一种高效测试污泥可生物降解性的实验方法研究

污泥的可生物降解性能由其有机组分的生物可及度和组分分子的复杂度共同决定。通过采用化学分级提取方法研究污泥组分的生物可及度,使用不同强度的提取溶液分离出4种化学可及度不同的提取组分,同时结合三维荧光光谱法对各组分中有机物质的复杂度进行分析。分析结果表明:组分的化学可及度与其生物可及度之间存在正相关关系;生物可及度较高,其成分有机物分子结构简单的组分SPOM(soluble particulate organic matter,SPOM)与REOM(readily extractible organic matter,REOM)在厌氧消化过程中降解率较高,分别为59.2%与46.3%的COD;而生物可及度低,组成复杂的组分SEOM(slowly extractible organic matter,SEOM)与PEOM(poorly extractible organic matter,PEOM)的生物降解率分别只有18.4%和5.8%的COD。     

基于Delft3D模型的三峡航道环保疏浚水质数值模拟研究

以忠县皇华城河段为例,利用Delft3D数学模型对三峡航道环保疏的水质变化进行了数值模拟。结果表明:疏浚工程的进行对河道水质环境影响比较明显,随水流方向污染物质量浓度上升速率变慢,在疏浚点污染物质量浓度上升245 mg/L,疏浚点下方4 km处污染物质量浓度上升约为20 mg/L,河段末端污染物质量浓度上升约为14 mg/L;疏浚工程结束后,河段的水体水质能够较快得到恢复,离疏浚点越近恢复得越快,疏浚结束1 d后污染物质量浓度基本已恢复到本底值,疏浚工程对水环境的影响可以较快得到恢复。     

羟基镧改性树脂的制备及其对氟离子的吸附

采用共沉淀法制备了羟基镧改性D101树脂复合吸附剂,利用扫描电子显微镜及能谱分析仪、红外光谱和比表面积分析仪对复合吸附剂的结构和形貌进行了分析,并对水溶液中氟离子(F~-)进行吸附研究,探讨了该复合吸附剂对F~-的吸附特性,并将其应用于实际含氟废水的处理。结果表明:在25℃、F~-初始质量浓度为10 mg/L、吸附剂量为0.4 g/L、溶液pH=5时,F~-吸附量最大,为24.45 mg/g;复合吸附剂对F~-的吸附动力学数据遵循拟二级动力学反应模型,整个吸附反应为多级控制过程;复合吸附剂对F~-的吸附符合Langmuir吸附等温模型,在10℃、25℃和35℃下,吉布斯自由能(ΔGo)均小于0,焓变(ΔHo)大于0,熵变(ΔSo)大于0,表明该吸附反应为自发吸热熵增过程。采用羟基镧改性D101树脂复合吸附剂可以有效去除实际含氟废水中的氟化物,实现废水的达标排放。     

基于信息融合的建筑施工安全预警管理研究

针对建筑业安全事故率居高不下的现状,找出事故频发的主要原因。基于主要原因中人、机、环境和管理4方面数据和信息的复杂性、不确定性,提出采用信息融合技术的D-S证据理论法对建筑施工全过程中的人、机、环境、管理4方面的数据和信息进行分析和预测,并构建建筑施工安全预警管理预测模型。该预测模型能判断建筑施工项目的"安全状态",能解决建筑施工中安全事故及危险源的预测问题;同时针对具体情况采取防范措施,及时矫正安全隐患和确保安全施工。将D-S证据理论法应用于建筑施工安全预警管理中,扩展了建筑施工安全管理的手段。     

单轴压缩下中部锁固岩桥变形破坏模式及演化机制研究

为了探究锁固岩桥破坏模式及演化机制，通过在完整试样端部预制裂隙以形成中部岩桥，采用物理试验和RFPA2D数值模拟方法，研究不同锁固岩桥角度试样破坏模式及裂隙扩展演化机制的影响规律，并利用断裂力学理论分析岩桥裂隙扩展机理。研究结果表明:利用数字图像技术，从定量角度分析裂隙扩展类型，得出试验试样最终破坏是由前期损伤不断积累所导致的结果；锁固段岩桥角度α对锁固段的破坏有重要影响，当α≤90°时，锁固岩桥段发生张拉贯通破坏；当90°＜α＜120°时，锁固岩桥段发生张拉剪切贯通破坏；当α≥120°时，锁固岩桥段并没有发生贯通破坏。最终得出3种试样破坏模式:下部裂隙张拉扩展，贯通中部岩桥；上下部裂隙同时张拉扩展，剪切贯通中部岩桥；下部裂隙张拉扩展，贯通试样上端面，中部岩桥没有发生破坏。     

基于DEA的我国能源R＆D经费配置评价研究

在对我国能源R＆D强度分析的基础上，运用DEA理论的C^2R模型对我国能源产业及其5个行业2001--2010年的R＆D经费投入、产出状况进行了实证分析。研究中用R＆D经费存量值来代替当年的R＆D经费值，得到各年的R＆D经费配置的相对效率和规模收益情况，找出R＆D经费配置配置存在的问题，有利于对我国能源R＆D经费的投人产出结构进行分析，提出优化国家能源R＆D经费配置的对策和建议。     

Estimation of transport parameters of phenolic compounds and inorganic contaminants through composite landfill liners using one-dimensional mass transport model

One-dimensional (1D) advection–dispersion transport modeling was conducted as a conceptual approach for the estimation of the transport parameters of fourteen different phenolic compounds (phenol, 2-CP, 2-MP, 3-MP, 4-MP, 2-NP, 4-NP, 2,4-DNP, 2,4-DCP, 2,6-DCP, 2,4,5-TCP, 2,4,6-TCP, 2,3,4,6-TeCP, PCP) and three different inorganic contaminants (Cu, Zn, Fe) migrating downward through the several liner systems. Four identical pilot-scale landfill reactors (0.25 m³) with different composite liners (R1: 0.10 + 0.10 m of compacted clay liner (CCL), L_e = 0.20 m, k_e = 1 × 10⁻⁸ m/s, R2: 0.002-m-thick damaged high-density polyethylene (HDPE) geomembrane overlying 0.10 + 0.10 m of CCL, L_e = 0.20 m, k_e = 1 × 10⁻⁸ m/s, R3: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick bentonite layer encapsulated between 0.10 + 0.10 m CCL, L_e = 0.22 m, k_e = 1 × 10⁻⁸ m/s, R4: 0.002-m-thick damaged HDPE geomembrane overlying a 0.02-m-thick zeolite layer encapsulated between 0.10 + 0.10 m CCL, L_e = 0.22 m, k_e = 4.24 × 10⁻⁷ m/s) were simultaneously run for a period of about 540 days to investigate the nature of diffusive and advective transport of the selected organic and inorganic contaminants. The results of 1D transport model showed that the highest molecular diffusion coefficients, ranging from 4.77 × 10⁻¹⁰ to 10.67 × 10⁻¹⁰ m²/s, were estimated for phenol (R4), 2-MP (R1), 2,4-DNP (R2), 2,4-DCP (R1), 2,6-DCP (R2), 2,4,5-TCP (R2) and 2,3,4,6-TeCP (R1). For all reactors, dispersion coefficients of Cu, ranging from 3.47 × 10⁻⁶ m²/s to 5.37 × 10⁻² m²/s, was determined to be higher than others obtained for Zn and Fe. Average molecular diffusion coefficients of phenolic compounds were estimated to be about 5.64 × 10⁻¹⁰ m²/s, 5.37 × 10⁻¹⁰ m²/s, 2.69 × 10⁻¹⁰ m²/s and 3.29 × 10⁻¹⁰ m²/s for R1, R2, R3 and R4 systems, respectively. The findings of this study clearly indicated that about 35–50% of transport of phenolic compounds to the groundwater is believed to be prevented with the use of zeolite and bentonite materials in landfill liner systems.     

Perspectives on community representation within the Extractive Industries Transparency Initiative: Experiences from south-east Madagascar

This article critically examines the nature and quality of governance in community representation and civil society engagement in the context of trans-national large-scale mining, drawing on experiences in the Anosy Region of south-east Madagascar. An exploration of functional relationships between government, mining business and civil society stakeholders reveals an equivocal legitimacy of certain civil society representatives, created by state manipulation, which contributes to community disempowerment. The appointment of local government officials, rather than election, creates a hierarchy of upward dependencies and a culture where the majority of officials express similar views and political alliances. As a consequence, community resistance is suppressed.     

基于虚拟现实技术的喷射火事故三维动态仿真及应用

基于Shell模型的原理和计算方法,把喷射火焰视为近似倒立圆台形,构建了不同风向影响下的喷射火三维模型,运用虚拟现实技术和三维可视化技术对喷射火事故进行模拟与仿真。以Delphi和OpenGL/GLScene为开发工具,实现了喷射火三维模型的程序化与三维场景绘制,同时引入粒子特效系统,实现了喷射火焰燃烧的实时动态仿真,完成了喷射火三维动态可视化软件系统的开发。最后,利用该系统进行实例分析。应用表明:虚拟现实技术与事故后果模拟相结合,使整个系统实现实时性和形象性的统一,虚拟现实技术在化工行业具有广泛应用前景,也为事故后果预测评估提供科学依据。     

Equilibrium study and kinetics of Cu removal from water by zeolite prepared from oil shale ash

Engineered zeolite was produced from oil shale ash by reaction with sodium hydroxide in a closed vessel reactor. This adsorbent was used for removal of copper ions from aqueous solution. The maximum adsorption capacity was 504.6 mg Cu²⁺/g zeolite. Kinetic studies showed that the rate of adsorption of copper is increased with increasing the solution pH and temperature, quantity of the zeolite and agitation speed. The kinetic data were fitted to homogeneous micropore model and found that the mass transfer coefficient and diffusivity of the Cu²⁺ are directly affected by the kinetic parameters. The increase in solution concentration will decrease the mass transfer coefficient while diffusivity is increased.