全文获取类型
收费全文 | 818篇 |
免费 | 136篇 |
国内免费 | 639篇 |
专业分类
安全科学 | 70篇 |
废物处理 | 144篇 |
环保管理 | 57篇 |
综合类 | 882篇 |
基础理论 | 181篇 |
污染及防治 | 230篇 |
评价与监测 | 19篇 |
社会与环境 | 7篇 |
灾害及防治 | 3篇 |
出版年
2024年 | 5篇 |
2023年 | 27篇 |
2022年 | 57篇 |
2021年 | 58篇 |
2020年 | 51篇 |
2019年 | 78篇 |
2018年 | 78篇 |
2017年 | 63篇 |
2016年 | 85篇 |
2015年 | 85篇 |
2014年 | 97篇 |
2013年 | 101篇 |
2012年 | 101篇 |
2011年 | 95篇 |
2010年 | 51篇 |
2009年 | 88篇 |
2008年 | 43篇 |
2007年 | 76篇 |
2006年 | 49篇 |
2005年 | 51篇 |
2004年 | 31篇 |
2003年 | 27篇 |
2002年 | 34篇 |
2001年 | 33篇 |
2000年 | 22篇 |
1999年 | 28篇 |
1998年 | 11篇 |
1997年 | 14篇 |
1996年 | 9篇 |
1995年 | 7篇 |
1994年 | 7篇 |
1993年 | 6篇 |
1992年 | 6篇 |
1991年 | 2篇 |
1990年 | 6篇 |
1988年 | 2篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1984年 | 1篇 |
1982年 | 1篇 |
1974年 | 1篇 |
1971年 | 1篇 |
排序方式: 共有1593条查询结果,搜索用时 203 毫秒
11.
目的评价纳米涂层/铝合金在不同pH值海水溶液中的腐蚀行为。方法通过测试纳米涂层/铝合金试样在不同pH值海水溶液中的EIS值,分析试样阻抗谱图及Bode谱图的演化规律,建立不同EIS图谱的不同电极阻抗模型,并采用ZView软件解析涂层体系不同时期的电化学阻抗谱,获得涂层电阻的变化趋势,及不同pH值海水浸泡的纳米涂层体系腐蚀失效速度。结果随着浸泡时间的增加及pH值的降低,纳米涂层/铝合金体系腐蚀损伤失效速率在浸泡前期整体趋势增大,但中后期由于腐蚀产物逐渐堵塞了涂层的微孔,腐蚀介质向铝合金表面渗透的速率逐渐减小。结论 pH为2.0海水浸泡下的3涂层失效最快,其次是pH为4.0海水浸泡下的2涂层,最后为p H为6.0海水浸泡下的1涂层,该涂层体系应采用等效电路模型C进行拟合。 相似文献
12.
Advanced oxidation technologies are a friendly environmental approach for the remediation of industrial wastewaters. Here, one pot synthesis of mesoporous WO_3 and WO_3-graphene oxide(GO) nanocomposites has been performed through the sol–gel method. Then, platinum(Pt) nanoparticles were deposited onto the WO_3 and WO_3-GO nanocomposite through photochemical reduction to produce mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites. X-ray diffraction(XRD) findings exhibit a formation of monoclinic and triclinic WO_3 phases. Transmission Electron Microscope(TEM) images of Pt/WO_3-GO nanocomposites exhibited that WO_3 nanoparticles are obviously agglomerated and the particle sizes of Pt and WO_3 are ~ 10 nm and 20–50 nm, respectively. The mesoporous Pt/WO_3 and Pt/WO_3-GO nanocomposites were assessed for photocatalytic degradation of Methylene Blue(MB) as a probe molecule under visible light illumination.The findings showed that mesoporous Pt/WO_3, WO_3-GO and Pt/WO_3-GO nanocomposites exhibited much higher photocatalytic efficiencies than the pure WO_3. The photodegradation rates by mesoporous Pt/WO_3-GO nanocomposites are 3, 2 and 1.15 times greater than those by mesoporous WO_3, WO_3-GO, and Pt/WO_3, respectively. The key factors of the enhanced photocatalytic performance of Pt/WO_3-GO nanocomposites could be explained by the highly freedom electron transfer through the synergetic effect between WO_3 and GO sheets, in addition to the Pt nanoparticles that act as active sites for O2 reduction, which suppresses the electron hole pair recombination in the Pt/WO_3-GO nanocomposites. 相似文献
13.
14.
Fence for traffic noise control sometimes causes adverse effect on air pollution. Thus in this study, performance of porous fence as a tool for control of both air pollution and noise pollution was evaluated. A two-dimensional numerical model for flow and pollutant concentration and an analytical model for traffic noise were utilized in the analysis of a double-decked road structure with fences only at ground (Case 1) and at both ground and upper deck (Case 2). Porous fences were assumed only at the ground level since the solid fences at the upper deck usually leads to desirable result on air pollution. Effects of the variable porosity on air quality and noise level near road were evaluated. Obtained results showed: (1) flow pattern in leeward of fence was drastically changed at 40–50% porosity in Case 1 and 50% in Case 2. The porosity larger than 40% excluded presence of a circulation behind the fence. (2) Effect of porous fence on air pollution was different in Cases 1 and 2. In Case 1, the porous fence generally resulted in the reduction of air pollution at the ground level; on the other hand, in Case 2, it rather led to increase of the concentration. (3) Traffic noise level was also largely changed by the porosity of the fence; an example of simultaneous evaluation of the effects of porous fence on both air and noise pollution in Case 1 showed that the fence of 60% porosity leads to reduction of air pollution by 20% compared with solid fence case, and reduction of noise pollution by 4–6% in dB compared with no fence case, at l m high and 10 m from the road. 相似文献
15.
Li Ning Li Guangming Yao Zhenya Zhao Jianfu 《Frontiers of Environmental Science & Engineering in China》2007,1(2):190-195
Catalytic wet air oxidation (CWAO) is one of the most promising technologies for pollution abatement. Developing catalysts
with high activity and stability is crucial for the application of the CWAO process. The Mn/Ce complex oxide catalysts for
CWAO of high concentration phenol-containing wastewater were prepared by coprecipitation. The catalyst preparation conditions
were optimized by using an orthogonal layout method and single-factor experimental analysis. The Mn/Ce serial catalysts were
characterized by Brunauer-Emmett-Teller (BET) analysis and the metal cation leaching was measured by inductively coupled plasma
torch-atomic emission spectrometry (ICP-AES). The results show that the catalysts have high catalytic activities even at a
low temperature (80°C) and low oxygen partial pressure (0.5 MPa) in a batch reactor. The metallic ion leaching is comparatively
low (Mn<6.577 mg/L and Ce<0.6910 mg/L, respectively) in the CWAO process. The phenol, CODCr, and TOC removal efficiencies in the solution exceed 98.5% using the optimal catalyst (named CSP). The new catalyst would
have a promising application in CWAO treatment of high concentration organic wastewater.
Translated from Techniques and Equipment for Environmental Pollution Control, 2005, 6(2): 40–44 [译自: 环境污染治理技术与设备] 相似文献
16.
OnthedeterminationofnitrousoxideemissionfactorduringbiomassburningCaoMeiqiu;ZhuangYahui(ResearchCenterforEco-EnvironmentalSci... 相似文献
17.
锦州湾表层沉积物中铅、锌、镉在各地球化学相间的分配规律 总被引:3,自引:0,他引:3
研究了受重金属严重污染的锦州湾内表层沉积物中铅、锌、镉在各地球化学相间的含量,及其在湾内河水-海水混合界面附近各相间的迁移转化特征。结果表明,锦州湾表层沉积物中上述重金属以非残渣相为主要存在形式,其中铁锰氧化物为重要的清除载体;以铁锰氧化物和碳酸盐形式存在的重金属含量由水环境的E_H和pH控制;在污染源附近的海区,表层沉积物中重金属在非残渣相和残渣相间的比值与近岸锌厂排出的这些重金属在废水和废渣中的含量比呈正相关关系。 相似文献
18.
田博 《辽宁城乡环境科技》2007,27(1):19-21
介绍了将铁法煤业(集团)有限责任公司三台子矿区污水处理工程工艺由以卡鲁塞尔氧化沟为主体的二级生化处理工艺改造为更适宜在北方气候条件下运行的A-O法工艺;同时对系统的启动进行了介绍。 相似文献
19.
液相加热法制备了Al2O3作为光催化剂,研究了不同光源、光照时间、催化剂用量和溶液酸度等条件对常见有机染料光催化降解性能影响。结果表明,用太阳光作为光源照射3h,50mL染料溶液中加入Al2O3 30mg,溶液pH8~10,孔雀石绿,酚藏花红,甲基紫等染料脱色率达93%以上。将使用过的Al2O3经过简单处理,孔雀石绿溶液脱色率仍达到94.1%,催化性能稳定,可以重复利用。通过紫外可见光谱分析,表明染料分子在催化剂和光照条件下发生了降解。 相似文献
20.