三唑磷农药废水厌氧处理可行性研究

采用厌氧流化率工艺处理在唑磷农药废水，必须降低原水中ＮＨ３－Ｎ含量，调整营养比例，当ＣＯＤ：Ｎ：Ｐ＝（１８０～２００）：５：１时，在中温厌氧消化条件下，ＣＯＤ含量可从４１７０ｍｇ／ｌ，去除率约５０％，沼气产率达到０．２５６ｍ＾３／ｍ＾３．ｄ。因此，把厌氧处理作为好氧处理的预处理单元，能确保整个处理系统出水达标。     

河流水污染定量研究进展

水质模型可定量地反映出水质状况与污染物排放之间的关系,从而为进行水质评价与预测、选择污染控制方案以及制定水质标准和排放污染规定提供可靠的依据.文章从建立模型所采用的数学方法角度出发,较为详细的概述了近年来水质模拟的研究进展,并对确定性模型所存在的问题和河流水质模型的发展趋势做出评价.     

一种新型复合式生物流化反应器混合特性的研究

对新型蜂窝状断面复合生物流化反应器进行了液体循环速率和水力停留时间分布曲线的测定，实验表明新型反应器具有抗冲击负荷强，接近CSTR反应器的特点，反应器随气量增大、载体投加量减少和进水量减少而更近似于CSTR反应器，通过理论分析，证明了影响液体循环速率的参数主要有气体流量(气含率)、反应器沿程和局部阻力系数以及Ad/Ar，并且得出液体循环速率与反应器高度的0．5次方成正比。     

甲烷高温自燃诱导过程实验与数值模拟研究

甲烷的转化在化工产业中具有举足轻重的地位与战略意义,近年来涌现的氧化偶联制烯烃等多种新型化工工艺涉及高温条件的甲烷-纯氧等体系的混合与反应过程,明确甲烷高温自燃诱导与爆炸规律是实现工艺安全设计与运行的前提,然而相关研究与基础数据仍较为欠缺。通过利用基于快速压缩装置的高温高压燃爆测试系统开展甲烷-纯氧等典型混合体系的自燃诱导过程研究,同时基于GRI-Mech 3.0机理的数值模拟方法进行了数值模拟研究。实验结果与数值模拟结果吻合较好,随着温度/压力的增加及氧气含量的下降,混合体系自燃诱导时间均缩短;燃料气中加入乙烷或氢气则会大幅缩短自燃诱导过程。对于多个工艺过程中涉及的低氧含量体系率先开展了研究,得到了不同当量比及温度条件下的典型体系自燃诱导时间,同时考察了惰性气的加入对于自燃诱导过程的延长作用。研究结果有助于深入理解甲烷自燃诱导机理,同时指导高温条件的甲烷转化工艺的本质安全化设计与爆炸防控。     

Treatment of 2-phenylamino-3-methyl-6-di-n-butylaminofluoran production effluent by combination of biological treatments and Fenton＇s oxidation

High strength refractory organic stream is produced during the production of 2-phenylamino-3-methyl-6-di-n-butylaminofluoran （One Dye Black 2, abbr. ODB 2）, a novel heat-sensitive material with a promising market. In this study, a combination of acidificationprecipitation, primary biological treatment, Fenton＇s oxidation and another biological treatment was successfully used for the removal of COD from 18000-25000 mg/L to below 200 mg/L from the ODB 2 production wastewater in a pilot experiment. A COD removal of 70%-80% was achieved by acidification-precipitation under a pH of 2.5-3.0. The first step biodegradafion permitted an average COD removal of 70% under an hydraulic residence time （HRT） of 30 h. By batch tests, the optimum conditions of Fenton＇s oxidation were acquired as： Fe^2＋ dose 6.0 mmol/L; H2O2 dose 3000 mg/L; and reaction time 6 h. The second step biological treatment could ensure an effluent COD below 200 mg/L under an HRT of 10 h following the Fenton＇s treatment.     

Determination and discussion hydraulic retention time in membrane bioreactor system

Based on the microorganism kinetic model, the formula for computing hydraulic retention time in a membrane bioreactor system (MBR) is derived. With considering HRT as an evaluation index a combinational approach was used to discuss factors which have an effect on MBR. As a result, the influencing factors were listed in order from strength to weakness as: maximum specific removal rate K, saturation constant Ks, maintenance coefficient m, maximum specific growth rate ,ua and observed yield coefficient Yobs. Moreover, the formula was simplified, whose parameters were experimentally determined in petrochemical wastewater treatment. The simplified formula is θ= 1.1( 1/β -1)(Kｓ S)/KXo , for oetroehemical wastewater treatment K and Ko eaualed 0.185 and 154.2, resoectively.     

液氯泄漏事故模拟分析

针对1996年1月21日在西班牙发生的一起液氯泄漏事故的后果进行了模拟分析。模拟分析结果同事故实际所造成的后果是一致的。表明采用基于数学模型的事故后果模拟分析具有一定程度的可靠性。对于救灾和对重大危险源编制应急事故预案有一定程度的指导意义。     

A THEORETICAL TRAVEL TIME BASED ON WATERSHED HYPSOMETRY1

ABSTRACT: The time to hydrograph peak of a watershed basin has been found to correlate with various statistical attributes (e.g., skewness and kurtosis) of its hypsometric curve (treated as probability distribution). This paper presents a theoretical travel time that is conceptually analogous to the time to hydrograph peak and can be calculated directly from the hypsometric curve of a watershed basin based on gravity and acceleration. The theoretical travel times for 23 selected watersheds in the United States are found to correlate significantly with their corresponding hypsometric attributes. In addition, the theoretical travel times are consistent with the times of concentration estimated from the Federal Aviation Administration method. Thus, this paper offers a simple theoretical explanation to the empirically identified linkage between time to hydrograph peak and hypsometric attributes. This theoretical travel time can provide an alternative way of characterizing the effects of basin morphometry on hydrologic response.     

Numerical Simulation of Synoptic Condition on a Severe Sand Dust Storm

By using observational data and MM5, an observational analysisand numerical study was conducted on the synoptic condition of a severe dust storm that was caused by a Mongolian cyclone whichoccurred from 6 to 8 April 2001. Results illustrated thatthe cyclogenesis was due to the isentropic potential vorticity (IPV) advection in the upper troposphere and the terrain modifiedbaroclinicity in the mid-lower troposphere. The Altai-Sayan complex of mountains blocked the lower level cold air and made the isentropic surface sharply steep. When the air slid down along the isentropic surface the increasing of baroclinicity anddecreasing of stability blew up the vertical vorticity development.The formation of the dust storm was a result of a cyclonic cold front passing across the area. The occurrence of this dust stormwas closely related to the strong surface wind, which was accompanied by a cold front passing, rather than the cyclogenesis, itself. Hence, the reason for the pre-front dust storm formulation was the formation of heating convection. Reasons behind the formation of a black storm (visibilitylower than 50 m), which occurred in the mid-north part ofInner Mongolia, lay in several aspects. Firstly, in thisarea the surface wind was strong, a direct result of thedownward transport in mid-lower troposphere. Secondly,the cold front passed over the effected area near sunsetso the air obtained much more surface heating to form adeeper mixed layer (ML). Thirdly, cooperation between thelower level wind and the terrain made the atmosphere inthis area and acquired the maximum advective contributionnecessary to form a deep post-front ML. The sensitivityexperiment revealed that surface heat flux was important to the frontal lifting. In addition, the forcing of surface heating wasalso seen as the primary forcing mechanism of frontogenesis. Meanwhile, removal of the surface heat flux made the atmosphericstratification became stable and the pre-storm ML very shallow,which weakened the strength of the dust storm.     

土地利用变化驱动下的上海市区水灾灾情模拟

对上海市区近50年来的土地利用结构变化进行了重建，并计算了由土地利用变化引起的上海市区水位变化量。以特定的1962年水灾为参照，模拟在同等雨强情况下，由土地利用结构变化和地面沉降引起的淹没范围的变化以及由此带来的水灾损失的变化。结果表明，在49mm／d降水条件下，由于土地利用的变化，使2001年的径流系数比1950年增大了34．0％，2001年的水位比1950年增高了45．9％；2001年的水灾灾情为1950年的1．0629倍；即使在目前千年一遇的防洪标准下，亦可造成相当于2001年地均GDP值0．088％(约为4．5亿元人民币)的损失，这是1991年相应数值的220倍。