首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   449篇
  免费   58篇
  国内免费   90篇
安全科学   148篇
废物处理   8篇
环保管理   60篇
综合类   212篇
基础理论   64篇
环境理论   1篇
污染及防治   43篇
评价与监测   12篇
社会与环境   35篇
灾害及防治   14篇
  2024年   4篇
  2023年   9篇
  2022年   20篇
  2021年   19篇
  2020年   16篇
  2019年   23篇
  2018年   20篇
  2017年   17篇
  2016年   27篇
  2015年   29篇
  2014年   22篇
  2013年   30篇
  2012年   50篇
  2011年   34篇
  2010年   35篇
  2009年   25篇
  2008年   16篇
  2007年   23篇
  2006年   32篇
  2005年   17篇
  2004年   7篇
  2003年   17篇
  2002年   8篇
  2001年   12篇
  2000年   7篇
  1999年   8篇
  1998年   8篇
  1997年   11篇
  1996年   6篇
  1995年   10篇
  1994年   6篇
  1993年   2篇
  1992年   2篇
  1991年   2篇
  1990年   3篇
  1989年   3篇
  1988年   2篇
  1987年   1篇
  1986年   2篇
  1982年   1篇
  1979年   2篇
  1978年   2篇
  1975年   2篇
  1974年   1篇
  1973年   2篇
  1972年   1篇
  1970年   1篇
排序方式: 共有597条查询结果,搜索用时 15 毫秒
31.
Sorption of 3,4-dichloroaniline (3,4-DCA) on four typical Greek agricultural soils, with distinct texture, organic matter content and cation exchange capacities, was compared by using sorption isotherms and the parameters calculated from the fitted Freundlich equations. The sorption process of 3,4-DCA to the soil was completed within 48–72 h. The 3,4-DCA sorption on all soils was well described by the Freundlich equation and all sorption isotherms were of the L-type. The sandy clay loam soil with the highest organic matter content and a slightly acidic pH was the most sorptive, whereas the two other soil types, a high organic matter and neutral pH clay and a low organic matter and acidic loam, had an intermediate sorption capacity. A typical calcareous soil with low organic matter had the lowest sorption capacity which was only slightly higher than that of river sand. The 3,4-DCA sorption correlated best to soil organic matter content and not to clay content or cation exchange capacity, indicating the primary role of organic matter. The distribution coefficient (K d) decreased with increasing initial 3,4-DCA concentration and the reduction was most pronounced with the highly sorptive sandy clay loam soil, suggesting that the available sorption sites of the soils are not unlimited. Liming of the two acidic soils (the sandy clay loam and the loam) raised their pH (from 6.2 and 5.3, respectively) to 7.8 and reduced their sorption capacity by about 50 %, indicating that soil pH may be the second in importance factor (after organic matter) determining 3,4-DCA sorption.  相似文献   
32.
外源硅对不同pH水田土壤吸附铅的影响   总被引:2,自引:0,他引:2  
通过等温吸附实验,研究了加硅对2种不同pH水田土壤吸附铅特性的影响。实验中用硝酸中和硅酸钠的碱性,各处理间钠离子和硝酸根离子的差异以硝酸钠补齐,消除了因硅酸盐的加入改变体系pH及伴随离子对土壤吸附铅可能产生的影响。结果表明,在本实验条件下,Langmuir方程、Freundlich方程和Temkin方程都能较好地描述不同硅浓度条件下两种土壤对铅的吸附特征,但以Freundlich模型为最优;加硅促进了酸性土壤对铅的吸附,抑制了碱性土壤对铅的吸附。  相似文献   
33.
ABSTRACT: The goal of this research was to develop a methodology for modeling a bioinfiltration best management practice (BMP) built in a dormitory area on the campus of Villanova University in Pennsylvania. The objectives were to quantify the behavior of the BMP through the different seasons and rainfall events; better understand the physical processes governing the system's behavior; and develop design criteria. The BMP was constructed in 2001 by excavating within an existing traffic island, backfilling with a sand/soil mixture, and planting with salt tolerant grasses and shrubs native to the Atlantic shore. It receives runoff from the asphalt (0.26 hectare) and turf (0.27 hectare) surfaces of the watershed. Monitoring supported by the hydrologic model shows that the facility infiltrates a significant fraction of the annual precipitation, substantially reducing the delivery of nonpoint source pollution and erosive surges downstream. A hydrologic model was developed using HEC‐HMS to represent the site and the BMP using Green‐Ampt and kinematic wave methods. Instruments allow comparison of the modeled and measured water budget parameters. The model, incorporating seasonally variable parameters, predicts the volumes infiltrated and bypassed by the BMP, confirming the applicability of the selected methods for the analysis of bioinfiltration BMPs.  相似文献   
34.
The basic theories and fundamental assumptions usually employed in the solution of unsteady groundwater flow problems are reviewed critically. The best known method of analysis for such problems is based on the Dupuit-Forchheimer approximation and leads to a nonlinear parabolic differential equation which is generally solved by linearization or numerical methods. The accuracy of the solution to this equation can be improved by use of a different approach which does not employ the Dupuit Forchheimer assumption, but rather is based on a semi-numerical solution of the Laplace equation for quasi-steady conditions. The actual unsteady process is replaced by a sequence of steady-state conditions, and it is assumed that the actual unsteady flow characteristics during a short time interval can be approximated by those associated with “average” steady state flow. The Laplace equation is solved by a semi-discretization method according to which the horizontal coordinate is divided into subintervals, while the vertical coordinate is maintained continuous. The proposed method is applied to a typical tile drainage problem, and, based on a comparison of calculated results with experimental data, the method is evaluated and practical conclusions regarding its applicability are advanced.  相似文献   
35.
A modified transient version of the Streeter-Phelps model along with the energy balance equation is employed to analyze the effects of waste heat discharge from power plants on stream water quality. Analysis is also made to examine the effects of the upstream water quality and stream velocity on the downstream DO concentration level. The resulting coupled nonlinear hyperbolic partial differential equations representing the energy, BOD and DO concentrations are solved by the method of characteristics and simulated on a digital computer. Final numerical results indicate that the allowable quantity of thermal discharge does heavily depend on the upstream quality.  相似文献   
36.
ABSTRACT: Extension of basic step methods of backwater computation to reaches of finite length is examined. Accuracies of commonly accepted hydraulic loss equations under particular water surface profile conditions are compared. Simulation of energy lines within a reach by parabolic curves is found to minimize error provided orientation of the axis of the parabola is selected in accordance with prevailing hydraulic conditions. Theoretical basis for an index reach length beyond which single-step computation from end to end of the reach must be in error is developed. Reduction of this reach length by suitable factors tailored to hydraulic conditions yields a mathematically defined allowable reach length for backwater computation. When reach length does not exceed this allowable reach length, no significant error may be detected. Automatic insertion of synthetic cross sections interpolated between surveyed cross sections when these are inadvertently spaced too far apart enables computation to proceed. This device is error-free for prismatic channls but may introduce error for irregular natural channels. Preliminary trials indicate that results so obtained may be accepted provided the fall in the original reach does not exceed from one to two feet. When this is exceeded, additional cross sections should be surveyed.  相似文献   
37.
ABSTRACT: A sediment routing technique was developed to route sediment yield from small watersheds through streams and valleys to the outlet of large watersheds. The technique is based on the modified universal sol loss equation and a first order decay function of travel time and particle size. Deposition is dependent upon settling velocities of sediment particles, travel time, and the amount of sediment in suspension. Sediment routing increases sediment yield prediction accuracy and allows determination of subwatershed contributions to the total sediment yield. Also, the locations and amounts of floodplain scour and deposition can be predicted. Another advantage of sediment routing is that measured sediment yield data are not required. The procedure performed satisfactorily in test routings on two Texas blackland watersheds Sediment routing will be useful in flood control evaluation, reservoir and channel design, water quality calculations, environmental impact assessment, and land-use planning.  相似文献   
38.
ABSTRACT: Deep percolation rates are normally estimated from a water balance. Results are presented of a study undertaken to evaluate three alternative methods of estimating percolation below the root zone when knowledge about the history of applied water and evapotranspiration are not available. The alternative methods are: 1) use of Darcy's equation to calculate deep percolation rate; 2) measurement of the soil temperature prof and calculation of the deep percolation rate from the shape of the temperature depth curve; and 3) measurement of the tritium concentration in the soil water and its relationship to the history of the tritium concentration in rainfall. At the principal study site, the Darcy velocity of flow ranged from 9 cm per year determined by the temperature method, to 40 cm per year determined by the tritium method. Darcy's equation to calculate seepage rates resulted in an estimation of deep seepage of 18 cm per year. An average deep percolation rate at the principal study site of 22 cm per year was determined using the average of all three methods. Results for other sites based on the temperature method indicated a lower seepage rate.  相似文献   
39.
The examination of the possible direct link between environmental protection and firm performance in the literature has generally produced mixed results. The present paper contributes to the literature by using the resource-based view as a mediating process in this relationship. The study specifically tests whether or not the resource-based view of the firm mediates the positive relationships of proactive environmental management and improved environmental performance with competitive advantage, which also has consequences for financial performance. We also check the possible link between the adoption of a pioneering approach and good environmental management practices. Our findings support that early investment timing and intensity in environmental issues impact on the adoption of a proactive environmental management, which in turn helps to improve environmental performance. The findings also show that a firm's resources and competitive advantage act as mediator variables for a positive relationship between environmental protection and financial performance. This contribution is original because the present paper develops a comprehensive whole picture of this path process, which has previously only been partially discussed in the literature. In addition, this study clarifies a relevant point in the literature, namely that the effect of environmental protection on firm performance is not direct and can vary depending on the sector considered. Whereas competitive advantage in relation to costs influences financial performance in the IPPC law sector, the relevant influence in the hotel sector comes from competitive advantage through differentiation.  相似文献   
40.
Abstract

Chemical transport in soil is a major factor influencing soil and water contamination. Four soils and turfgrass thatch, representing a wide range of organic carbon OC content were studied to determine sorption Kd and Kf parameters for the insecticides chlorpyrifos and fonofos. The batch equilibrium method was used. The concentration of insecticide was measured in the solution as well as in the solid phase to determine the most accurate sorption data. Four soils and thatch were equilibrated for 24 h at 22 ± 1OC with aqueous insecticide solutions. Four concentrations of the insecticides, each <50% of their respective water solubilities, were selected for the experiments. After extraction with an organic solvent, the concentration of insecticides in the aqueous solution was determined by gas liquid chromatography using electron capture detection for chlorpyrifos, and nitrogen/phosphorus detection for fonofos. Data obtained were fitted to the log and simple linear form of the Freundlich equation. Mass balance Freundlich isotherm exponents n ranged between 0.82 and 0.93 for chlorpyrifos. 0.82 and 1.21 for fonofos, with r2 ≥ 0.97. Koc (percent of organic carbon %OC normalized Sorption coefficient) values were calculated by using experimentally developed Kd and Kf coefficients in relation to OC levels from 0.29 to 34.85%. Kd and Kf coefficients of both insecticides were positively correlated with OC (r2 ≥ 0.96). organic matter OM (r2 0.96), and cation exchange capacity CEC (r2 ≥ 0.90).  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号