The composting potential of different organic solid wastes: experience from the island of Crete

For the past 20 years, the National Foundation for Agricultural Research in Crete and the School of Agricultural Technology of the Technological and Educational Institute of Crete have been involved in a number of research and development activities, related to the production and evaluation of compost derived from a variety of local solid, mainly agricultural organic wastes. Materials such as olive press cake, olive tree leaves (OTL) and branches, vine branches (VB), pressed grape skins (PGS), pig manure (PM), sewage sludge and the organic fraction of municipal solid waste (OFMSW) have been evaluated for their behaviour during composting, their compatibility in mixtures and the quality of the end product. The quality evaluation included both a detailed physiochemical (pH, electrical conductivity (EC), nutrients concentration, heavy metal concentration, etc.) and biological analyses (pathogenic microorganisms). It also included an agronomic evaluation, in which composts were used either as a soil amendment or as a component for substrates in open air or covered (greenhouse) cultivation mainly of local vegetables (tomatoes, cucumbers, etc.). All materials were composted successfully, especially when mixed. The end products contained large amounts of organic matter, usually combined with an increased EC value. Pressed grape skins should be considered as the ideal raw material, producing a high quality compost, with the lowest EC value (1.57 mS cm(-1)) and the largest organic matter concentration (84.50%), compared to all other materials. When any of the produced compost was used in a ratio of 30% by volume (v/v), it increased plant growth, whereas in larger volumes, it presented phytotoxic behaviour, inhibiting both root and shoot development.     

Microwave-Assisted Solvent-Free or Aqueous-Based Synthesis of Biodegradable Polymers

Microwave radiation was used as the energy source for various types of chemical derivatizations of polysaccharides and for the synthesis of biodegradable polyesters in solvent-free or aqueous-based reaction systems. A medium to high degree of substitution was obtained for starch acetates, starch succinates, carboxymethyl konjac, aminated starch, and aminated chitosan. Ring-opening polymerization of lactide and -caprolactone proceeded rapidly even at low power output in the presence of tin octanoate catalyst. Complete monomer conversion and high molecular weight were achieved in less than 6 minutes under nonisothermal conditions. The yield rapidly increased with increasing power output and showed no significant change in a wide range of batch sizes. Polycaprolactone was successfully grafted from starch and konjac acetate in 3 minutes, yielding as high as 24% grafting efficiency and 25% grafting degree.     

新疆油田稠油开发固体废物对环境的影响及处置措施

新疆油田九1～九5区稠油开发过程中,产生了大量的固体废物,主要包括落地原油、废钻井液和岩屑及原油处理站的含油泥砂,如果处理不当,会对环境造成极大的危害。通过对各主要污染物的环境影响分析,提出了几种针对性的防治措施,以确保油田开发实现清洁生产,达到经济效益、环境效益和社会效益统一。     

我国城市生活垃圾的处理和发展趋势

城市生活垃圾给城市环境造成了严重污染，威胁了城市居民的生存环境和经济、社会的可持续发展。目前，国内采取的垃圾处理技术主要有卫生填埋、焚烧、堆肥等，热解技术由于具有资源回收率高、二次污染小、综合效益好等优点，越来越适合我国中小城市的垃圾处理。垃圾气化技术的研究成为当今世界的热点。此外，我国对垃圾衍生燃料的研究也刚刚起步。为促进城市持续、稳定的发展，提出了垃圾分类收集、分拣、综合利用垃圾处理技术的措施。     

Compostability of Poly(lactide): Degradation in an Inert Solid Medium

Commercial poly(lactide) degradation was studied in an inert solid medium simulating compost conditions, with the aim to achieve a complete carbon balance of the polymer degradation. The mineralisation rate at the end of the test was compared to those obtained for poly(lactide) degradation in compost. It was shown that the mineralisation rate after 45 days of degradation was quite lower in inert solid medium than in compost but the standard deviation of data was enhanced. A protocol for both extraction and quantification of the carbon included in the different degradation by-products was proposed and the carbon balance of the polymer degradation was followed during the test with a satisfactory accuracy. The non-degraded PLA material was recovered during the test, hence the evolution of the glass transition temperature and the molecular weight was followed. A two-step degradation mechanism was highlighted in inert solid medium, showing the fundamental role of abiotic reactions for PLA degradation in compost.     

微生物絮凝剂处理造纸中段废水的实验研究

实验从土壤中分离筛选出1株絮凝活性较高的絮凝剂产生菌,经鉴定为1株黑曲霉.采用其产生的微生物絮凝剂M-2处理造纸中段废水,对絮凝条件进行了优化,在最佳絮凝条件下,M-2对造纸中段废水的CODcr去除率可达70.6%,浊度去除率可达91.7%,其絮凝效果优于传统的絮凝剂.     

生活垃圾卫生填埋场安全运行问题探讨

分析总结了垃圾填埋场的安全运行中常出现的4个安全问题,即沼气爆炸和火灾事故、边坡和大坝不稳定性造成滑坡、填埋区作业时存在较大的安全隐患、填埋场周边环境污染等。笔者以建设部科技示范工程广州市兴丰生活垃圾卫生填埋场成功的运行经验为例进行了探讨,提出了针对垃圾填埋场常见安全问题相应的解决办法,即科学的填埋场设计、完善的安全运行制度、规范的营运管理和营运监管相结合的管理模式等。     

Assessing instruments for mixed household solid waste collection services in the Flemish region of Belgium

Instruments to reduce waste can be divided into three groups: first, pecuniary incentives; second, service level; finally, measurements stimulating prevention and waste reduction. Also specific characteristics of the community determine the amount of waste generated. We evaluate whether findings in literature on effectiveness of policy measures are valid for Belgium, specifically for the Flemish region. The policy mix instituted by the Flemish authorities in the ‘implementation plan household waste 2003–2007’ and implemented by local authorities, is assessed. Multiple regression analysis identifies those measurements having the greatest impact on household solid waste.We found an income elasticity of 0.326. Also the provided service level has a significant impact. Pecuniary incentives are effective instruments in reducing waste, with a price elasticity of −0.139. Furthermore, a higher percentage of direct costs, directly attributable to waste services, borne by households, reduces waste. A consequent implementation of the ‘polluter pays’ principle proves to be effective.     

基于风险的检验(RBI)在国内合成氨装置中的应用

利用API581基于风险的检验原理,采用RISKWISE分析软件对九江石化合成氨装置中的设备和管道进行了风险评估;并在装置采用的工艺、不同装置的设备和管道的失效机理和计算出的风险分布这3方面,将其风险评估结果与国内兄弟单位完成的其他合成氨装置的风险评估结果进行了比对;其结果体现了我国目前合成氨装置的设备和管道风险的大致分布,可供我国其他合成氨装置的风险评估参考,也为制定我国合成氨装置基于风险检验的法规标准提供了相关数据;同时,对国内采用针对装置的基于风险的检验的新模式进行了探讨。     

响应面法优化养殖水体中炔雌醇的固相萃取条件

在单因素试验、Plackett-Burman设计试验基础上,采用Box-Behnken响应面法对养殖水体中炔雌醇(EE2)的固相萃取条件进行优化。结果表明,洗脱液体积、洗脱液组成和淋洗液体积是影响EE2固相萃取回收率的3个主要因素;EE2的最佳固相萃取条件为:水样pH值为3,进样流量为3.0 mL/min,淋洗液为体积分数为10%的甲醇水溶液,淋洗液体积7.0 mL,洗脱液为乙酸乙酯-正己烷混合溶液(体积比为9∶1),洗脱液体积12.0 mL。该条件下养殖水样中EE2固相萃取回收率为81.6%～86.7%。