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71.
应用激光粒度粒形分析仪、灰熔融性测定仪、原子吸收光谱仪和XRD等仪器手段对国内2种垃圾焚烧飞灰的密度、颗粒特性、熔点、成分和晶相结构等物理化学性质进行了详细的研究。研究发现,2种灰样颗粒直径的数量积分分布非常接近,其中基本没有超过40/μm的颗粒。由于垃圾焚烧飞灰在化学成分上存在的差异导致了其熔点有很大的不同。此外,XRD结果显示不同来源的飞灰其晶相结构存在较大的差别,这可能与垃圾的来源和焚烧工艺以及烟气处理方法有关。实验结果为飞灰无害化低温烧结工艺的选择和运行参数的制定提供了依据。 相似文献
72.
Robert France 《Environmental management》1996,20(2):249-255
Due to assimilation of recycled CO2 from litter decomposition and photosynthetic changes in carbon fractionation at low light levels, the foliage at the base of a forest is often more depleted in13C compared to that exposed to the atmosphere in either the canopy or in open clearings. This is referred to as the canopy effect. African research has indicated that these habitat differences in foliar 13C can be substantial enough to affect the carbon isotope ratios of resident fauna. Previous work documenting a 30-year chronology on moose teeth from Isle Royale National Park indicated a progressive depletion in13C and suggested that this could be due to forest regrowth following extensive burning. The present study examined the assumption implicit in this hypothesis that foliar 13C varies between open and closed boreal forest sites. I found a marginal canopy effect of 2 13C difference between upper canopy and ground flora for a forest in northwestern Ontario and an average difference of 1.2 in under- and mid-story vegetation between closed forests and open clear-cuts. Because of these small differences, the utility of carbon isotope analysis in quantifying temporally integrated exploitation of deforested habitats will be low for northern boreal locations. In denser forests, such as those in the tropics or western North American where the canopy effect can be expected to be much greater, 13C analysis may still offer some promise for determining selection by wildlife of disturbed habitats. 相似文献
73.
Atsuyoshi Nakayama Norioki Kawasaki Ioannis Arvanitoyannis Seiichi Aiba Noboru Yamamoto 《Journal of Polymers and the Environment》1996,4(3):205-211
Biodegradable polyesters were synthesized by ring-opening copolymerization of -butyrolactone (BL) and its derivatives withl-lactide (LLA). Although tetraphenyl tin was the main catalyst used, other organometallic catalysts were used as well.1H and13C NMR spectra showed that poly(BL-co-LLA)s were statistical and that their number-average molecular weights were as high as 7×104. The maximum BL content obtained from copolymerization BL/LLA was around 17%. TheT
m andT
g values of the copolymers showed a gradual depression with an increase in BL content. NoT
m was obtained for the copolymers containing more than 13 mol% BL. The biodegradability of the copolyesters was evaluated by enzymatic hydrolysis and nonenzymatic hydrolysis tests. The enzymatic hydrolysis was carried out at 37°C for 24 h using lipases fromRhizopus arrhizus andR. delemar. Hydrolyses by both lipases showed that an increase in BL content of the copolymer resulted in enhanced biodegradability. Nonenzymatic accelerated hydrolysis of copolymers at 70°C was found to increase proportionally to their exposure time. The hydrolysis rate of these copolymers was considerably faster than that of PLLA. The higher hydrolyzability was recorded for the BL-rich copolymers. The copolymerization of -methyl--butyrolactone (MBL) or -ethyl--butyrolactone (EBL) with LLA resulted in relatively LA-rich copolymers. 相似文献
74.
J. J. Jesudason R. H. Marchessault T. Saito 《Journal of Polymers and the Environment》1993,1(2):89-98
The synthetic analogue of a bacterially produced polyester, poly(-hydroxybutyrate) (PHB) was synthesized from racemic -butyrolactone using anin situ trimethyl aluminum-water catalyst. The polymer was fractionated into samples differing in molecular weight and isotactic diad content. The latter was closely related to degree of crystallinity. The biodegradation of these fractions were examined by monitoring mass loss over time in the presence of anAlcaligenes faecalis T1 extracellular bacterial poly(-hydroxybutyrate) depolymerase. The fraction with high isotactic diad tacticity content showed little or no degradation over a 50 hour incubation period, whereas the fraction of intermediate isotactic diad content degraded in a continuous steady fashion at a rate that was less than that for bacterial PHB. The low isotactic diad fraction underwent a rapid initial degradation, followed by no further mass loss. The presence of stereoblocks in the polymer structure of the various fractions was an influence on the degree of susceptibility towards degradation and is related to sample crystallinity. 相似文献
75.
以铬渣和粉煤灰为混合填充体系的主要填料,采用柱子淋洗法,通过改变混合填料的配比来研究其对铬渣中Cr(Ⅵ)的阻留作用。试验结果表明,各种混合填充体系对Cr(Ⅵ)均有一定程度的阻留作用,其中I—5校对Cr(Ⅵ)的阻留固定效果最佳,淋出液中Cr(Ⅵ)的质量分数为0.删%,相对阻留效果达94.53%。 相似文献
76.
77.
J. Y. Kim M.-C. Shin J.-R. Park K. Nam 《Journal of Material Cycles and Waste Management》2003,5(1):0055-0062
The effect of the soil solids concentration in batch tests on the measured values of the partition coefficient (K
p) of organic pollutants in landfill liner-soil material was investigated. Since this study was based on the results of batch
and column tests conducted independently, there were limitations to the conclusions derived. The organic compounds tested
were benzene, methylene chloride, toluene, trichloroethylene, and p-xylene. The results of this study showed that as soil solids concentrations increased, the measured K
p values of these organic compounds strongly decreased. The observed values of K
p stabilized when the soil solids concentration was above a certain value. Typical K
p values obtained from batch tests conducted under high soil solids concentrations were close to those obtained from column
tests. It was concluded that the K
p values of organic compounds measured under low soil solids concentrations, i.e., less than 100 g/l, may not correctly simulate
the field situation. Consequently, the values of K
p obtained with low soil solids concentrations can result in an overestimation of the retardation factor of the landfill liner
material.
Received: March 14, 2002 / Accepted: August 25, 2002 相似文献
78.
Occurence and Distribution of Polycyclic Aromatic Hydrocarbons in Ankara Precipitation 总被引:1,自引:0,他引:1
Urban atmospheric environment contains many trace organic pollutants that are related to the incomplete fuel combustion in domestic heating, industrial plants and automobile traffic. Removal of these pollutants from the atmosphere takes place through wet and dry deposition as well as chemical transformations. In this study, concentrations of polycyclic aromatic hydrocarbons (PAHs) in wet deposition samples were determined at an urban site of Turkey. Wet and dry deposition samples were collected using Andersen Rain Sampler. The sampler was modified accordingly for the collection of organic pollutants. Collected samples were preconcentrated by using solid phase extraction (SPE) disks and consecutively analyzed by Gas Chromatography-Mass Spectrometry (GC-MS). Among the 13 compounds quantified in this study, anthracene, fluoranthene, and pyrene were found more frequently and at elevated concentrations (202, 271 and 260 ng L-1 mean concentrations, respectively).Concentrations of PAHs were found to be high in winter period. 相似文献
79.
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