中国地区二次有机气溶胶的时空分布特征和来源分析

二次有机气溶胶(SOA)由于其在大气污染、气候变化与人体健康方面的影响,是我国大气环境中一种重要的污染物.确定中国SOA分布规律以及产生来源是大气污染防治的前提.利用全球化学传输模型(Model for Ozone and Related Chemical Tracers,Version 4,MOZART4)并集成多相SOA参数化方案,模拟了中国地区SOA的时空分布,并按前体物分区域进行了来源分析.结果表明,受SOA前体物排放分布的影响,中国地区的SOA主要分布在东部和南部地区,并且夏季SOA产量是冬季产量的2.5倍.中国地区分布的SOA由人为源排放产生占55%,高于自然源(45%);并且境内排放贡献了我国SOA产量的77%,主要影响东部近地面大气的浓度分布.境外排放主要影响我国西部地区,尤其是对高空SOA分布影响显著.     

金华地区PM2.5中的极性有机示踪物

用GC/MS,对金华地区3个采样点、四个季节,225个PM_(2.5)样品中10种极性有机示踪化合物进行了分析,包括天然源:3个异戊二烯SOA示踪物、1个α-蒎烯SOA示踪物和2个真菌孢子示踪物,和人为源:1个甲苯SOA示踪物、3个生物质燃烧示踪物.结果表明,异戊二烯SOA示踪物浓度为3.41~48.50 ng·m~(-3),α-蒎烯SOA示踪物浓度为2.45~25.40 ng·m~(-3),甲苯SOA示踪物为4.75~39.80 ng·m~(-3).各SOA示踪物均有明显的季节变化,其中,异戊二烯SOA示踪物呈夏季秋季≈春季冬季,α-蒎烯SOA示踪物夏季春季≈秋季冬季,甲苯SOA示踪物秋季夏季春季冬季.估算得出甲苯SOC对OC的贡献为3.03%~24.50%,而来源于生物质燃烧的有机碳对OC的贡献可以达到1.23%~42.80%.表明人为源排放前体物的二次转化以及生物质燃烧是金华地区大气细颗粒物污染的重要来源.     

Treatment of digestate from a co-digestion biogas plant by means of vacuum evaporation: Tests for process optimization and environmental sustainability

Vacuum evaporation consists in the boiling of a liquid substrate at negative pressure, at a temperature lower than typical boiling temperature at atmospheric conditions. Condensed vapor represents the so called condensate, while the remaining substrate represents the concentrate.This technology is derived from other sectors and is mainly dedicated to the recovery of chemicals from industrial by-products, while it has not been widely implemented yet in the field of agricultural digestate treatment. The present paper relates on experimental tests performed in pilot-scale vacuum evaporation plants (0.100 and 0.025 m³), treating filtered digestate (liquid fraction of digestate filtered by a screw-press separator). Digestate was produced by a 1 MW_e anaerobic digestion plant fed with swine manure, corn silage and other biomasses. Different system and process configurations were tested (single-stage and two-stage, with and without acidification) with the main objectives of assessing the technical feasibility and of optimizing process parameters for an eventual technology transfer to full scale systems.The inputs and outputs of the process were subject to characterization and mass and nutrients balances were determined.The vacuum evaporation process determined a relevant mass reduction of digestate.The single stage configuration determined the production of a concentrate, still in liquid phase, with a total solid (TS) mean concentration of 15.0%, representing, in terms of mass, 20.2% of the input; the remaining 79.8% was represented by condensate. The introduction of the second stage allowed to obtain a solid concentrate, characterized by a content of TS of 59.0% and representing 5.6% of initial mass.Nitrogen balance was influenced by digestate pH: in order to limit the stripping of ammonia and its transfer to condensate it was necessary to reduce the pH. At pH 5, 97.5% of total nitrogen remained in the concentrate. This product was characterized by very high concentrations of total Kjeldhal nitrogen (TKN), 55,000 mg/kg as average.Condensate, instead, represented 94.4% of input mass, containing 2.5% of TKN. This fraction could be discharged into surface water, after purification to meet the criteria imposed by Italian regulation. Most likely, condensate could be used as dilution water for digestion input, for cleaning floor and surfaces of animal housings or for crop irrigation.The research showed the great effectiveness of the vacuum evaporation process, especially in the two stage configuration with acidification. In fact, the concentration of nutrients in a small volume determines easier transportation and reduction of related management costs. In full scale plants energy consumption is estimated to be 5–8 kWh_e/m³ of digestate and 350 kWh_t/m³ of evaporated water.     

ESTIMATION OF ENERGY REQUIREMENTS OF MORNING DEW EVAPORATION FROM LEAF SURFACES1

ABSTRACT: Evapotranspiration from vegetation is generally computed without consideration for early morning energy loss involved in drying wet leaf surfaces. In humid areas where dew formation is frequent, estimation of energy requirements for evaporating dew should be of interest. In this study, sensible heat flux (H) was computed from wind and temperature profile measurements over the study site. A leaf wetness sensor was used to measure the duration of evaporation from an exposed leaf surface, and net radiation was measured with a radiometer. The energy flux during the period of wet leaf surface evaporation was integrated over time. A cattail lysimeter situated at the site indicated the time when evapotranspiration started after wet leaves were dry. The energy requirements to dry an exposed wet leaf surface was estimated using energy balance methods. The mean value based on 44 days of observations from mid February to early May of 1993 indicates that the energy required to evaporate dew from openly exposed wet leaves was 5 percent of the total daily evapotranspiration of cattails with a coefficient of variation of 0.72. The mean time required to evaporate dew from exposed leaf surfaces from the onset of positive net radiation was 78 minutes. The mean dew evaporation in a morning from an exposed leaf surface was 0.16 mm with a maximum value of 0.41 mm. The energy required to dry wet leaves is a factor that should be considered when modeling evapotranspiration at hourly or shorter time intervals. Also, physical evapotranspiration models need to account for energy requirements for drying dew and rainfall wetted leaves.     

Vermiculture and waste management: study of action of earthworms Elsinia foetida, Eudrilus euginae and Perionyx excavatus on biodegradation of some community wastes in India and Australia

The practice of vermiculture is at least a century old but it is now being revived worldwide with diverse ecological objectives such as waste management, soil detoxification and regeneration and sustainable agriculture. Earthworms act in the soil as aerators, grinders, crushers, chemical degraders and biological stimulators. They secrete enzymes, proteases, lipases, amylases, cellulases and chitinases which bring about rapid biochemical conversion of the cellulosic and the proteinaceous materials in the variety of organic wastes which originate from homes, gardens, dairies and farms. The process is odour free because earthworms release coelomic fluids in the decaying waste biomass which has anti-bacterial properties which kills pathogens. The species used in India were Indian blue (Perionyx excavatus), African night crawler (Eudrilus euginae) and the Tiger worm (Elsinia foetida). E. foetida was used in Australia. E. euginae was found to have higher feeding, growth and biodegradation capacity compared to other two species.Earthworm action was shown to enhance natural biodegradation and decomposition of wastes (60–80 percent under optimum conditions), thus significantly reducing the composting time by several weeks. Within 5 to 6 weeks, 95–100 percent degradation of all cellulosic materials was achieved. Even hard fruit and egg shells and bones can be degraded, although these may take longer.     

垃圾填埋二次污染的危害与防治

介绍了垃圾卫生填埋中二次污染的危害,指出垃圾卫生填埋场建设和填埋操作中为防止填埋释放物对周围环境的二次污染所应采取的防渗、收集、处理和利用等措施,探讨了在垃圾卫生填埋场建设和填埋操作中应注意的问题及应着重考虑的方面.     

PROBABILISTIC GREAT LAKES HYDROLOGY OUTLOOKS1

ABSTRACT: The Great Lakes Environmental Research Laboratory developed a semiautomatic software package for making hydrological outlooks for the Great Lakes. These include basin moisture storages, basin runoff, lake heat storage, lake evaporation, heat fluxes, and net lake supplies, one or more full months into the future. The package combines GLERL's rainfall-runoff and lake evaporation models with near real-time data reduction techniques to represent current system states. Users select historical meteorologic record segments as candidate future scenarios to generate deterministic near real-time hydrological outlooks. GLERL has extended the package to make probabilistic outlooks for a decision-maker who must estimate the risk associated with his decisions. GLERL matches National Weather Service meteorologic outlook probabilities by selecting groups of historical meteorologic sequences, and constructs embedded outlook intervals for each hydrologic variable of interest. Interval probabilities are assigned from comparisons over a recent evaluation period. This physically-based approach for generating outlooks offers the ability, as compared to other statistically-based approaches, to incorporate improvements in the understanding, of process dynamics as they occur in the future and to respond reasonably to conditions initial to a forecast (such as heat and moisture storages), not observed in the past.     

RELATIVE RATES OF EVAPORATIVE WATER LOSSES FROM OPEN AND VEGETATION COVERED WATER BODIES1

ABSTRACT: A review of literature pertaining to the relative rates of evaporation from vegetation covered and open water bodies is presented. The review indicates that the only reliable experiments capable of correctly addressing this question are those conducted in situ. Experiments of this nature show the ratio of vegetation covered (swamp) evaporation to open water evaporation to generally be less than unity over extensive surfaces and to only approach unity for vegetation that is young and vigorous. Recent experimental evidence presented within a theoretical context, however, indicates that even in the latter situation the ratio may never reach unity. Consequently, over large lakes and reservoirs, the presence of vegetation may actually be a water conservation mechanism, with the eradication of the vegetation leading to significantly increased evaporative water losses.     

东涌工业污水处理站污泥处置方法的研究和探讨

本文通过番禺区东涌工业污水处理站污泥特性和污泥堆肥技术的研究,提出了污泥堆肥的可行性,并用之于实践,变废为宝,解决了污泥的处置问题.     

Management of an Agroecosystem

Agroecosystems (AESs) are autotrophic ecosystems managed by man. The goal of the management is to obtain the maximum possible amount of high-quality agricultural products while preserving agricultural resources, primarily the soils and biodiversity. The main components of the management of AES structures and functions, including primary and secondary biological production, the ratio between the energy flows in the plant–man and plant–livestock–man food chains, the efficiency of energy transfer in the plant–livestock link, and conservation of agricultural resources, are considered.