatorial regions due to biomass burningand lowest near smelters and other large sources of SO₂.     

An Assessment on Variation of Sulphur Dioxide and Particulate Matter in Erzurum (Turkey)

Sulphur dioxide and PM₁₀ levels are investigated in Erzurum during the periods of 1990–2000 heating season to assess air pollution level. For that reason, emissions of sulphur dioxide and particulate matter were calculated by using consumption of fuels and Turkish emission factors. These emission values were evaluated together with air pollution levels, which were measured at six stations in Erzurum atmosphere during 1990–2000 winter periods. Results reveal that in 1990–1994 heating period, there is an increasing trend in the emissions and air pollution levels over Erzurum, and the air quality limits were not met. The daily 24 h limit (short-term limit) was exceeded 127 days in 1992–1993 winter period. The reason for this increase was found to be the switching to use of low-quality fossil fuels instead of cleaner ones. Results also indicated that there was a considerable decrease in emissions of air pollutants and air pollution levels after 1995. This can be explained by the consumption of more high-quality fossil fuels. The correlation coefficient of SO₂ with PM₁₀ is obtained as r² = 0.85, which is a high value supporting the idea that both pollutants are emitted from the same source.     

若干生态农业的模式及其应用

本文根据浙江省生态农业的实践,总结出数种生态农业模式,叙述了各种模式的结构、功能、效益、特点及应用现状,提出了模式的适用对象和应用时需重点注意的问题。     

Pyrolysis of rice husk and sawdust for liquid fuel

The paper is focused on studying how to convert rice husk and sawdust into liquid fuel. Rice husk, sawdust and their mixture were pyrolyzed at the temperature between 420℃ and 540℃, and the main product of liquid fuel was obtained. The experimental result showed that the yield of liquid fuel heavily depended on the kind of feedstock and pyrolysis temperature. In the experiments, the maximum liquid yields for rice husk, sawdust and their mixture were 56% at 465 ℃, 61% at 490℃ and 60% at 475℃ respectively. Analysis with GC-MS and other apparatus indicated that the liquid fuel is a complicated organic compound with low caloric value and can be directly used as fuel oil without any up-grading. As a crude oil, the liquid fuel can be refined to be vehicle oil.     

LPWCO method for the treatment of high concentrated organic wastewater

Based on wet air oxidation (WAO) and Fenton reagent, thispaper raises a new low pressure wet catalytic oxidation(LPWCO)which requires low pressure for the treatment of highlyconcentrated and refractory organic wastewater. Compared withgeneral wet air oxidation, the pressure of the treatment(0.1-0.6MPa) is only one of tens to percentage of latter(3.5-10MPa). Inaddition, its temperature is no more than 180℃.Compared withFenton reagent, while H2O2/COD(weight ratio) less than 1.2, theremoval of COD in the treatment is over twenty percents more thanFenton's even the value of COD is more than 14000mg/L. In thispaper, we study the effect factor of COD removal and the mechanismof this treatment. The existence of synergistic effect (catalytic oxidation and carbonization) for COD removal in H2SO4-Fenton reagent system under the condition of applied pressure and heating (0.1-0.6MPa, 104-165℃) was verified. The best condition of this disposal are as follows:H2O2/COD(weight ratio)=0.2-1.0, Fe2+ 0.6×10-3 mol, H2SO4 0.5mol, COD>1×104mg/L, the operating pressure is 0.1-0.6MPa and temperature is 104-165℃. This method suit to dispose the high-concentrated refractory wastewater, especially to the wastewater containing H2SO produced in the manufacture of pesticide, dyestuff and petrochemical works.     

花岗岩类岩体与金矿床成因关系的探讨

花岗岩类岩体与金矿床存在着密切的空间联系，其成因关系一直是矿床学界争论的焦点，目前传统的岩浆热液成因观点仍居统治地位。随着地质资料的积累，高温高压实验技术，尤其是金矿床同位素定年技术的进展，传统观点受到了严峻挑战。成岩成矿的时代与时差、成矿流体的来源和成矿物质的来源等确定金矿床成因类型关键因素的综合研究表明，有密切空间关系的金矿床与花岗岩类岩体之间，在多数情况下两者并无直接的成因联系，金矿床不是岩浆热液成因，而是与大气降水或建造水有关的改造成矿作用的产物。     

滇池细菌总数与有机碳、氮、磷的调查研究

通过对滇池水体一年多的定点采样工作,重点调查研究了草海、外海表层水中细菌数量及有机营养盐碳、氮、磷的季节变化规律,分析探讨了细菌总数与环境条件和有机营养盐之间的某些关系.对滇池富营养治理提出了一些建议,并提出利用微生物学的方法参与这一研究.     

高级氧化技术机理及在水处理中的应用进展

综述了近年来发展迅速的高级氧化技术，主要包括Fenton法、臭氧氧化法、湿式氧化技术、超临界水氧化法、纳米光催化氧化法电化学催化降解法及超声降解法等。介绍了各种高级氧化技术的基本原理及在废水处理中的应用进展，并对其特点进行了评述。