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41.
Background, Aim and Scope Air quality is an field of major concern in large cities. This problem has led administrations to introduce plans and regulations
to reduce pollutant emissions. The analysis of variations in the concentration of pollutants is useful when evaluating the
effectiveness of these plans. However, such an analysis cannot be undertaken using standard statistical techniques, due to
the fact that concentrations of atmospheric pollutants often exhibit a lack of normality and are autocorrelated. On the other
hand, if long-term trends of any pollutant’s emissions are to be detected, meteorological effects must be removed from the
time series analysed, due to their strong masking effects.
Materials and Methods The application of statistical methods to analyse temporal variations is illustrated using monthly carbon monoxide (CO) concentrations
observed at an urban site. The sampling site is located at a street intersection in central Valencia (Spain) with a high traffic
density. Valencia is the third largest city in Spain. It is a typical Mediterranean city in terms of its urban structure and
climatology. The sampling site started operation in January 1994 and monitored CO ground level concentrations until February
2002. Its geographic coordinates are W0°22′52″ N39°28′05″ and its altitude is 11 m. Two nonparametric trend tests are applied.
One of these is robust against serial correlation with regards to the false rejection rate, when observations have a strong
persistence or when the sample size per month is small. A nonparametric analysis of the homogeneity of trends between seasons
is also discussed. A multiple linear regression model is used with the transformed data, including the effect of meteorological
variables. The method of generalized least squares is applied to estimate the model parameters to take into account the serial
dependence of the residuals of this model. This study also assesses temporal changes using the Kolmogorov-Zurbenko (KZ) filter.
The KZ filter has been shown to be an effective way to remove the influence of meteorological conditions on O3 and PM to examine underlying trends.
Results The nonparametric tests indicate a decreasing, significant trend in the sampled site. The application of the linear model
yields a significant decrease every twelve months of 15.8% for the average monthly CO concentration. The 95% confidence interval
for the trend ranges from 13.9% to 17.7%. The seasonal cycle also provides significant results. There are no differences in
trends throughout the months. The percentage of CO variance explained by the linear model is 90.3%. The KZ filter separates
out long, short-term and seasonal variations in the CO series. The estimated, significant, long-term trend every year results
in 10.3% with this method. The 95% confidence interval ranges from 8.8% to 11.9%. This approach explains 89.9% of the CO temporal
variations.
Discussion The differences between the linear model and KZ filter trend estimations are due to the fact that the KZ filter performs the
analysis on the smoothed data rather than the original data. In the KZ filter trend estimation, the effect of meteorological
conditions has been removed. The CO short-term componentis attributable to weather and short-term fluctuations in emissions.
There is a significant seasonal cycle. This component is a result of changes in the traffic, the yearly meteorological cycle
and the interactions between these two factors. There are peaks during the autumn and winter months, which have more traffic
density in the sampled site. There is a minimum during the month of August, reflecting the very low level of vehicle emissions
which is a direct consequence of the holiday period.
Conclusions The significant, decreasing trend implies to a certain extent that the urban environment in the area is improving. This trend
results from changes in overall emissions, pollutant transport, climate, policy and economics. It is also due to the effect
of introducing reformulated gasoline. The additives enable vehicles to burn fuel with a higher air/fuel ratio, thereby lowering
the emission of CO. The KZ filter has been the most effective method to separate the CO series components and to obtain an
estimate of the long-term trend due to changes in emissions, removing the effect of meteorological conditions.
Recommendations and Perspectives Air quality managers and policy-makers must understand the link between climate and pollutants to select optimal pollutant
reduction strategies and avoid exceeding emission directives. This paper analyses eight years of ambient CO data at a site
with a high traffic density, and provides results that are useful for decision-making. The assessment of long-term changes
in air pollutants to evaluate reduction strategies has to be done while taking into account meteorological variability 相似文献
42.
Schaefer CE do Amaral EF de Mendonça BA Oliveira H Lani JL Costa LM Fernandes Filho EI 《Environmental monitoring and assessment》2008,140(1-3):279-289
The relationships between soils attributes, soil carbon stocks and vegetation carbon stocks are poorly know in Amazonia, even
at regional scale. In this paper, we used the large and reliable soil database from Western Amazonia obtained from the RADAMBRASIL
project and recent estimates of vegetation biomass to investigate some environmental relationships, quantifying C stocks of
intact ecosystem in Western Amazonia. The results allowed separating the western Amazonia into 6 sectors, called pedo-zones:
Roraima, Rio Negro Basin, Tertiary Plateaux of the Amazon, Javari-Juruá-Purus lowland, Acre Basin and Rondonia uplands. The
highest C stock for the whole soil is observed in the Acre and in the Rio Negro sectors. In the former, this is due to the
high nutrient status and high clay activity, whereas in the latter, it is attributed to a downward carbon movement attributed
to widespread podzolization and arenization, forming spodic horizons. The youthful nature of shallow soils of the Javari-Juruá-Purus
lowlands, associated with high Al, results in a high phytomass C/soil C ratio. A similar trend was observed for the shallow
soils from the Roraima and Rondonia highlands. A consistent east–west decline in biomass carbon in the Rio Negro Basin sector
is associated with increasing rainfall and higher sand amounts. It is related to lesser C protection and greater C loss of
sandy soils, subjected to active chemical leaching and widespread podzolization. Also, these soils possess lower cation exchangeable
capacity and lower water retention capacity. Zones where deeply weathered Latosols dominate have a overall pattern of high
C sequestration, and greater than the shallower soils from the upper Amazon, west of Madeira and Negro rivers. This was attributed
to deeper incorporation of carbon in these clayey and highly pedo-bioturbated soils. The results highlight the urgent need
for refining soil data at an appropriate scale for C stocks calculations purposes in Amazonia. There is a risk of misinterpreting
C stocks in Amazonia when such great pedological variability is not taken into account. 相似文献
43.
针对间接冷却水的特点和核算其污染当量数过程中存在的问题,阐述了间接冷却水的界定,水源水的采样监测技术,本底值的扣除以及超标排放的判别等环节的技术要求和注意事项,并就与之密切相关的几个问题展开了讨论,为核算间接冷却水当量数提供了一定的参考依据,建议增加水湿排放指标,以切实控制间接冷却水造成的主要污染-热污染。 相似文献
44.
本文从柑桔冻害和热害的危害因子和指标等级划分的研究和选取入手,着重探讨了长江三峡地区(湖北境内)两害显著的时空变化特征、差异与关联性及对柑桔生产的影响;揭示了80年代以来冬暖春热的重大气候变化是使两害向“两极分化”的根本原因;讨论了三峡水利工程对两害时空格局的可能调整及减灾原理;最后提出了可能的对策。 相似文献
45.
Samaratunga SS Nishimoto J Tabata M 《Environmental science and pollution research international》2008,15(1):27-30
BACKGROUND, AIMS AND SCOPE: Chromium enters into the aquatic environment as a result of effluent discharge from steel works, electroplating, leather tanning industries and chemical industries. As the Cr(VI) is very harmful to living organisms, it should be quickly removed from the environment when it happens to be contaminated. Therefore, the aim of this laboratory research was to develop a rapid, simple and adaptable solvent extraction system to quantitatively remove Cr(VI) from polluted waters. METHODS: Aqueous salt-solutions containing Cr(VI) as CrO4(2-) at ppm level (4-6 ppm) were prepared. Equal volumes (5 ml) of aqueous and organic (2-PrOH) phases were mixed in a 10 ml centrifuge tube for 15 min, centrifuged and separated. Concentrations of Cr(VI), in both the aqueous and organic phases, were determined by atomic absorption spectrometry. The effects of salt and acid concentrations, and phase-contact time on the extraction of Cr(VI) were investigated. In addition, the extraction of Cr(VI) was assessed in the presence of tetramethylammonium chloride (TMAC) in 2-PrOH phase. Effects of some other metals, (Cd(II), Co(II), Cu(II), Ni(II) and Zn(II)), on the extraction of Cr(VI) were also investigated. RESULTS AND DISCUSSION: The Cr(VI) at ppm level was extracted quantitatively by salting-out the homogeneous system of water and 2-propanol(2-PrOH) using chloride salts, namely CaCl2 or NaCl, under acidic chloride media. The extracted chemical species of Cr(VI) was confirmed to be the CrO3Cl-. The ion-pair complex extracted into the organic phase was rationalized as the solvated ion-pair complex of [2-PrOH2+, CrO3Cl-]. The complex was no longer stable. It implied the reaction between extracted species. Studies revealed that salts and acid directly participated in the formation of the above complex. Use of extracting agents (TMAC) didn't show any significant effect on the extraction of Cr(VI) under high salting-out conditions. There is no significant interference effect on the extraction of Cr(VI) by the presence of other metals. The Cr(VI) in the organic phase was back-extracted using an aqueous ammonia solution (1.6 mol dm(-3)) containing 3 mol dm(-3) NaCl. The extraction mechanism of Cr(VI) is also discussed. CONCLUSIONS: Salting-out of homogeneous mixed solvent of 2-propanol can be employed to extract Cr(VI) quantitatively, as an ion-pair of [2-PrOH2+ * CrO3Cl-] solvated by 2-PrOH molecules. Then, the complex becomes 'solvent-like' and is readily separated into the organic phase. The increase of Cl- ion concentration in the aqueous phase favors the extraction. The 2-PrOH, salts and acid play important roles in the extraction process. There is no need to use an extracting agent at a high salting-out condition. RECOMMENDATIONS AND PERSPECTIVES: Chromium(VI) must be quickly removed before it enters into the natural cycle. As the 2-PrOH is water-miscible in any proportion, ion-pairing between 2-PrOH2+ and CrO3Cl- becomes very fast. As a result, Cr(VI) can easily be extracted. Therefore, the method is recommended as a simple, rapid and adaptable method to quickly separate Cr(VI) from aqueous samples. 相似文献
46.
The methodology of materials accounting is presented and applied to developing nutrient balance (nitrogen and phosphorus)
in a river basin. The method is based on the balance principle: inputs and outputs of each nitrogen and phosphorus related
sub-systems were balanced. The application of the methodology strategies was illustrated by means of a case study of the Krka
river, Slovenia. Different pathways of emission to surface waters were taken into account: WWTP discharges, direct discharges,
erosion/runoff and baseflow. Total annual emission into the river Krka was estimated to be 362 tonnes N/year and 73.3 tonnes
P/year. The main sources of nitrogen are diffuse sources, emitted via baseflow (52%). Other important sources are effluents
from WWTP, which account for 36% of total emissions. Other sources like erosion and direct discharges to surface water (animal
manure, industry, households) are of lower magnitude. Erosion is main source of phosphorus emission (55% of total emission),
WWTP effluents account for 37% of total emission, while other sources are less important. Besides reduction of point sources
by means of wastewater collection and implementation of nutrient removal technology, managing agricultural nitrogen and phosphorus
to protect water quality should become a major challenge in the Krka river basin. 相似文献
47.
针对某乡镇企业十分发达地区的跨行政(市县)区域水污染死鱼事故的剖析,本文提出了处理解决跨行政区域水污染纠纷事故的若干对策建议。 相似文献
48.
岷江上游崩塌滑坡分布规律研究 总被引:1,自引:0,他引:1
乔建平 《长江流域资源与环境》1994,3(4):365-370
岷江为长江—级支流,上游长330km,自1986年以来,发生崩塌滑坡200余处,体积约2.1亿m ̄3。作者研究了岷江上游崩塌滑坡的分布规律。采用统计指标法,将岷江上游分为三种不同的崩塌滑坡分布密度区:①UXS.高密度区;②MXS,中密度区;③LXS_3低密度区。 相似文献
49.
María L. Pignata Martha S. Cañas Hebe A. Carreras Liliana Orellana 《Environmental management》1997,21(5):793-801
Ligustrum lucidum Ait. f. tricolor (Rehd.) Rehd. in relation to atmospheric pollutants in Córdoba city, Argentina. The study area receives
regional pollutants and was categorized taking into account traffic level, industrial density, type of industry, location
of the sample point in relation to the street corner, treeless condition, and topographic level. Dried weight/fresh weight
ratio (DW/FW) and specific leaf area (SLA) were calculated, and concentrations of chlorophylls, carotenoids, total sulfur,
soluble proteins, malondialdehyde (MDA), and hydroperoxy conjugated dienes (HPCD) were determined in leaf samples. Sulfur
content correlates positively with traffic density and SLA correlates negatively with some combinations of the categorical
variables; MDA correlates positively with topographic level and total protein concentration correlates negatively with treeless
condition. On the basis of our results, traffic, location of trees, type of industry, situation of a tree with respect to
others, and topographic level are the environmental variables to bear in mind when selecting analogous sampling points in
a passive monitoring program. An approximation to predict tree injury may be obtained by measuring DW/FW ratio, proteins,
pigments, HPCD, and MDA as they are responsible for the major variability of data. 相似文献
50.
Data on the existence of a specific system regulating the growth, size, and structure of enterobacterial populations are first summarized in terms of the chemical ecology concept formulated by S.S. Shvarts. The role of this system in transgene functioning is described using the example of the lux operon integrated into Escherichia coli. A relatively simple test for estimating such interactions is proposed.Translated from Ekologiya, No. 2, 2005, pp. 91–96.Original Russian Text Copyright © 2005 by Pshenichnov, Maslennikova, Nikitina. 相似文献