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71.
72.
Haruhiro Ino Yoshihisa Matsumoto Ryo Takahashi Kazukiyo Takami Junya Nishino Masaaki Itoh 《Journal of Material Cycles and Waste Management》2008,10(2):129-133
H-ZSM-5 zeolite-supported gallium oxides were studied as aromatization catalysts for polyolefin pyrolysate. The catalysts
were prepared by a conventional physical mixing method with a gallium content of 1.0 and 4.5 wt% and were reduced in flowing
hydrogen at 585°C. To test their activity, a polyolefin sample was pyrolyzed and passed over a heated catalyst layer; the
product was analyzed by gas chromatography/mass spectrometry. A continuous-flow fixed-bed reactor was used for aromatization
of a model gas of polyolefin pyrolysate. For chlorine-free sources at 450°C, the catalyst with only 1.0 wt% gallium exhibited
activity comparable to a gallium silicate catalyst. For chlorine-contaminated sources, the catalyst with 4.5 wt% gallium sustained
catalytic activity for long periods. From the activity test results, it was found that zeolite-supported gallium catalysts
prepared by the physical mixing method are suitable for converting polyolefin into aromatic hydrocarbons. 相似文献
73.
Mercuric reductase is detected in Cephalosporium tabacinum F2.The enzyme, which is an intracellular one,catalyzes the reduction of mercuric ions to elemental mercury,which requires NADH as an electron donor and added sulfhydryl compound.The optimum temperature and pH of the enzymatic reaction are 30℃ and 7.0- 8. 0,respectively.The enzyme activity is stable in the range of 25- 30℃ for 40min,and stable at pH 7. 0 for 2 hours. Metal ions such as Ag+ ,CO2+), Cu2+,Zh2+, Mn2+,Ni2+ show different degrees of inhibitory effect on the enzyme activity,other compounds such as phenylmercury acetate and potassium ferricyanide also partially inhibit the enzyme activity. 相似文献
74.
时英杰 《辽宁城乡环境科技》2006,26(2):25-27
当水温低于10℃时,常规生化法中的微生物活性迅速下降,水处理效果急剧下降。研究分离出冷适应微生物用于低温生活污水的处理。实验证明北方地区市政下水道里的沉淀物中存在着耐冷细菌,它们均能在10℃以下生长、繁殖。 相似文献
75.
植物对重金属的抗性和抗性代价 总被引:5,自引:1,他引:5
本文就植物对重金属污染的长期适应产生抗性、抗性试验技术及抗性代价几个方面的研究进行了简要论述和初步探讨。 相似文献
76.
研究了细菌农药降解质粒P~(JP4)向根瘤菌的转移以及农药降解质粒引入根瘤菌后,对其共生性、固氮能力和根瘤结构的影响。结果表明,三种根瘤菌受体均接受了农药2,4-D降解质粒P~(JP4)。转移频率在4.0×10~(-6)—6.4×10~(-6)之间。其中一个受体菌株在灭菌土壤中接受该质粒,其转移频率为5.1×10~(-7)。接受了农药降解质粒的接合子保持了根瘤菌的共生性状、乙炔还原活性,所形成的根瘤结构与亲本株没有明显差别。从根瘤中分离的接合子仍保持了质粒P~(JP4)。 相似文献
77.
Petrochemical buildings are usually distributed near chemical installations and have a high risk of explosion because of the concentration of people. In order to effectively design and protect buildings against explosion, it is needed to determine the blast-resistant and defense loads reasonably. Based on the theory of risk, a triangular pyramid explosion risk model was established in this study, which combined the overpressure p, duration t, and frequency f of the explosion scene at the same time. The first principle of “acceptable cumulative frequency” and the key principle of “maximum explosion risk” were formulated. According to this method, the explosion risk of eight leakage units with 10 groups of leakage hole size and three dangerous wind directions were obtained. According to the cumulative explosion frequency curve and the explosion risk curve, blast-resistant and defense loads of the four walls were determined quantitatively. Among the four walls, the explosion overpressure were 44.0–74.5 kPa, and the corresponding duration were 34.1–39.1 ms. The cumulative explosion frequency were 2.11E−5 to 8.58E−5 times annually. The explosion risk value were 3.64E−3 to 5.35E−3 kPa·ms annually. The results indicated that it was of great importance for the calculation of the explosion risk to reasonably divide the leakage unit and determine the leakage frequency. The explosion scene and its frequency, the volume of the obstructed region, and the distance of the explosion source were the key variables that affected the explosive load. The final blast-resistant and defense load values were found in the case of the middle hole size leakage. Blast-resistant and defense loads not only met the risk acceptance standard but also considered the overpressure and the duration of explosion. At present, they have been extensively applied in the blast-resistant design and engineering transformation of buildings in SINOPEC. 相似文献
78.
生物实验室产生的废弃重组基因片段的排放是造成.基因污染"的途径之一.热处理是目前生物实验室处置废弃重组基因片段、核酸等物质的主要手段.以pET-28b质粒为材料,采用定量PCR技术结合电泳和质粒转化等手段分析了重组基因片段在热处理过程中的降解与失活规律,以及不同离子强度对重组质粒热降解的影响.结果显示,100℃热处理过程中质粒 pET28b 的降解随时间变化较为明显,降解半衰期约为2.7min;处理30min后仍存在具有转化活性的质粒;实验结果表明,100℃热处理后的废弃重组基因片段排入自然生态系统后仍存在基因转移的可能性. 相似文献
79.
80.
利用岛津DTG-60H型热重分析仪,在氮气气氛、升温速率为15 ℃/min条件下,对自行配制的一种超薄型钢结构防火涂料的热分解过程进行了分析,发现该防火涂料的热解过程可分为5个阶段.用Coats-Redfern积分方法分阶段对TG曲线数据进行了处理,并用常见的12种反应机理方程进行拟合,发现各阶段反应机理不尽相同: 第一阶段属于一维扩散反应机理D1,第二、第三阶段为1.5级化学反应模型RO(1.5),第四阶段为二级化学反应模型RO(2),第五阶段为一级化学反应模型RO(1).同时,求解出了各阶段的热解动力学参数及动力学方程. 相似文献