广西近岸海域海水和沉积物及生物体中的重金属

以1998年广西近岸海域环境综合调查的资料，分析了广西近岸海域海水、表层沉积物及海洋生物体中重金属的含量分布，表层沉积物中重金属与有机质含量之间的相关关系，海洋生物对重金属的富集情况。结果表明，广西近岸海域海水中的Pb和表层沉积物中的Cu、Pb和As及生物体中的Cd含量部分超标。     

Recovery of heavy metals from electroplating sludge and stainless steel pickle waste liquid by ammonia leaching method

１　ＩｎｔｒｏｄｕｃｔｉｏｎＥｌｅｃｔｒｏｐｌａｔｉｎｇｓｌｕｄｇｅ，ｃｏｎｔａｉｎｉｎｇＣｕ，Ｎｉ，Ｚｎ，Ｃｒ，Ｆｅ，ｅｔｃ．，ｉｓｈａｒｍｆｕｌｗａｓｔｅｍａｔｅｒｉａｌｐｒｏｄｕｃｅｄｂｙｇａｌｖａｎｉｚａｔｉｏｎｉｎｄｕｓｔｒｙ．Ｔｈｅｒｅｉｓｓｔｉｌｌｎｏｅｆｆｅｃｔｉｖｅｍｅｔｈｏｄｔｏｒｅｃｏｖｅｒｒｅｓｏｕｒｃｅａｎｄｃｏｎｔｒｏｌｐｏｌｌｕｔｉｏｎｂｏｔｈａｔｈｏｍｅａｎｄａｂｒｏａｄ．Ｔｈｅｍｅｔａｌｓｄｉｓｃａｒｄｅｄｂｙｇａｌｖａｎｉｚａｔｉｏｎｉｎｄｕｓｔｒｙａｍｏｕｎ…     

论小于63μm粒级作为水体颗粒物重金属研究介质的合理性及有关粒级转换模型研究

粒度是影响水体颗粒物中重金属含量的重要因素。研究了与此有关的两个问题：１．对各种粒度校正方法进行了讨论，论证了以小于６３μｍ粒级作为水体颗粒物中重金属研究介质的合理性：２．由于我国文献中大量资料是关于小于５０μｍ粒级颗粒物的，为使其与小于６３μｍ粒级数据有对比性，我们采集了我国东部自北至南地理、水文条件显著不同的十数条河流共２７个表层沉积物样品，对Ｃｕ、Ｐｂ、Ｚｎ、Ｃｄ、Ｃｏ、Ｎｉ、Ｆｅ、Ｍｎ等７种重金属元素在小于５０μｍ和小于６３μｍ两种粒级中的含量进行了分析，以简约主轴法回归模型Ⅱ建立了两种粒级中重金属含量的回归模型。     

若干典型岩性区域沉积物金属元素地球化学特征比较研究

研究了４种成片分布的典型岩性（页岩、石灰岩、花岗岩、黄土）区域沉积物金属元素（Ｌｉ、Ｎａ、Ｋ、Ｃａ、Ｓｒ、Ｂａ、Ｔｉ、Ｖ、Ｃｒ、Ｍｎ、Ｆｅ、Ｃｏ、Ｎｉ、Ｃｕ、Ｚｎ、Ａｌ等共１６种）总量与形态特征．结果表明：这４种岩性区域沉积物金属元素含量与形态均有显著的差别．与其它岩性相比，黄土地区易迁移元素含量高，而重金属含量显著较低；其金属元素残渣态含量高，而有机态、铁锰氧化物态和可交换态含量低．石灰岩地区重金属含量较高，而易迁移元素如Ｎａ，Ｓｒ等含量则较低；其重金属元素残渣态含量不偏低，表明经风化作用释放出来的重金属参与了次生矿物的形成过程而得以富集．花岗岩地区重金属含量居中，而Ｆｅ和Ａｌ含量较高；其金属元素残渣态含量不偏高则与风化作用较强有关．页岩地区元素含量与形态均居中，代表了各种岩性的平均水平．     

The influence of sewage sludge properties on sludge-borne metal availability

With the advent of more stringent controls on wastewater treatment, sewage sludge production in Europe and many parts of the world is increasing. With this increase comes the problem of sludge disposal, and recycling to land arguably offers an economically and environmentally sustainable option. However, a major limitation of sewage sludge reuse is the potential release of heavy metals from the sludge and heavy metal accumulation to toxic levels in topsoils. The properties of the sludge play a crucial role in determining the initial release and subsequent availability of heavy metals in amended soils. Bioavailable forms of heavy metals in recently amended soils are most likely to be those that are bioavailable in the sewage sludge. In this paper, published research on the importance of sewage sludge characteristics on metal release and bioavailability will be reviewed and contrasted with original research. A selection of sludges from around Australia has been collected for this purpose. Through the use of incubation studies, isotope dilution techniques, ion-selective electrode measurements and ¹³C-NMR spectroscopy, the importance of a range of sludge properties on heavy metal behaviour in sludges and sludge-amended soils is addressed.     

Trace element speciation in selected smelter-contaminated soils in Anaconda and Deer Lodge Valley, Montana, USA

Long-term copper smelting in the Anaconda and Deer Lodge Valley area of Montana has resulted in an extensive area of trace element contamination. Aerial extent of contamination is generally established, but total analysis of soils does not correlate to relative degree of impact on vegetation growth. Three pedons (Beaverell, Cetrack and Judco) were analyzed by routine soil characterization methods, aqua regia microwave digestion, sequential chemical extraction, and X-ray diffraction analysis with the objective of providing a better understanding of chemical forms and potential reactivity of selected trace elements (Cd, Co, Cr, Cu, Hg, Mn, Ni, P, Pb). Surface horizons of soils are more acidic than subsoils, with pH for all horizons ranging from 4.0 to 8.7. Beaverell is the most contaminated in the upper 20 cm with the sum of total extractable (SUM_TE) trace elements by microwave digestion ranging from 1836 to 3605 mg kg⁻¹, largest H₂O-soluble (WS) and exchangeable (EX) fractions (e.g. 1.6 and 9.3%, respectively), and smallest residual (RES) fraction (e.g. 14.3%). Cetrack has greater SUM_TE elements than Judco, though a lower WS+EX fraction due to the effects of alkaline pH, carbonates and high P. Oxide (OX), organic matter/sulfide (OM/S), and RES fractions predominate over WS, EX, and specially-sorbed/carbonate-bound fractions (SS/CAR) for all horizons. Copper, Zn, Pb and Cd are elevated in surface over subsurface horizons in these latter fractions, indicating these elements were anthropogenic additions. X-ray data indicate that Pb, Cu, Cr and Cd partially exists as both OX and sulfide mineral forms.     

Removal of heavy metals (Cr6+,Ni2+)from polluted water using decaying leaves of plane (Plantanus orientalis)

plane decaying leaves have been found capable of removing chromium and nickel ions from aqueous solutions. The removal efficiency depends upon the pH conditions, ions components and concentrations, and concentrations of leaves in media. The maximum removal for unique Cr⁶⁺ is about 7.5-8.0g/kg leaves at pH 4. 0, for unique Ni²⁺ about 2. 6g/kg at the region of PH5. 0-5.5. Under the described conditions nickel increases chromium uptake by plane decaying leaves from solution.     

氢化物发生一原子荧光光谱法测定气田废水中的痕量砷

采用氢化物发生－原子荧光光谱法测气田废水中的痕量砷。方法有取样量少，操作简单、灵敏度高、准确度高、重现性好等优点。砷的测定线性范围为1～200ng/mL，方法的检出限为0．0453ng/mL，相对标准偏差小于等于1．6％，加标回收率在96．0％～97．7％范围内。测定密码标样与气田废水中的痕量砷，获得了满意的结果。     

活性氧化铁/石英砂吸附剂去除水体中的重金属

介绍了活性氧化铁／石英砂吸附剂的特点和制备方法。该吸附能有效去除水体中的重金属，包括阳离子、阴离子、重金属颗粒物及一些络离子，且容易再生，被吸附的金属可以回收。     

色谱痕量分析中的非线性效应及影响

根据溶质在流动相与固定相中吸附平衡热力学的观点简要讨论了色谱分离中的非线性原理，及其在进行色谱痕量分析采用大进样量时对定性和定量的影响，并提出了改进方法。同时也探讨了非线性效应对样品前处理及未知物馏份制备分离的影响与应用。