全文获取类型
收费全文 | 327篇 |
免费 | 38篇 |
国内免费 | 150篇 |
专业分类
安全科学 | 22篇 |
废物处理 | 32篇 |
环保管理 | 23篇 |
综合类 | 297篇 |
基础理论 | 39篇 |
污染及防治 | 78篇 |
评价与监测 | 22篇 |
社会与环境 | 2篇 |
出版年
2023年 | 3篇 |
2022年 | 6篇 |
2021年 | 11篇 |
2020年 | 12篇 |
2019年 | 11篇 |
2018年 | 15篇 |
2017年 | 15篇 |
2016年 | 18篇 |
2015年 | 15篇 |
2014年 | 21篇 |
2013年 | 43篇 |
2012年 | 32篇 |
2011年 | 25篇 |
2010年 | 29篇 |
2009年 | 25篇 |
2008年 | 16篇 |
2007年 | 34篇 |
2006年 | 46篇 |
2005年 | 28篇 |
2004年 | 27篇 |
2003年 | 16篇 |
2002年 | 13篇 |
2001年 | 7篇 |
2000年 | 9篇 |
1999年 | 8篇 |
1998年 | 8篇 |
1997年 | 3篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 3篇 |
1988年 | 2篇 |
1985年 | 1篇 |
1983年 | 1篇 |
排序方式: 共有515条查询结果,搜索用时 656 毫秒
81.
The decomposition of chloroform (CHCl3) diluted in air was studied. The experiment was carried out by using a gliding arc plasma. Different values of initial concentrations of chloroform, total gas flow rates, and input power frequencies have been used to investigate this effects on the conversion reaction products both qualitatively and quantitatively. Experimental results indicate that the maximum conversion of chloroform was 97% at a total gas flow rate of 180?L?h?1 containing 1% chloroform. Using air as carrier gas, decomposition of CHCl3 produces CCl4, CO2, CO, and Cl2 as the main products. Small amounts of HCl and COCl2 are also detected. Liquid products were also produced. 相似文献
82.
An automated method for the indirect determination of fluoride by inductively coupled plasma atomic emission spectrometry using discontinuous-flow analysis has been developed. A modified flow injection analysis system was used for sample preparation. The method is based on the determination of excess cerium(III) ion after precipitation of CeF3. Separation of the precipitate is performed online on a syringe membrane filter that is cleaned each analysis cycle by 1 M nitric acid, ensuring a long life-time for the filter. As a result of the short reaction time, a detection limit of 9.5 mg L?1 was obtained. The precision (RSD) of the proposed method is 1.02% at fluoride concentration of 28 mg L?1. The applicability of the technique for groundwater monitoring of fluoride-contaminated area is demonstrated. 相似文献
83.
Kebede Nigussie Mekonnen Bhagwan Singh Chandravanshi Mesfin Redi-Abshiro Robert Ian McCrindle 《毒物与环境化学》2013,95(10):1501-1515
For the determination of 15 potentially toxic elements (V, Cr, Fe, Mn, Co, Ni, Cu, Zn, As, Se, Ag, Cd, Sn, Hg, and Pb) in plant and sediment samples of the Akaki River, Ethiopia, inductively coupled plasma–mass spectrometry, inductively coupled plasma–optical emission spectrometry, and a RA-915+ mercury analyzer were applied. Sediment and plant samples were mineralized using a closed-vessel microwave-assisted digestion system. The elemental concentrations varied considerably in plant and sediment samples. The minimum concentration was observed for known toxic elements (As, Hg, and Cd) while the highest concentration was observed for the elements of relatively low toxicity Zn, Mn, and Fe. The concentration of Cr, Fe, Pb, Zn, and As in Swiss chard surpassed the maximum permissible levels at specific sites. At some of the sites, the sediment quality guidelines are surpassed for Cu, Zn, and Pb. 相似文献
84.
为了解CS2(二硫化碳)在介质阻挡放电反应器中的降解特性,提高其去除率,设计并制作了同轴圆柱介质阻挡放电反应器,研究了介质层数、外施电压、中心电极材料及直径、背景气氛种类和RH(相对湿度)对CS2去除率的影响. 结果表明:在外施电压(4.0~6.5kV)较低时,单介质反应器的CS2去除率高于双介质反应器;而在外施电压(6.5~9.0kV)较高时,双介质反应器对CS2的去除效果更好,增大外施电压有利于CS2的降解. 铜丝比不锈钢丝更适合用作反应器的中心电极,此外,增加中心电极的直径也可提高CS2去除率. 当中心电极直径从 3.2mm增至4.8mm时,CS2平均去除率由63%增至75%,但平均质量能耗由510kJ/mg增至611kJ/mg. 同等条件下,CS2在氧气中的平均去除率(74%)最大,空气(59%)中次之,氮气(48%)中最小;背景气氛中适量的RH(26%)有助于提高CS2去除率,但RH太大(大于50%)反而会降低CS2去除率. 相似文献
85.
86.
Antonius Indarto Jae-Wook Choi Hwaung Lee Hyung Keun Song 《International Journal of Green Energy》2013,10(3):309-321
Decomposition of dichloromethane (CH2Cl2) using a gliding plasma was examined and reported in this paper. The effects of initial concentrations of CH2Cl2, total gas flow rates, and input frequency have been studied to evaluate the performance of gliding arc on CH2Cl2 decomposition. Using atmospheric pressure air as the carrier gas, experimental results indicate that the maximum conversion of CH2Cl2 was 95.1% at a total gas flow rate of 180 L/hr containing 1% by volume of CH2Cl2. The reaction occurred at an exothermic condition and gaseous products are dominated by CO, CHCl3, and Cl2. CO2 and CCl4 are also detected in the product stream in small amounts. The conversion of CH2Cl2 increases with the increasing applied voltage and decreasing total gas flow rate. 相似文献
87.
非热等离子体与催化相结合去除气相低浓度苯系物 总被引:1,自引:1,他引:1
利用串齿线-简体构成的等离子体反应器,研究了非热等离子体及其与Pt/Al2O3或Mn/Al2O3催化剂组合作用下的苯系物转化率、COx产率和O3生成情况.结果表明.苯系物转化率排序为对二甲苯>甲苯>苯.产生非热等离子体的放电区后接Pt/Al2O3或Mn/Al2O3催化剂可提高苯系物的转化率,并使达到相同转化率所对应的电压降低1~2kV,等离子体与催化剂之间表现出明显的协同效应.非热等离子体放电与Pt/Al2O3或Mn/Al2O3催化剂组合后也有利于苯系物向COx转化及去除放电产生的O3,可使最大COx产率从80%分别提高到86%和100%,而反应器出口的最大O3浓度则从707mg·m-3分别降至339mg·dm-3和39mg·dm-3.经过等离子体反应器、催化剂以及两者组合方式的优化,等离子体放电协同Mn/Al2O3催化剂工艺有望成为处理气相低浓度有机物的实用方法. 相似文献
88.
研究放电等离子体灭活大肠杆菌的效果。采用远程氧等离子体反应器,分别考察探究放电功率、处理时间、氧气流量、远程距离及有机污染物对灭菌效果的影响,并观察灭菌前后大肠杆菌的显微结构。结果表明在100W,60s,40cm3/min条件下,远程氧等离子体的杀菌效果值在距放电区0、20、40cm处分别为3.42、3.38和3.32。有机物浓度升高,灭菌效果急剧下降。结论为氧等离子体在距放电区040cm内均能有效灭活大肠杆菌,但有机污染物影响较大。氧等离子体场中高能粒子的刻蚀作用是导致细菌死亡的主要原因。 相似文献
89.
《International Journal of Sustainable Engineering》2013,6(4):290-300
The author offers collections from his previous research of the revolutionary new ideas: wireless transfer of electric energy to a long distance – from one continent to another continent through the Earth's ionosphere and the storage of the electric energy in the ionosphere. Earlier he also suggested the use of electronic tubes as the method for transportation of electricity into outer space and the 100-km electrostatic space towers for connection to the Earth's ionosphere. Earlier a connection to the Earth's ionosphere using 100-km solid or inflatable towers was suggested. however, the technology faces difficulties. In this work, connection to the Earth's ionosphere by thin plastic tubes supported in the atmosphere by electron gas and electrostatic force is researched. Building this system is cheap and easy using the current technology. The computation allows estimating the possibility of the suggested method. 相似文献
90.