“成型-烧结”碎磷矿的黄磷生产工业性试验

将中小黄磷企业长期堆存的碎磷矿 (粒径 <5mm) ,经过“粘接成型 烧结”及理化指标检测后 ,按烧结矿∶块矿 =1∶1入炉进行工业性试验 ,试验表明该烧结矿可用于黄磷电炉生产 ,该法是降低黄磷生产成本 ,减少环境污染 ,使资源得到合理利用的有效途径之一     

Y形通风采空区自燃与有害气体排放的数值模拟

基于非均质多孔介质漏风渗流方程、多相气体渗流-扩散方程和多孔介质渗流综合传热方程,建立了采空区瓦斯与自燃发火耦合数值模型,开发了用迎风格式有限元方法联立求解的计算机程序(简称G3).计算以图形方式给出各量的区域分布解,从理论上描绘了Y形通风采空区的漏风流态,动态描绘了瓦斯、氧和CO的体积分数以及温度分布状态及其变化过程,并证明了Y形通风形式能避免采空区瓦斯向工作面涌出.计算中采空区按冒落非均质介质处理,考虑了瓦斯涌出对自燃的耦合作用,给出了这种耦合作用关系和解决办法.Y形通风采煤的自燃,两者存在着顾此失彼的关系.     

烟气脱硫设施运行及脱硫电价实时监控系统设计

由于缺乏有效监管手段,目前脱硫设施实际投运情况不理想。设计了一套B/S架构的烟气脱硫设施运行及脱硫电价实时监控系统,分为数据采集、数据通讯、数据处理及发布3个子系统。选择能全面反映脱硫设施运行状况的28个信号,采用"共享-分流"信号防伪采集技术进行采集,通过电力系统内载波电话拨号与无线GPRS两种通讯方式相互竞争、互为备用来实现可靠通讯,并经过软件防伪判别模块和统计运算后以WEB形式发布。数据以5m in的间隔实时刷新,且每小时更新脱硫投入率、脱硫电价款等报表数据。     

S波段低副瓣天线的分析与设计

研究了一种半波振子馈电的带圆片副反射面的抛物面天线.简要介绍了天线低副瓣的含义,并对该天线所使用的馈源的辐射特性进行了理论分析和电磁仿真.设计了一个成本低、体积小、结构简单、电性能良好的低副瓣抛物面天线.这种天线适用于生命探测雷达系统等需要的小尺寸低成本低副瓣天线的特殊场合.     

IN SITU MEASUREMENT OF ADSORPTION AND BIOTRANSFORMATION AT A HAZARDOUS WASTE SITE1

ABSTRACT: A three well injection-production test was performed at the United Creosoting Company (UCC) site in Conroe, Texas, to estimate the effective in situ retardation factors for adsorption and to evaluate the significance of biotransformation in limiting the transport of polycydic aromatics present in the shallow aquifer. The field test was also used as a model to determine if this type of testing would be feasible at other hazardous waste sites. During the test, chloride, a non-reactive tracer and two organic compounds, naphthalene and paradichlorobenzene (pDCB), were injected into a center well for 24 hours followed by clean ground water for six days. Ground water was continuously produced from two adjoining wells and monitored to observe the breakthrough of these compounds. Data from the test were analyzed by comparing the statistical moments of the chloride and organics distributions. Retardation factors for naphthalene and pDCB were estimated to be 1.03 and 0.97 by comparison of the statistical moments. A significant loss of naphthalene and pDCB was also observed during the three well test, apparently due to biotransformation. These results suggest that biotransformation is the major process limiting the transport of naphthalene and similar compounds at the UCC site.     

Important role of reaction field in photodegradation of deca-bromodiphenyl ether: Theoretical and experimental investigations of solvent effects

Photolysis of deca-bromodiphenyl ether (BDE-209) was investigated in tetrahydrofuran, dichloromethane, isopropanol, acetone, ethanol, methanol, acetonitrile and dimethylsulfoxide. Noticeable differences of the photolytic rates and quantum yields were found in the diverse solvents. Different to the previous deductions, hydrogen donating efficiency and electron donating efficiency of solvents were not the decisive factors for the photolytic rate in this study, which was proved by the fast photolysis of BDE-209 in CCl₄, a solvent without hydrogen and difficult to donate electrons. Besides hydrogen addition process, intermolecular polymerization might occur during the photolysis. Density functional theory (DFT) calculation was performed to understand the molecular properties of BDE-209 in different solvents. The lowest singlet vertical excitation energy (E_ex) and the average formal charge on Br () of BDE-209, reflecting the difficulty for the excitation of BDE-209 and for the departing of Br atom, respectively, were changed by the reaction fields formed by the different solvents. E_ex and linearly correlated with the photolytic activity (log k). This study is helpful to better understand the photolytic behavior of BDE-209 in different media.     

浓缩型入口下排气旋风分离器流场和性能的数值计算

运用CFD方法,对浓缩型入口下排气旋风分离器内的气固两相流动进行了研究。计算中气相采用RNGk-ε湍流模型,颗粒相采用拉格朗日坐标系下的离散相模型。重点计算了分离器流场、分离效率及其阻力特性,结果表明,采用浓缩入口后分离器内流场发生明显改变,分离器上部切向速度明显提高,有利于大颗粒的分离。同时通过对不同浓缩结构旋风分离器的分离效率和阻力特性进行分析比较,为工程设计提供了依据。     

Absolute configuration of the major sex pheromone component of the satin moth, Leucoma salicis, verified by field trapping test in Hungary

Summary. Male satin moths, Leucoma (Stilpnotia) salicis L. (Lepidoptera, Lymantriidae) were attracted only to (3Z,6R,7S,9R,10S)-isomer out of the four (3Z)-cis-6,7-cis-9,10-diepoxy-3-henicosenes (leucomalure). This was demonstrated by field trapping test with a bivoltine population in a mixed poplar-willow forest along the flood area of the river Danube at Adony, Hungary.     

模拟烹饪油烟的粒径分布与扩散

烹饪油烟颗粒物粒径分布与扩散特性研究有助于解析其对室内空气质量和居民健康的影响,采用电子低压撞击器(ELPI)实时监测了油烟机开启和关闭状态下,模拟烹饪油烟发生处和3 m外位置处,0.03~10μm范围内油烟颗粒数浓度和质量浓度随粒径分布.油烟颗粒主要以655 nm以下的细颗粒为主.油烟机能够显著降低室内油烟浓度,开启油烟机后,油烟发生处颗粒数浓度从2.8×106个·cm-3降低到2.3×105个·cm-3,PM2.5(空气动力学直径≤2.5μm的颗粒)质量浓度从85.9 mg·m-3降低到6.2 mg·m-3.油烟机对PM10的净化效率高于PM2.5.油烟迅速从发生处扩散到3 m外,无通风状态下,总颗粒数浓度衰减达65%,PM2.5质量浓度衰减达75%.计算流体动力学(CFD)模拟了油烟机对油烟PM2.5质量浓度场扩散分布影响.红外摄像仪监测了油烟温度场分布扩散,以扇形向外扩散,伴随着油烟温度梯度降低.     

移动基站远场区功率密度分布和规划控制距离

为掌握畸变条件下移动通讯基站周围功率密度分布,合理确定其规划控制距离,在杭州市主城区选取具有不同网络类型和载波数的2057个移动基站,实测话务高峰期基站周围射频场功率密度.结果表明,畸变条件下GSM基站远场区功率密度S∝r-1.83 (非畸变条件下S∝r-2),决定系数R2=0.80;距基站天线20m内,约85.91%测点功率密度实测值小于非畸变条件下依据天线标称功率和增益计算的理论值.,频数统计结果表明,距天线1~15m范围内,运营商A所属基站S10值(表示有10%的测点功率密度高于该值)比运营商B高10.00%;距天线1~30m内,双网和三网共站基站S10值分别比单网基站高50.31%和57.10%.移动通讯基站规划控制距离以15m为宜,15m外测点功率密度值超过8μW/cm2的基站只占所测基站的0.11%.