激发剂作用下的盐石膏废渣的水化过程

运用Kondo模型,研究了在激发剂硫酸钠作用下盐石膏废渣的水化过程.盐石膏废渣的水化过程分为3个阶段,第1、第3阶段受扩散作用控制;第2阶段受相边界反应控制.分别研究了激发剂溶液浓度和温度对相边界反应阶段水化速率的影响,结果表明,在0—0.60 mol.L-1范围内,增大激发剂溶液浓度可使水化速率常数k增大,在12℃≤...     

双负载双金属催化剂催化有机卤化物水相脱卤研究

通过把起相转移作用的聚乙二醇链固载在硅胶上（SiO2-PEG600），再将聚乙稀吡咯烷酮（PVP）络合双金属Pd-Cu(PVP-PdCl2-CuCl2)后负载其中，制成一种新型双负载双金属水相脱卤催化剂PVP－PdCl2-CuCl2/SiO2-PEG600。以甲酸钠为氢转移试制，在水相中催化有机卤化物脱卤，研究结果表明：反应温度为800℃，Pd∶Cu=2∶1（摩尔比），反应介质pH≈11.7左右时，该催化剂对芳香氯化物及α－氯代酮、酯具有良好的催化脱氯和重复使用性能。     

气相色谱仪检测溶解气H_2、He最佳观测条件的选择

通过色谱柱、固定相以及载气流速的选择性实验 ,提高了气相色谱仪在观测地下水中H2 、He分离效能和检测效能。本文对此作介绍 ,以期对使用气相色谱仪进行地下水H2 、He观测的台站能有所启发和借鉴     

废水生化处理出水吸收SO2过程相平衡关系的确定

应用相平衡理论对吸收液－ＳＯ２体系的相平衡关系进行了系统研究,确定了吸收相平衡的数学模型,并通过试验对数学模型进行了验证,结果表明,数学模型计算值与试验实测值基本吻合。     

微生物絮凝剂处理造纸中段废水的实验研究

实验从土壤中分离筛选出1株絮凝活性较高的絮凝剂产生菌,经鉴定为1株黑曲霉.采用其产生的微生物絮凝剂M-2处理造纸中段废水,对絮凝条件进行了优化,在最佳絮凝条件下,M-2对造纸中段废水的CODcr去除率可达70.6%,浊度去除率可达91.7%,其絮凝效果优于传统的絮凝剂.     

响应面法优化养殖水体中炔雌醇的固相萃取条件

在单因素试验、Plackett-Burman设计试验基础上,采用Box-Behnken响应面法对养殖水体中炔雌醇(EE2)的固相萃取条件进行优化。结果表明,洗脱液体积、洗脱液组成和淋洗液体积是影响EE2固相萃取回收率的3个主要因素;EE2的最佳固相萃取条件为:水样pH值为3,进样流量为3.0 mL/min,淋洗液为体积分数为10%的甲醇水溶液,淋洗液体积7.0 mL,洗脱液为乙酸乙酯-正己烷混合溶液(体积比为9∶1),洗脱液体积12.0 mL。该条件下养殖水样中EE2固相萃取回收率为81.6%～86.7%。     

星形大分子液晶在气相色谱分析中的应用研究

将首次合成的偶氮苯硅氧烷类星形液晶大分子化合物用于毛细管柱气相色谱固定液 ,在其相转变温度附近具有良好的选择性 ,成功地分离了二甲酚异构体。     

Mathematical Modeling of Column and Field Dense Nonaqueous Phase Liquid Tracer Tests

Mathematical models for the simulation of dense nonaqueous phase liquid tracer tests (DTTs) in laboratory columns and in the field are developed and examined. The DTT technique is a means of estimating the quantity of dense nonaqueous phase liquid (DNAPL) in a domain of interest in an aquifer. The two-dimensional field DTT model uses the Method of Principal Directions and an asymmetrical upwind algorithm for describing advective transport. Both models include diffusion transport of tracer into and from low-permeability porous structures such as clay lenses, as well as the mass transport kinetics of partitioning tracer to and from the DNAPL droplets. The dependence of the effluent tracer concentration curves on the parameters of the models is explored, and conclusions are drawn regarding the applicability of, and several possible problems with, the DTT technique. Model results indicate that the DTT performs well at locating distributed droplets of DNAPL, but is unlikely to be useful in the assessment of pooled DNAPL.     

喻家土扁滑坡形成的力学机理与险情分析

喻家滑坡发现于去年5月,体积近17×104m3,呈长条纺棰状,分成上.下滑块,本文从斜坡的变形历史、特征调查入手,较深入地研究了该滑坡滑移-拉裂-推动-牵引的耦合力学机理,该滑坡正处在蠕滑阶段,近期存在整体滑移和出现较大危害的险情,已引起有关部门的重视,并采取了有力的减灾防灾措施.     

Blast wave clearing behavior for positive and negative phases

The purpose of the research was to improve prediction of response of buildings to blast waves by including the negative phase and considering clearing of both positive and negative phases. Commonly used structural design practices, which trace their origins to military design manuals, often ignore the negative phase as well as positive phase clearing. For high explosive threats, this approach is conservative in most circumstances. However, negative phase clearing had not previously been studied for blast waves, and the implications for structural response had not been evaluated. This paper presents results of modeling negative phase blast clearing behavior for a typical blast wave and discusses the differences from positive phase clearing. The implications of including positive and negative phase clearing in building blast damage analysis are also investigated through single-degree-of-freedom (SDOF) analyses.Blast waves from explosion sources like a vapor cloud explosion (VCE), pressure vessel burst or high explosive exhibit both positive and negative phases, and the relative magnitude of the positive and negative phases varies among explosion sources and the specific circumstances of each source. A fully reflected blast wave is produced if an incident blast wave were to strike an infinitely tall and wide wall in a normal orientation. Both the positive and negative phases of the blast wave are enhanced by the reflection process. However, when an incident blast wave strikes a wall of finite size in a normal orientation, rarefaction waves are created at the edges of the wall, and the rarefactions sweep down from the roof and inward from sides. The rarefaction waves result in a clearing effect for both the positive and negative phases.Clearing relieves some of the applied blast load on the reflected wall for the positive phase. However, this is not always the case for the negative phase. As shown by the results presented in this paper, clearing may either relieve or enhance the applied negative phase blast load, depending on the duration of the blast wave and the wall dimensions.The impact of negative phase clearing on structural response for generic building components was also investigated. Nonlinear SDOF methods were used to characterize response in terms of peak positive and negative displacements. It was found that the influence of the negative phase is significant and the peak structural response can occur during negative (outward) displacement.