全文获取类型
收费全文 | 263篇 |
免费 | 5篇 |
国内免费 | 29篇 |
专业分类
安全科学 | 92篇 |
废物处理 | 9篇 |
环保管理 | 24篇 |
综合类 | 87篇 |
基础理论 | 22篇 |
污染及防治 | 47篇 |
评价与监测 | 15篇 |
社会与环境 | 1篇 |
出版年
2023年 | 11篇 |
2022年 | 5篇 |
2021年 | 16篇 |
2020年 | 16篇 |
2019年 | 10篇 |
2018年 | 5篇 |
2017年 | 3篇 |
2016年 | 9篇 |
2015年 | 26篇 |
2014年 | 8篇 |
2013年 | 18篇 |
2012年 | 12篇 |
2011年 | 16篇 |
2010年 | 3篇 |
2009年 | 11篇 |
2008年 | 22篇 |
2007年 | 24篇 |
2006年 | 9篇 |
2005年 | 5篇 |
2004年 | 9篇 |
2003年 | 10篇 |
2002年 | 7篇 |
2001年 | 4篇 |
2000年 | 7篇 |
1999年 | 3篇 |
1998年 | 5篇 |
1997年 | 7篇 |
1996年 | 2篇 |
1994年 | 7篇 |
1993年 | 1篇 |
1992年 | 2篇 |
1991年 | 1篇 |
1990年 | 2篇 |
1989年 | 1篇 |
排序方式: 共有297条查询结果,搜索用时 15 毫秒
91.
Hydrogen explosion risk needs to be carefully assessed and evaluated in nuclear facilities because of the potential catastrophic consequences: breakdown of safety equipments, failure of containment, dissemination of radioactive materials in the environment.When studying an indoor release, one possible simplification is to assume a perfect gas mixing inside the room. This assumption is effectively often used to evaluate toxic risks in the environment outside a building (Mastellone, Ponte, & Arena, 2003). However, perfect gas mixing assumption is only a rough approximation, as indoor concentrations can largely differ from mean values, due to buoyancy, recirculation zones or obstacles for example.In order to better evaluate the risk of explosion in case of an accidental release of hydrogen, IRSN conducted a numerical study using FLACS CFD software. Several parameters have been studied to identify dangerous situations and draw a representative picture of the risk: room size, position and direction of hydrogen leak, ventilation characteristics. Hydrogen release flow rates used for numerical simulations have been chosen as the highest leak rate which, by applying the assumption of perfect mixing, produces an average concentration in the room equal to hydrogen lower flammability limit (LFL).Simulation results indicate that in some particular configurations, especially for impinging hydrogen jets, hydrogen concentrations can locally be above LFL and then create explosive atmospheres with significant volumes. 相似文献
92.
Angelika Wähner Gisbert Gramse Tim Langer Michael Beyer 《Journal of Loss Prevention in the Process Industries》2013,26(6):1655-1660
Based on existing MIE test results and new measurements, a statistical analysis for the MIE of hydrogen, ethene and propane is made by means of the logistic regression. The conditions necessary to carry out such an approach are discussed. It is shown that MIE values which are connected with a certain ignition probability could be determined adequately and lead to a more sophisticated result, also with regard to measurement uncertainties. This, in turn, leads to a better comparability and a higher informative content. At the same time, the MIEs of hydrogen, ethene and propane are reviewed. In doing so, a useful contribution to the discussion concerning the MIE of propane is made. 相似文献
93.
Woo Kyung Kim Toshio Mogi Ritsu Dobashi 《Journal of Loss Prevention in the Process Industries》2013,26(6):1501-1505
Flame behavior and blast waves generated during unconfined hydrogen deflagrations were experimentally studied using infrared photography. Infrared photography enables expanding spherical flame behaviors to be measured and flame acceleration exponents to be evaluated. In the present experiments, hydrogen/air mixtures of various concentrations were filled in a plastic tent of thin vinyl sheet of 1 m3 and ignited by an electric spark. The onset of accelerative dynamics on the flame propagation was analyzed by the time histories of the flame radius and the stretched flame speed. The results demonstrated that the self-acceleration of the flame, which was caused by diffusional-thermal and hydrodynamic instabilities of the blast wave, was influenced by hydrogen deflagrations in unconfined areas. In particular, it was demonstrated that the overpressure rapidly increased with time. The burning velocity acceleration was greatly enhanced with spontaneous-turbulization. 相似文献
94.
This paper presents an experimental study on employing a pellet form of catalyst in photo-reduction of carbon dioxide with water. Water was first absorbed into titania pellets. Highly purified carbon dioxide gas was then discharged into a reactor containing the wet pellets, which were then illuminated continuously for 65 hours using UVC lamps. Analysing the products accumulated in the reactor confirmed that methane and hydrogen were produced through photo-reduction of carbon dioxide with water. No other hydrocarbons were detected. Increasing the temperature in the reactor has showed little change on the amount of methane produced. 相似文献
95.
96.
Carmen Difiglio Dolf Gielen 《Mitigation and Adaptation Strategies for Global Change》2007,12(3):387-405
If hydrogen (H2) is to significantly reduce greenhouse gas emissions and oil use, it needs to displace conventional transport fuels and be
produced in ways that do not generate significant greenhouse gas emissions. This paper analyses alternative ways H2 can be produced, transported and used to achieve these goals. Several H2 scenarios are developed and compared to each other. In addition, other technology options to achieve these goals are analyzed.
A full fuel cycle analysis is used to compare the energy use and carbon (C) emissions of different fuel and vehicle strategies.
Fuel and vehicle costs are presented as well as cost-effectiveness estimates. Lowest hydrogen fuel costs are achieved using
fossil fuels with carbon capture and storage. The fuel supply cost for a H2 fuel cell car would be close to those for an advanced gasoline car, once a large-scale supply system has been established.
Biomass, wind, nuclear and solar sources are estimated to be considerably more expensive. However fuel cells cost much more
than combustion engines. When vehicle costs are considered, climate policy incentives are probably insufficient to achieve
a switch to H2. The carbon dioxide (CO2) mitigation cost would amount to several hundred US$ per ton of CO2. Energy security goals and the eventual need to stabilize greenhouse gas concentrations could be sufficient. Nonetheless,
substantial development of related technologies, such as C capture and storage will be needed. Significant H2 use will also require substantial market intervention during a transition period when there are too few vehicles to motivate
widely available H2 refueling.
相似文献
Dolf GielenEmail: |
97.
Hydrogen safety is a critical component of modern industrial safety production. In this study, a set of hydrogen explosion suppression equipment is designed independently. The suppression effects of the equipment on hydrogen explosions are studied at normal room temperature and pressure. The experimental results show that the actuation time of the equipment and the spraying mode of the suppressant are the main factors leading to the failure of the hydrogen explosion suppression equipment. The flame, with a hydrogen equivalence ratio of 0.7 and 1.0, spreads out of control when the suppressant touches the flame front. At this time, the addition of the suppressant enhances flame propagation and increases pressure. In addition, because the suppressant does not fully cover the developing flame, the hydrogen flame with the equivalence ratio of 0.5 eventually breaks through the suppressant cloud, and the explosion happens. However, when the initial flame is completely covered by the suppressant, the hydrogen explosion is suppressed by hydrogen explosion suppression equipment. This research provides a solid and reliable foundation for hydrogen explosion suppression equipment in industrial safety and production protection. 相似文献
98.
Xiaomin Zhang Wenjie Xiong Zengyu Yin Yongle Chen Youting Wu Xingbang Hu 《绿色能源与环境(英文)》2022,7(1):137-144
In this work, a series of novel proton-gradient-transfer acid complexes (PGTACs) were developed. Their physicochemical properties, including thermal stability, melting point, and Hammett acidity, were measured. The effects of catalyst loading, reaction temperature, and substrate expansion on the catalytic performance were systematically studied. It is found that the combination of bidentate N-heterocycle and H2SO4 (1:2 M ratio) could form simultaneously N–H covalent bond and N…H hydrogen bond, which makes the PGTACs excellent catalysts integrate the advantages of strong acids (high catalytic activity) and ionic liquids (phase separation) in the esterification reaction. Moreover, these PGTACs can be reused by convenient phase separation without obvious diminution of catalytic activity. It is concluded that these PGTACs are potential alternative candidates for esterification reaction in the process of industrial catalysis. 相似文献
99.
Hydrogen is an indispensable energy carrier for the sustainable development of human society. Nevertheless, its storage, transportation, and in situ generation still face significant challenges. Methanol can be used as an intermediate carrier for hydrogen supplies, providing hydrogen energy through instant methanol conversion. In this study, a sorption-enhanced, chemical-looping, oxidative steam methanol-reforming (SECL-OSRM) process is proposed using CuO–MgO for the on-board hydrogen supply, which could be a promising method for safe and efficient hydrogen production. Aspen Plus software was used for feasibility verification and parameter optimization of the SECL-OSRM process. The effects of CuO/CH3OH, MgO/CH3OH, and H2O/CH3OH mole ratios and of temperature on H2 production rate, H utilization efficiency, CH3OH conversion, CO concentration, and system heat balance are discussed thoroughly. The results indicate that the system can be operated in auto-thermal conditions with high-purity hydrogen (99.50 vol%) and ultra-low-concentration CO (<50 ppm) generation, which confirms the pos-sibility of integrating low-temperature proton-exchange membrane fuel cells (LT-PEFMCs) with the SECL-OSRM process. The simulation results indicate that the CO can be modulated in a lower concentration by reducing the temperature and by improving the H2O/CH3OH and MgO/CH3OH mole ratios. 相似文献
100.
Rüdiger Riesch Virginia Duwe Nina Herrmann Lisa Padur Annemarie Ramm Kristin Scharnweber Matthias Schulte Tanja Schulz-Mirbach Madlen Ziege Martin Plath 《Behavioral ecology and sociobiology》2009,63(10):1515-1526
One potential trade-off that bold individuals face is between increased predation risks and gains in resources. Individuals
experiencing high predation and hungry individuals (or individuals with low body condition) are predicted to show increased
boldness. We examined one behavioral trait previously reported to be associated with boldness (the time individual fish needed
to emerge from shelter) in various populations of mollies (Poecilia spp.). Our study system included several southern Mexican surface streams with high piscine predation and high food availability,
sulfidic surface streams with high avian predation, in which the inhabiting fish show reduced body condition, and a sulfidic
cave, where predation and body condition are low. Our comparison revealed very short times to emerge from the start box in
populations from non-sulfidic streams. In sulfidic habitats (whether surface or cave), it took individual Poecilia mexicana considerably longer to emerge from the start box, and the same difference was also found in an independent comparison between
P. mexicana and the closely related, highly sulfide-adapted Poecilia sulphuraria. Fish reared under common garden conditions (in the absence of predators and hydrogen sulfide) showed intermediate boldness
scores to the extremes observed in the field. Our data thus indicate that (a) boldness is shaped by environmental conditions/experiential
effects, but is not heritable, (b) predation affects boldness in the predicted direction, but (c) low body condition leads
to reduced boldness. Extremophile Poecilia spp. spend most of their time surfacing to survive under sulfidic and hypoxic conditions, which exposes them to increased
levels of predations, but the fish forage on the bottom. Hence, in this system, increased boldness does not increase foraging
success. We argue that energy limitation favors reducing energetically costly behaviors, and exploring novel environments
may be just one of them. 相似文献