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51.
Fenton法脱色降解活性黑5模拟废水 总被引:1,自引:0,他引:1
本研究对benton试剂脱色降解活性黑5模拟废水进行了初步的实验研究。在恒温条件下,分别以600nm和255nm波长下染料溶液吸光度为主要测定指标,对该种染料的脱色及其芳环结构的氧化降解进行了同步分析。考察了染料溶液初始pH值、Fe^2+浓度、H2O2投加量、染料浓度等因素的影响。结果表明,在一定实验条件下,活性黑5的脱色效率可达到99%,染料芳环结构的降解可达30%,COD去除率达到57.5%。活性黑5的脱色降解过程分为两个阶段进行。在最佳pH范围内,H2O2投加量、Fe^2+浓度、染料浓度对染料初始脱色速率影响不大,但对后续的芳环结构降解影响较大。 相似文献
52.
Jingjing Jiang Jiaying Gao Shu Niu Xingyue Wang Tianren Li Shengda Liu Yanhong Lin Tengfeng Xie Shuangshi Dong 《环境科学学报(英文版)》2021,33(8):147-160
The extensive use of tetracycline hydrochloride (TCH) poses a threat to human health and the aquatic environment. Here, magnetic p-n Bi2WO6/CuFe2O4 catalyst was fabricated to efficiently remove TCH. The obtained Bi2WO6/CuFe2O4 exhibited 92.1% TCH degradation efficiency and 50.7% and 35.1% mineralization performance for TCH and raw secondary effluent from a wastewater treatment plant in a photo-Fenton-like system, respectively. The remarkable performance was attributed to the fact that photogenerated electrons accelerated the Fe(III)/Fe(II) and Cu(II)/Cu(I) conversion for the Fenton-like reaction between Fe(II)/Cu(I) and H2O2, thereby generating abundant ?OH for pollutant oxidation. Various environmental factors including H2O2 concentration, initial pH, catalyst dosage, TCH concentration and inorganic ions were explored. The reactive oxidation species (ROS) quenching results and electron spin resonance (ESR) spectra confirmed that ?O2? and ?OH were responsible for the dark and photo-Fenton-like systems, respectively. The degradation mechanisms and pathways of TCH were proposed, and the toxicity of products was evaluated. This work contributes a highly efficient and environmentally friendly catalyst and provides a clear mechanistic explanation for the removal of antibiotic pollutants in environmental remediation. 相似文献
53.
Sustainable method towards magnetic ordered mesoporous polymers for efficient Methylene Blue removal
The difficulty in achieving high removal efficiency for contaminants in textile wastewater over a wide range of pH impedes the progress of its treatment technique greatly. Herein, a facile and sustainable strategy was adopted for constructing magnetic ordered mesoporous polymers (M-OMPs) without the assistance of organic solvent and catalyst. The prepared M-OMPs were endowed with high special surface area and good superparamagnetism simultaneously, and exhibited high removal efficiency (>99%) for Methylene Blue (MB) within a short time (10 min) at a concentration of 50 mg/L. What's more, high removal efficiency was achieved over a wide range of pH 2-12 and the adsorption capacity for MB on M-OMPs was substantially retained even after 5 adsorption-desorption cycles, further demonstrating the application potential of M-OMPs in the decontamination of textile wastewater. 相似文献
54.
Hasti Daraei Kimia Toolabian Ian Thompson Guanglei Qiu 《Frontiers of Environmental Science & Engineering》2022,16(2):19
55.
56.
改性氧化铝微波诱导氧化处理雅格素蓝BF-BR染料废水的研究 总被引:27,自引:0,他引:27
采用微波诱导氧化工艺(MIOP)技术,以改性氧化铝为催化剂,对雅格素蓝BF-BR染料模拟废水进行氧化处理.优化了处理工艺条件,实验在固液质量比为1:10(50mL雅格素蓝BF-BR水溶液中投加5.0g改性氧化铝)、微波功率为400W的条件下微波辐照处理5min.在此工艺条件下,对水中雅格素蓝BF-BR的脱色率可达到98%,COD去除率为87.4%.改性氧化铝在重复使用9次后仍能保持很高的脱色率.进一步研究表明在微波辐射场中废水中的有机污染物在改性氧化铝表面通过吸附.氧化协同作用而被迅速降解.反应动力学研究表明,该氧化过程符合一级反应动力学规律,反应速率常数k=0995min^-1,反应半衰期t1/2=0.697min.实验结果显示,在本实验中改性氧化铝比颗粒活性炭具有更高的催化活性. 相似文献
57.
丝瓜瓤固定无花果曲霉吸附活性艳蓝KN-R的脱色研究 总被引:1,自引:0,他引:1
利用植物载体丝瓜瓤对无花果曲霉(Aspergillus ficuum)进行固定,并对活性艳蓝KN-R进行脱色研究探讨了固定化菌体的菌龄、pH、温度、菌量对染料脱色的影响.比较了固定化菌体与菌丝球对活性艳蓝KN-R的脱色效果,研究了该固定化菌体的重复利用和动力学实验,并进行了实际废水的脱色研究.结果表明,最佳脱色条件为菌龄3d,温度33℃,pH为6.0,菌量对染料脱色的影响依次为2%>1%>0.5%;固定化菌体对活性艳蓝KN-R的脱色效果优于菌丝球,且它对实际染料废水的脱色率均达80%以上;丝瓜瓤固定无花果曲霉对不同初始浓度(25~186mg·L-1)活性艳蓝KN-R的脱色过程遵循二级动力学方程;经6次重复利用后的该固定化菌体,其脱色率仍达80.79%. 相似文献
58.
玄武湖蓝藻水华成因探讨 总被引:18,自引:3,他引:15
为了解南京玄武湖蓝藻水华的成因,对玄武湖长期监测资料进行了分析和现场调查。结果表明,玄武湖鲢鳙急剧减少中断了正常的食物链,使浮游植物的牧食压力降低,在东南湖回水的诱因作用下,发生了以微囊藻为优势种群的蓝藻水华。指出,玄武湖蓝藻水华的发生进程表明,东南湖回水可能是蓝藻水华发生的诱因,生态失衡是蓝藻水华发生的主要原因,蓝藻水华的暴发与富营养化程度无显著相关性,其暴发加重了玄武湖富营养化程度。 相似文献
59.
Hanzhong Jia Yafang Shi Xiaofeng Nie Song Zhao Tiecheng Wang Virender K. Sharma 《Frontiers of Environmental Science & Engineering》2020,14(4):73
60.
Uranium removal from groundwater via in situ biostimulation: Field-scale modeling of transport and biological processes 总被引:1,自引:0,他引:1
Yabusaki SB Fang Y Long PE Resch CT Peacock AD Komlos J Jaffe PR Morrison SJ Dayvault RD White DC Anderson RT 《Journal of contaminant hydrology》2007,93(1-4):216-235
During 2002 and 2003, bioremediation experiments in the unconfined aquifer of the Old Rifle UMTRA field site in western Colorado provided evidence for the immobilization of hexavalent uranium in groundwater by iron-reducing Geobacter sp. stimulated by acetate amendment. As the bioavailable Fe(III) terminal electron acceptor was depleted in the zone just downgradient of the acetate injection gallery, sulfate-reducing organisms came to dominate the microbial community. In the present study, we use multicomponent reactive transport modeling to analyze data from the 2002 field experiment to identify the dominant transport and biological processes controlling uranium mobility during biostimulation, and determine field-scale parameters for these modeled processes. The coupled process simulation approach was able to establish a quantitative characterization of the principal flow, transport, and reaction processes based on the 2002 field experiment, that could be applied without modification to describe the 2003 field experiment. Insights gained from this analysis include field-scale estimates of the bioavailable Fe(III) mineral threshold for the onset of sulfate reduction, and rates for the Fe(III), U(VI), and sulfate terminal electron accepting processes. 相似文献