Microwave-assisted regeneration of hypercrosslinked polymeric adsorbent saturated with nitrophenols

Thermal regeneration ofhypercrosslinked polymeric adsorbent （HPA） was performed at 67℃. Experiments were carried out using a multimode microwave oven operating at 2450 MHz and a thermostatic water bath so as to compare the effect of the different heating mechanisms on the regeneration efficiency of the HPA saturated with nitrophenols. The temperature rise action of the heterogeneous regeneration system under microwave irradiation was described. Additionally, a complete structure and chemical characterization of the regenerated HPA was also carried out in order to study the influence of the subsequent regeneration cycles on the structure and the adsorption capacities of the adsorbents. Structure characterization of the regenerated HPA was accomplished by means of the analysis of FTIR spectra.     

Nonylphenol photodegradation by novel ternary MIL-100（Fe）/ZnFe2O4/PCN composite under visible light irradiation via double charge transfer process

Nonylphenol（NP） residues, as a typical endocrine disrupting chemical（EDC）, frequently exist in sewage, surface water, groundwater and even drinking water, which poses a serious threat to human health due to its bioaccumulation. In order to remove NP, a series of MIL-100（Fe）/Zn Fe₂O₄/flake-like porous carbon nitride（MIL/ZC） was synthesized through in-situ synthesis at room temperature. High performance of ternary MIL/ZC is used to degrade NP under visible light irradiation. ...     

影响平板式太阳能热水器热效率诸因素的研究

本文根据辐射传热和对流传热理论,利用Ｍａｔｌａｂ 程序结合太阳能热水器本身的尺寸以及与其有关的水和空气的物理弹性详细分析了影响平板式太阳能热水器热效率的因素包括太阳能热水器表面的太阳光辐射的吸收率αｓ 和辐射系数ε,太阳能热水器的水进口温度Ｔｃ,ｉｎ和流量ｍｃ 太阳辐射能力Ｇｓ,,环境大气温度Ｔｅ,大气辐射系数εｓｋｙ 以及太阳能热水器内部的总传热系数Ｕ。分析结果表明较高的太阳照射能力、环境温度和总传热系数有利于提高集热效率,而增加水量和水进口温度、热水器辐射系数和大气辐射系数则有相反的效果。     

Degradation of nitrobenzene in wastewater by γ-ray irradiation

The degradation of nitrobenzene(NB) by γ-ray irradiation was studied. The influences of dose rate and initial NB concentration were investigated in details. At a dose rate of 55 Gy/min, the degradation kinetics was pseudo-first-order at NB concentrations from 0.2 mmol/L to 4.0 mmol/L. At an initial NB concentration of 0.8 mmol/L, the degradation of NB at various dose rates also followed pseudo-first-order kinetics. Dissolved oxygen was found to have a positive effect on NB degradation. The degradation products were identified as nitrophenol, nitrosobenzene, and hydroquinone, and so on. Based on the product analysis, possible degradation pathways of nitrobenzene were proposed.     

激光表面处理对工业级锆基块体非晶合金弯曲变形和缺口韧性的影响

目的 改善块体非晶合金的弯曲力学性能,同时考虑航空结构材料选材的经济性,研究激光表面处理工艺对工业级Zr_49.7Ti₂Cu_37.8Al₁₀Er_0.5块体非晶合金弯曲变形和缺口韧性的影响规律。方法 采用低纯原料和低真空制备条件获得工业级Zr_49.7Ti₂Cu_37.8Al₁₀Er_0.5块体非晶合金试样,考虑到弯曲条件下试样受到拉伸和压缩2种正应力状态,研究不同处理工艺和激光处理表面对试样弯曲变形和缺口韧性的影响。结果 当激光处理表面位于弯曲试样的2个侧表面时,其对试样的塑性变形能力和断裂强度没有明显的影响,但会显著降低试样的缺口韧性,从(56.4±3.4)MPa·m^1/2降低到(26.2±4.8)MPa·m^1/2;激光处理表面位于弯曲试样的受拉侧时,试样的弯曲断裂强度从2 150 MPa降低到1 800 MPa;当激光处理表面位于...     

垃圾渗沥液中有机污染物的超声去除

采用超声辐照技术去除垃圾渗沥液中的有机污染物。研究了输入电功率、初始浓度、初始pH、曝气对垃圾渗沥液中COD的超声去除效果影响,探讨了垃圾渗沥液中有机物的超声去除主要是通过羟自由基的氧化反应,高温热解反应虽然存在,但贡献相对很小。超声去除垃圾渗沥液中COD的动力学模式不能简单用动力学原理来解释,一方面由于超声降解有机物的机理和垃圾渗沥液中有机物的种类都很复杂,另一方面由于基于K2Cr2O7法测定出的COD指标不能完全表征超声去除垃圾渗沥液中有机污染物的程度。     

某尾矿坝稳定性分析与加固措施

针对某尾矿库堆积坝下游坡出现的水流高位出逸及流砂现象,对该尾矿坝进行了渗流与稳定计算,提出了渗流和稳定评价意见及可行的除险加固方案。研究内容包括:采用先进的三维激光扫描仪对尾矿坝及其附近区域进行大比例尺地形测量,现场测量堆积坝坡及干滩坡比,为数值计算提供基础地形资料;现场取尾矿砂样本,进行室内试验,包括颗粒分析、渗透性和强度参数试验等;根据下游坡出逸点高度进行渗流计算输入参数反分析,获取合理的尾矿砂渗透系数各向异性比例与坝顶垂直入渗流量;对尾矿坝现状与远期规划坝高进行6个工况的渗流与抗滑稳定分析,指出坝体处于滑动失稳临界状态,提出采用辐射井降水的排渗措施。该尾矿库采用辐射井降水后,稳定安全系数提高至1.7以上,坝体下游坡水流高位出逸和流砂管涌现象已基本消除。