环境监测实验室废液的管理与处理方法

环境监测实验室的废液处理常常被忽视,提出建立有效的废液管理制度的必要性.有针对性地介绍了环境监测实验室中常见废液的处理方法.     

粗苯污染事故应急处理

针对一次苯泄漏事故的应急处理过程、方法进行论述与总结，并分析了事故现场周围地表、地下水中苯污染浓度的变化情况，提出了该类事故的应急措施，以此作为处理同类事故的参考和依据。     

混凝沉淀用于铬鞣废液处理方法的探讨

对制革生产废水中的铬鞣废液的处理方法进行了探讨，通过投加处理效率高且费用低廉的混凝剂提高废水中铬的去除效率，并最终应用于实际工程中，取得了良好的效果。     

消泡剂硅油I在工业废水氨氮测定中的应用

对色泽较深，含杂质量较高的废水加硅油I以抑制测定中蒸馏产生的泡沫．结果表明，在250ml水样中加硅油IO．10～1．25ml，即可收到理想效果．硅油I性质稳定，不随水蒸汽蒸出，对测定无干扰．     

上海部分城市污水处理厂现状调查

对上海市部分城市水污水处理厂的工艺特点，处理能力，污染物去除率，废水排放达标率进行了调查与分析，指出，必须加强对城市污水处理厂的监督监测，并就污水处理厂的建设，改造提出了一些建议。     

气相色谱-质谱法测定废酸油渣中的16种多环芳烃

建立了废酸油渣中16种多环芳烃超声萃取、Florisil萃取柱净化、气相色谱-质谱测定的方法。笔者对提取方式、提取剂类型和体积、提取时间和次数、净化方式等进行研究,采用无水硫酸钠分散,二氯甲烷作为提取剂超声40 min,提取液经纯水清洗、离心后取适量有机相经过3 g Florisil萃取柱净化,采用气相色谱-质谱选择离子模式(SIM),加入内标进行定量分析。结果表明:二氯甲烷提取效率比正己烷好,丙酮可能引起酸性样品中多环芳烃的降解,丙酮超声萃取时加入无水硫酸钠能在一定程度上防止目标物降解,但萃取效率不可控制,宜采用二氯甲烷作为萃取剂。分散提取能有效减少提取时间,超声清洗仪超声40 min提取效率为86.2%～104%。3g Florisil萃取柱净化比1 g Florisil萃取柱净化和GPC净化效果略好。方法检出限为0.4～1.3 mg/kg,6次空白加标的相对标准偏差为2.3%～15.3%,6个实际样品测定结果的相对标准偏差为1.2%～27.3%,基体加标回收率为51.3%～126%,连续校准稳定。该方法适用于废酸油渣样品中16种多环芳烃的检测,比直接溶解有效,比加速溶剂萃取、索氏提取、微波萃取和超声探头萃取简单、快捷,能有效减少设备污染和腐蚀,净化方法有效,测定结果准确可靠,是实现大批量样品检测的可行方法。     

分光光度法测定染色废水的色度

为消除测定染色废水色度的主观误差，采用分光光度法测定染色废水的色度，与稀释倍数法相比，具有精确，重现性好，适用范围广等特点，ＰＨ值对色度的测定有明显影响，控制ＰＨ值为７．６０，测定色度具有可比性。     

无剩余污泥的多级活性生化处理工艺

介绍了多级活性生化处理 (MSABP)这项新的废水处理技术的原理、技术特点及两个实例运用。这是此项技术在国内的首次运用 ,其最大的优点是无剩余污泥产生 ,不需要沉淀池     

Aliphatic and polycyclic aromatic hydrocarbons in sediments of Kaohsiung Harbour and adjacent coast, Taiwan

Surficial sediment samples collected from Kaohsiung Harbour and its nearby coast were analyzed for aliphatic hydrocarbons and parent polycyclic aromatic hydrocarbons (PAHs). According to our results, the average total concentrations of n-alkanes (n-C₁₂ to C₃₅) and aromatics (15 PAHs) were 4.33 µg g^–1 dry weight (ranged 0.46–22.60) and 0.59 µg g^–1 dry weight (ranged 0.09–1.75), respectively. The highest concentrations of aliphatic and aromatic hydrocarbons were recorded in stations near the estuaries of Qianzhen River and Love River, respectively. Aliphatic hydrocarbons in the samples indicate that there has been significant non-petrogenic, possibly terrestrial, contribution in the sediment of the open coast of Kaohsiung Harbour and that there has been dominant contribution from petrogenic sources in the sediment of the inner harbour. PAHs, detected in the samples, however, indicated a higher pyrolytic contribution in open-coast samples and a higher petrogenic contribution in the inner harbour. Overall, sediment concentrations of total alkanes in this study were comparable to those found in Victoria Harbour, Hong Kong and are higher than those found in Xiamen Harbour, China. Concentrations of total PAHs in inner Kaohsiung Harbour sediments were relatively lower than those found in Victoria Harbour, Hong Kong and Xiamen Harbour, China, but comparable to those found in Hsin-ta Harbour, Taiwan and Incheon Harbour, Korea. In comparison with several effect-based sediment quality guidelines, most PAH concentrations found in samples taken from inner harbour stations exceeded the Threshold Effect Level of Florida indicating a slight possibility of adverse effects.     

石油化工工业区区域废水中COD_（Cr）和COD_（Mn）的相关性研究

连续同时监测天津市大港石化发展规划区区域废水中的ＣＯＤＣｒ和ＣＯＤＭｎ，并考查其线性相关性后得出ＣＯＤＣｒ＝４．９６ＣＯＤＭｎ＋１１６．３，相关系数为０．７５０。该回归方程适用于类似石油化工工业区区域废水中ＣＯＤＣｒ和ＣＯＤＭｎ间的换算