排序方式: 共有46条查询结果,搜索用时 140 毫秒
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在PH3生物净化体系中添加呼吸链电子传递抑制剂,对比分析微生物生长代谢、磷的迁移转化、活性氧(ROS)产生及氧化酶活性等变化规律.当鱼藤酮或抗霉素A分别添加至R1、R2PH3生物反应器后,其微生物体O2-·含量在运行时间14~17d期间的平均值分别上升至0.68,0.96mmol/g,明显高于空白对照组R0反应器.除自由基O2-·外,另一类型的活性氧HO·也存在于PH3净化系统中;受累积的活性氧影响,生物体内丙二醛(MDA)含量处于较高水平,PH3净化效率通常不超过75%,添加抑制剂的R1与R2反应体系在15~17d期间PH3平均去除率分别下降至65.1%、59.5%.pH值、ROS含量以及氧化酶活性等因素均明显影响PH3生物净化效果,当Fe3+、Cu2+、Mg2+等金属阳离子迁移转运至微生物体内时,超氧化物歧化酶(SOD)与过氧化氢酶(CATase)活性得以不同程度的增强,可缓解活性物质O2-·或HO·导致的氧化胁迫作用,PH3净化效能得以适度提升. 相似文献
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利用气相色谱-脉冲火焰光度检测器(GC-PFPD),对金普湾海域夏季表层沉积物中基质结合态磷化氢的含量及其影响因素进行了初步分析.结果表明,研究区域内沉积物中均检测到基质结合态磷化氢的存在,其含量介于62.58~190.81ng·kg-1之间,均值为114.42 ng·kg-1;并且,在近岸海域沉积物中基质结合态磷化氢的含量普遍高于远岸海域沉积物.相关数理统计分析显示,沉积物中基质结合态磷化氢与有机磷含量和碱性磷酸酶活性有显著的线性正相关(R=0.882,P=0.01;R=0.819,P=0.023),而与有机氮、无机磷含量、沉积物粒径的相关性并不显著.由此,揭示了金普湾海域沉积物中基质结合态磷化氢的累积与分布主要受有机磷化合物微生物降解作用的影响. 相似文献
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Production and emission of phosphine gas from wetland ecosystems 总被引:2,自引:1,他引:1
Chao Han Xueyuan Gu Jinju Geng Yuning Hong Rui Zhang Xiaorong Wang Shixiang Gao 《环境科学学报(英文版)》2010,22(9):1309-1311
Phosphine is a part of an atmospheric link of phosphorus cycle on earth, which could be an important pathway for phosphorus transport in environment.Wetland ecosystems are important locations for global biogeochemical phosphorus cycle.In this study, production and emission fluxes of free phosphine from four wetlands types in southern China were observed in different seasons.The results showed that the concentration of phosphine liberated from wetlands was at pg/m3-ng/m3 level.The emission concentrations of different wetlands followed the sequence:paddy field(51.83 ± 3.06) ng/m3 marsh(46.54 ± 20.55) ng/m3 lake(37.05 ± 22.74) ng/m3 coastal wetland(1.71 ± 0.73) ng/m3, the positive phosphine emission flux occurred in rice paddy field(6.67 ± 5.18) ng/(m2·hr) and marsh(6.23 ± 26.9) ng/(m2·hr), while a negative phosphine flux of(-13.11 ± 35.04) ng/(m2·hr) was observed on the water-air interface of Lake Taihu, suggesting that paddy field and marsh may be important sources for phosphine gas in atmosphere, while lake may be a sink of atmospheric phosphine gas during the sampling period.Atmospheric phosphine levels and emission flux from Yancheng marsh and rice paddy field varied in different seasons and vegetational zones.Both diffusion resistance in aqueous phase and temperature were dominating factors for the production and transportation of phosphine to atmosphere. 相似文献
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以自制介孔碳(MC)为吸附剂,采用吸附—电-臭氧-UV再生组合工艺将难降解有机磷三(2-羧乙基)膦(TCEP)富集后转化为磷酸盐释放,为后续磷回收提供基础。运用TEM,SEM,XRD等技术对MC进行了表征。表征结果显示,MC为碳纳米线堆积有序介孔结构,比表面积为699.76 m2/g,可为有机磷提供吸附位点。在吸附温度为298 K、TCEP初始质量浓度为100 mg/L、吸附剂投加量为1 g/L的条件下,MC对TCEP的平衡吸附量为33.72 mg/g。利用电-臭氧-UV对MC进行再生,总磷释放率可达100%,并基本矿化为磷酸盐,再生效率显著高于臭氧、臭氧-H2O2、臭氧-UV等方法。 相似文献