Transformation products of pharmaceuticals in surface waters and wastewater formed during photolysis and advanced oxidation processes - degradation, elucidation of byproducts and assessment of their biological potency

The significance of transformation products of pharmaceuticals resulting from the parent compounds during natural and technical photolytic processes and advanced oxidation processes has only recently started to attract the interest of the scientific community. Even though relevant studies have now started to produce important knowledge, still many gaps exist that hinder the in-depth and broad understanding of the extent of the potential problems stemming from the presence of such compounds in the environment and the applicability of such techniques for wastewater and potable water treatment. The great diversity of pharmaceutical compounds, the variety of processes and conditions applied by the various research groups active in the field, and the endless list of potential biological endpoints that could potentially be explored, coupled with the limitations related to the analytical capabilities presently available, are some of the crucial parameters that characterize this challenging research direction. This review paper tries to highlight some of the most relevant studies performed so far and to summarize the parameters that prevent scientists from reaching comprehensive conclusions in relation to the formation, fate, and effects of transformation products of pharmaceutical compounds during photo-driven and advanced oxidation processes.     

安徽省休闲度假旅游产品现状及优化研究

在对安徽省休闲度假旅游产品现状分析的基础上,提出优化对策——整合资源,构造休闲度假新格局;调查市场,优化产品结构;创新产品,提升竞争力等。为发展安徽休闲度假旅游,编制休闲度假旅游规划提供理论借鉴。     

Mobile fission and activation products in nuclear waste disposal

When disposing nuclear waste in clay formations it is expected that the most radiotoxic elements like Pu, Np or Am move only a few centimetres to meters before they decay. Only a few radionuclides are able to reach the biosphere and contribute to their long-term exposure risks, mainly anionic species like I129, Cl36, Se79 and in some cases C14 and Tc99, whatever the scenario considered. The recent OECD/NEA cosponsored international MOFAP workshop focussed on transport and chemical behaviour of these less toxic radionuclides. New research themes have been addressed, such as how to make use of molecular level information for the understanding of the problem of migration at large distances. Diffusion studies need to face mineralogical heterogeneities over tens to hundreds of meters. Diffusion rates are very low since the clay rock pores are so small (few nm) that electrostatic repulsion limits the space available for anion diffusion (anion exclusion). The large volume of traversed rock will provide so many retention sites that despite weak retention, even certain of these “mobile” nuclides may show significant retardation. However, the question how to measure reliably very low retention parameters has been posed. An important issue is whether redox states or organic/inorganic speciation change from their initial state at the moment of release from the waste during long term contact with surfaces, hydrogen saturated environments, etc.     

饱和砂土排水与不排水剪切特性的比较研究

针对相对密度为30%的福建标准砂,利用土工静力-动力液压-三轴扭转多功能剪切仪,进行了复杂初始固结条件下应力路径变化的应力控制式单调排水与不排水剪切试验。试验过程中,控制平均主应力保持不变,分别探讨在排水与不排水条件下中主应力系数和主应力方向角对饱和砂土剪切特性和强度的影响。通过对比表明:在排水与不排水试验中,与排水条件无关,中主应力系数对归一化的应力—应变关系具有影响,但对体变或孔压的影响并不明显;当其余初始条件相同时,偏应力比随中主应力系数的增大而降低。主应力方向角的影响同样显著,排水试验的主应力方向角不同时,应力—应变关系所表现出的变化规律取决于水平面与竖直面上受到的剪应力作用,相变及峰值偏应力比和内摩擦角与主应力方向角之间存在抛物线型关系。不排水试验的峰值有效偏应力比随着主应力方向角的增大而减小。同时,对于不同的主应力方向,排水条件改变会影响试验得到的抗剪强度指标。     

苏北乡土文化旅游产品开发研究

乡村文化是乡村旅游开发的灵魂。以江苏北部地域为靶区,在分析乡土文化概念的基础上,指出苏北乡土文化系统主要包括海洋文化、两汉文化和传统农耕文化等文化序列。以睢宁县为例,分析了小区域范围内乡土文化景观的展示形式,构建了苏北乡土文化系统的层次结构,提出了开发苏北乡土文化旅游产品的开发对策。     

白银市工业污染源重金属排放特征分析

以甘肃省白银市为例,利用等标污染负荷法和单位产值等标污染负荷法,从污染物种类、时间变化、空间分布、行业排放4个方面,分析了白银市工业污染源重金属的排放特征,重点比较了2000—2010年期间重金属排放特征的变化。结果表明,近11年以来白银市工业污染源重金属等标污染负荷大小排序为砷>铅>镉>汞>六价铬;重金属排放总量呈下降趋势,单位产值重金属排放总量呈显著下降趋势;但是定量趋势分析的结果则显示最近5年仅有砷和镉呈下降趋势,而汞和铅呈现明显上升趋势;2009年重金属等标污染负荷和单位产值等标污染负荷最大的行政区和流域分别为白银区和白银市东大沟流域;污染负荷和单位产值污染负荷最大的行业均为金属制品业。因此,白银市应将白银区东大沟流域沿线的金属制品业行业,特别是白银公司的重金属污染作为环境整治的重点。     

可持续发展与绿色产品设计实现的途径

本文论述了产品设计与可持续发展的关系，认为绿色产品设计是实现可持续发展的有效手段之一，绿色产品设计包括寿命周期评价、生态设计和可持续产品设计等。低物质化、再循环、生态标志，宣传教育和政府行为等是绿色产品设计可以采取的方法和途径。     

发展中水造福人民

介绍了发展中水的重要性,认为应从建立法规政策、充足技术储备、加大宣传力度几方面推广中水。     

The socioeconomic significance of nature-based recreation in Canada

In recognition of the many values that people ascribe to nature, federal, provincial, and territorial agencies worked inpartnership to complete the 'Survey on the Importance of Natureto Canadians' (SINC) in 1981, 1987, 1991, and 1996. Between 1981 and 1996, more than 80% of Canadians 15 years of age and older engaged in one or more nature-related activities. This paper describes the evolution of this cooperative monitoring program, defines a classification system as a context for the values examined by the SINC, highlights trends of some nature-related recreational activities measured by the survey, and comments onthe importance of this information to Canadians.     

中国与东盟水产品资源贸易价格波动——以冻鲭鱼出口价格为例

东盟是我国第三大水产品出口地,掌握对东盟水产品出口价格波动规律,以预测未来水产品出口价格波动趋势,为拓展水产品贸易潜力、有效进行渔业资源配置、促进水产品信息体系的建立提供依据和支撑。冻鲭鱼是我国重要的水产品出口品种,而东盟又是我国冻鲭鱼的最大出口地。以冻鲭鱼为例,利用2012—2017年我国对东盟以及东盟主要国家冻鲭鱼出口的月度价格数据,采用ARCH族模型和H-P滤波法研究其出口价格的聚簇性、非对称性和构成价格波动的四种因素。结果表明：（1）冻鲭鱼出口价格具有聚簇性,可以进行价格预测,市场价格上涨或下跌对其影响力基本相同;（2）价格呈现明显的季节性波动和周期性,可分为3或4个周期,2014—2015年之前的价格波动幅度大于之后期间内的波动幅度;（3）价格波动由四种因素构成,各因素对冻鲭鱼出口价格波动的贡献率差别较大。