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61.
Cr(Ⅵ)污染土壤的热解还原无害化处理 总被引:4,自引:2,他引:2
提出了用热解还原法对含铬土壤进行无害化处理的新技术,研究了热解温度、热解时间及土壤有机质对铬无害化处理的影响,分析了热解前后土壤中铬的元素形态的变化.同时还探讨了热解还原过程中Cr(Ⅵ)的无害化机制.结果表明,土壤中的有机质在热解还原过程中产生的挥发分对Cr(Ⅵ)的无害化起核心作用;在200~600℃范围内,Cr(Ⅵ)的还原量随着热解温度升高而增大,500.0℃最适合于经济有效地实现Cr(Ⅵ)的热解还原处理;Cr(Ⅵ)的热解还原过程较快.铬的形态分析结果表明,热解后可交换态和碳酸盐结合态铬量大大降低,大部分铬转化成了活性低的残渣态,极大地降低了铬的危害. 相似文献
62.
铁炭微电解预处理电路板废水 总被引:3,自引:0,他引:3
采用铁炭微电解法预处理电路板废水.结果表明,在进水pH为2.00、铁炭质量比为4:1、振荡时间为20 min的铁炭微电解静态实验最佳条件下,絮凝出水COD去除率为30%;在进水pH为2.00、铁炭质量比为4:1、水力停留时间为50 min的铁炭微电解柱动态实验最佳条件下,连续曝气.絮凝出水COD为11021 mg/L,COD去除率约为34%,BOD5/COD从0.12上升到0.32,可生化性提高,Cu2+质量浓度从9.11 mg/L下降至0.76 mg/L,降低了废水的生物毒性,为生化处理创造了条件. 相似文献
63.
Jason A. Dittman James B. Shanley George R. Aiken Janet E. Towse 《Environmental pollution (Barking, Essex : 1987)》2009,157(6):1953-1956
Stream water samples were collected over a range of hydrologic and seasonal conditions at three forested watersheds in the northeastern USA. Samples were analyzed for dissolved total mercury (THgd), DOC concentration and DOC composition, and UV254 absorbance across the three sites over different seasons and flow conditions. Pooling data from all sites, we found a strong positive correlation of THgd to DOC (r2 = 0.87), but progressively stronger correlations of THgd with the hydrophobic acid fraction (HPOA) of DOC (r2 = 0.91) and with UV254 absorbance (r2 = 0.92). The strength of the UV254 absorbance-THgd relationship suggests that optical properties associated with dissolved organic matter may be excellent proxies for THgd concentration in these streams. Ease of sample collection and analysis, the potential application of in-situ optical sensors, and the possibility for intensive monitoring over the hydrograph make this an effective, inexpensive approach to estimate THgd flux in drainage waters. 相似文献
64.
A method for quality screening is suggested to detect volatile impurities in inorganic coagulants that are used for drinking water treatment. Static headspace gas chromatography with mass spectrometry detection (HS–GCMS) is sensitive and selective to detect volatiles in low concentrations. This study has discovered that volatile organic impurities are detectable in ferric and aluminium-based coagulants which are used for drinking water treatment. For ferric chloride, 2-propanol was detected at a level of 17–24 μg ml−1, acetone at 0.7–1.7 μg ml−1, 1,1,1-trichloroacetone at 0.02–0.04 μg ml−1, trichloromethane at 0.01–0.02 μg ml−1 and toluene at 0.01–0.12 μg ml−1. For ferric chloride sulfate, acetone was detected at a level of 0.12 μg ml−1, 1,1,1-trichloroacetone at 0.06–0.08 μg ml−1, trichloromethane at 0.13–0.23 μg ml−1, bromodichloromethane at 0.04–0.06 μg ml−1 and dibromochloromethane at 0.04–0.05 μg ml−1. For aluminium hydroxide chloride, only trichloromethane was detectable, but below the method detection limits (MDL). Although the concentrations of these impurities in commercial coagulants are low, this observation is important and should have impact on water industries for them to pay attention to the chemicals they are using for drinking water production. 相似文献
65.
Jessica T. Newlin Peggy A. Johnson 《Journal of the American Water Resources Association》2009,45(5):1197-1208
Abstract: An adaptive management framework is applied to the problem of identifying mitigation measures for sediment deposition near bridge crossings in small streams in the Northern Tier region of northern Pennsylvania. The presence of the rigid bridge infrastructure introduces a challenge for applying adaptive management practices, because the integrity of the bridge structure itself has to be maintained regardless of the mitigation practices used in the stream channel near the bridge. In an effort to overcome the unacceptable risk that field‐scale adaptive management experiments present to rigid bridge infrastructure, an adaptive management approach for laboratory‐scale experimentation of mitigation methods at bridge crossings in the Northern Tier region is presented as a way to decrease the level of uncertainty about channel response to mitigation measures and increase the rate of learning about the effectiveness of these measures. Four cycles of adaptive management experiments are discussed to demonstrate that this approach results in fast and efficient learning about channel response to mitigation methods for the given conditions. The value of monitoring and of assessment of monitored data in the overall efficiency of the adaptive management approach is highlighted. Assessment of what was learned in the adaptive management experiment cycles presented here leads to new directions to continually improve management policies and practices in stream channels at bridge crossings in the Northern Tier region. The adaptive management process, rather than continuing with a normally risk‐averse management approach, results in opportunities for learning new information about a system’s response. 相似文献
66.
67.
有机废气中VOC的回收方法 总被引:33,自引:1,他引:33
介绍了炭吸附法、冷凝法和膜分离法回胥机废报中VOD的原理、工艺流程和工业应用情况,并对这些方法进行了比较,指出了适用范围。 相似文献
68.
Fenton法处理垃圾渗滤液MBR-NF浓缩液 总被引:1,自引:0,他引:1
采用Fenton法处理MBR-NF浓缩液,考察了FeSO4·7H2O投加量、n(H2O2)/n(Fe2+)投加比、初始pH对渗滤液MBR-NF浓缩液处理效果的影响,并在最佳实验条件下,探讨浓缩液富里酸(FA)、亲水性有机物(HyI)组分在Fenton氧化前后组成的变化。研究结果表明,在FeSO4·7H2O投加量为0.055 mol/L、n(H2O2)/n(Fe2+)投加比为4、初始pH为7.58时,对COD、腐植酸(UV254)、色度(CN)的去除率分别为79.6%、93.7%和97.8%。Fenton氧化后,浓缩液中有机物组分含量发生了较大变化,腐植酸含量下降,HyI成为渗滤液溶解性有机物主要成分。紫外-可见光谱表明,Fenton法对FA去除效果较好,而对HyI氧化效果较差;傅立叶红外光谱显示,经Fenton氧化后,FA的结构发生了明显变化,而HyI则变化不明显。 相似文献
69.
《Journal of Environmental Policy & Planning》2012,14(2):163-175
In this paper, we explore the dissemination potential of organic farming in Andalucía, using the case of Olivarera de los Pedroches, a small farmer cooperative. This will be done in the search for an agroecological strategy in the olive tree organic agricultural sector. A comparative analysis of organic and conventional olive oil production is made: both in economic terms, and regarding employment creation, taking into account its environmental benefits. This will permit us to shed light on certain elements necessary in the design of rural policies linked to this economic sector, and in the family farming social stratum. After a brief analysis of the Andalucían inequality structure in rural areas—both historically and at present times—this work presents the following issues: (i) a systematic characterization of European olive cultivation, with special reference to the Spanish and Andalucían situations; (ii) an exploration of the socio-economic impact of the case study within the context of the major actors involved, and their relations in terms of its reproducibility, taking into account their relationships with institutional and policy arrangements. Organic agriculture in Spain has developed slowly since 1995—the year in which aid towards this type of production began to be established—and, at present, begins to show an exponential increase. Many farmers began the transition to ecological handling of olive groves. Consequently, the organic management of the olive groves and the sale of organic olive oil can be a stimulus to farmers to increase their profits. Hence, it can be a fundamental pillar on which to establish rural development in areas with a high level of importance concerning this crop. In this work, data clearly show that, in spite of high costs, organic olive farming has advantages over conventional agriculture in terms of incomes and employment. Copyright © 2001 John Wiley & Sons, Ltd. 相似文献
70.
Moe MK Huber S Svenson J Hagenaars A Pabon M Trümper M Berger U Knapen D Herzke D 《Chemosphere》2012,89(7):869-875
For several decades, perfluorooctane sulfonate (PFOS) has widely been used as a fluorinated surfactant in aqueous film forming foams used as hydrocarbon fuel fire extinguishers. Due to concerns regarding its environmental persistence and toxicological effects, PFOS has recently been replaced by novel fluorinated surfactants such as Forafac®1157, developed by the DuPont company. The major component of Forafac®1157 is a 6:2 fluorotelomer sulfonamide alkylbetaine (6:2 FTAB), and a link between the trade name and the exact chemical structure is presented here to the scientific community for the first time. In the present work, the structure of the 6:2 FTAB was elucidated by 1H, 13C and 19F nuclear magnetic resonance spectroscopy and high-resolution mass spectrometry. Moreover, its major metabolites from blue mussel (Mytilus edulis) and turbot (Scophthalmus maximus) and its photolytic transformation products were identified. Contrary to what has earlier been observed for PFOS, the 6:2 FTAB was extensively metabolized by blue mussel and turbot exposed to Forafac®1157. The major metabolite was a deacetylated betaine species, from which mono- and di-demethylated metabolites also were formed. Another abundant metabolite was the 6:2 fluorotelomer sulfonamide. In another experiment, Forafac®1157 was subjected to UV-light induced photolysis. The experimental conditions aimed to simulate Arctic conditions and the deacetylated species was again the primary transformation product of 6:2 FTAB. A 6:2 fluorotelomer sulfonamide was also formed along with a non-identified transformation product. The environmental presence of most of the metabolites and transformation products was qualitatively demonstrated by analysis of soil samples taken in close proximity to an airport fire training facility. 相似文献