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41.
Sulfur-containing amino acid methionine as the precursor of volatile organic sulfur compounds in algea-induced black bloom 总被引:2,自引:0,他引:2
After the application of methionine, a progressive and significant increase occurred in five volatile organic sulfur compounds (VOSCs): methanethiol (MeSH), dimethyl sulfide (DMS), dimethyl disulfide (DMDS), dimethyl trisulfide (DMTS) and dimethyl tetrasulfide (DMTeS). Even in the untreated control without a methionine addition, methionine and its catabolites (VOSCs, mainly DMDS) were found in considerable amounts that were high enough to account for the water’s offensive odor. However, blackening only occurred in two methionine-amended treatments. The VOSCs production was observed to precede black color development, and the reaching of a peak value for total VOSCs was often followed by water blackening. The presence of glucose stimulated the degradation of methionine while postponing the occurrence of the black color and inhibiting the production of VOSCs. In addition, DMDS was found to be the most abundant species produced after the addition of methionine alone, and DMTeS appeared to be the most important compound produced after the addition of methionine+glucose. These results suggest that methionine acted as an important precursor of the VOSCs in lakes suffering from algea-induced black bloom. The existence of glucose may change the transformation pathway of methionine into VOSCs to form larger molecular weight compounds, such as DMTS and DMTeS. 相似文献
42.
以炼钢过程中排放的固体废弃物钢渣为碳捕获剂,进行了钢渣湿法捕获烟气CO2工艺的实验研究。通过分析钢渣的组成成份及反应机理,研究液固比、反应温度、反应时间、pH值及反应产物等主要参数对钢渣湿法碳捕获状况的影响。实验证明,通过合理的设计和适当的操作,可使钢渣湿法碳捕获效率达60%以上,具有一定的应用价值。 相似文献
43.
以2001~2010年十年间天水市城区二氧化硫浓度与硫酸盐化速率的监测数据为依据,对城区二氧化硫与硫酸盐化速率的浓度水平和变化规律进行了研究,分析和探讨了二氧化硫浓度与硫酸盐化速率相关性。 相似文献
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文章主要通过对酸性水气体及硫磺回收工艺特点的介绍与比选,着重分析“无在线炉硫磺回收及尾气处理工艺”(SSR),其中硫回收为一段高温转化,二级催化转化的克劳斯工艺,尾气处理为加氢还原一吸收工艺,并介绍原辅材料成分及处理效率。该工艺能够有效解决石化企业的酸性气及酸水排放问题,具有良好的社会、环境效益显著。 相似文献
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XIE Jian-jun YANG Xue-min ZHANG Lei DING Tong-li SONG Wen-li LIN Wei-gang 《环境科学学报(英文版)》2007,19(1):109-116
This paper presents the experimental investigations of the emissions of SO2, NO and N2O in a bench scale circulating fluidized bed combustor for coal combustion and co-firing coal and biomass. The thermal capacity of the combustor is 30 kW. The setup is electrically heated during startup. The influence of the excess air, the degree of the air staging, the biomass share and the feeding position of the fuels on the emissions of SO2, NO and N2O were studied. The results showed that an increase in the biomass shares resulted in an increase of the CO concentration in the flue gas, probably due to the high volatile content of the biomass. In co-firing, the emission of SO2 increased with increasing biomass share slightly, however, non-linear increase relationship between SO2 emission and fuel sulfur content was observed. Air staging significantly decreased the NO emission without raising the SO2 level. Although the change of the fuel feeding position from riser to downer resulted in a decrease in the NO emission level, no obvious change was observed for the SO2 level. Taking the coal feeding position R as a reference, the relative NO emission could significantly decrease during co-firing coal and biomass when feeding fuel at position D and keeping the first stage stoichiometry greater than 0.95. The possible mechanisms of the sulfur and nitrogen chemistry at these conditions were discussed and the ways of simultaneous reduction of SO2, NO and N2O were proposed. 相似文献
49.
The off-gas handling system is a vital component of a smelter and it is essential that it operates in accordance with environmental regulations. A key feature of the off-gas management system is maintaining a slightly negative system pressure to prevent gas leakage, such as SO2, out into the work and external environments. To enhance sustainable development, there is also growing interest in capturing and reusing the significant amount of heat and CO2 contained within off-gas. The potential incorporation of heat and CO2 recovery systems places importance on enhancing control to minimize the risk of both gas leakage and disturbance of the smelting process. With these requirements in mind, an easily implementable feedforward control enhancement to existing control schemes is proposed to help provide improved performance. 相似文献
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