COMBUSTIVE APPROACH FOR MEASURING TOTAL VOLATILE PHOSPHORUS CONTENT IN LANDFILL GAS

A technique was developed to measure the total gaseous phosphorus content in biogas. The amount of air needed for a neutral to oxidising flame was mixed with the biogas. The gas mixture was burnt in a closed quartz burner and the combustion gasses were bubbled through a nitric acid solution. The phosphate content in the bubbling liquid was determined with sector field ICP-MS. The technique was validated in the lab with phosphine. Afterwards the set-up was installed on a landfill. The total gaseous phosphorus content in the landfill gas, measured with the combustive technique, ranged from 1.65 to 4.44 g P/m³. At the same time the phosphine concentration in the landfill gas was determined gas chromatographically (GC). The phosphine (PH₃) content measured with GC ranged from 7.6 to 16.7 g PH₃-P/m³. Since the phosphine-P content (GC) was consistently higher than the total gaseous phosphorus content (burner/ICP-MS), the hypothesised presence of highly toxic gaseous phosphorus compounds other than phosphine could not be demonstrated.     

圆杯—多边形杆复合挤压的上限研究

此文采用三次多项式表示的流线速度场和基元圆环技术相结合的混合流动模型对国杯—多边形截面杆型复合挤压进行了上限分析,得到挤压力的上限解,分析了杆部截面形状对复合挤压分流点位置及变形力的影响规律并对理论计算进行了实验验证.     

二维无压稳定渗流分析的改进方法

人类发展演变过程中,经历了各种各样的地质作用所造成的灾害,其中大部分地质灾害的形成都有地下水的参与,因而确定地质体稳定性时不能忽略地下水。无压渗流是比较复杂的非线性问题,难点在于如何求自由面, 尤其是对溢出点的求解一直没有很好的解决。本文提出了求解无压渗流自由面的一种新方法,在采用等效渗透系数法搜索到自由面后,通过反复移动溢出点再次搜索自由面,最终达到准确求解自由面的目的。实例证明该方法是简单准确有效的。本方法对解决工程问题具有一定的实际意义。     

循环序批式活性污泥反应器的调试及运行

介绍了循环序批式活性污泥反应器的工艺流程及设计参数、调试和运行情况,分析探讨了系统运行中出现的一些问题。稳定运行期间的检测结果表明,反应器对COD和NH3-N具有较好的去除效果,平均去除率分别达到86.2%和92.1%,但对TP的去除率有待提高。     

铸态珠光体基体球墨铸铁 S195曲轴的研制

针对生产实际要求,研究了微量元素加入量、开箱时间等对铸态球墨铸铁珠光体量及性能的影响,试验了铸态球墨铸铁曲轴的各种常规性能.     

水质动态评价的马尔柯夫方法

根据随机过程原理 ,构造了一个新的概率转移矩阵 ,并在此基础上引入进步度的概念 ,对河流水质综合质量变化情况进行动态评价。最后给出了实例分析     

Insights into reactive oxygen species formation induced by water-soluble organic compounds and transition metals using spectroscopic method

Ambient particulate matter (PM) can cause adverse health effects via their ability to produce Reactive Oxygen Species (ROS). Water-Soluble Organic Compounds (WSOCs), a complex mixture of organic compounds which usually coexist with Transition Metals (TMs) in PM, have been found to contribute to ROS formation. However, the interaction between WSOCs and TMs and its effect on ROS generation are still unknown. In this study, we examined the ROS concentrations of V, Zn, Suwannee River Fulvic Acid (SRFA), Suwannee River Humic Acid (SRHA) and the mixtures of V/Zn and SRFA/SRHA by using a cell-free 2′,7′-Dichlorodihydrofluorescein (DCFH) assay. The results showed that V or Zn synergistically promoted ROS generated by SRFA, but had an antagonistic effect on ROS generated by SRHA. Fluorescence quenching experiments indicated that V and Zn were more prone to form stable complexes with aromatic humic acid-like component (C1) and fulvic acid-like component (C3) in SRFA and SRHA. Results suggested that the underlying mechanism involving the fulvic acid-like component in SRFA more tending to complex with TMs to facilitate ROS generation through π electron transfer. Our work showed that the complexing ability and complexing stability of atmospheric PM organics with metals could significantly affect ROS generation. It is recommended that the research deploying multiple analytical methods to quantify the impact of PM components on public health and environment is needed in the future.     

区域水污染控制多目标组合规划模型研究

提出水污染综合多目标规划思路，把治理投资，运行费用，收益和污染物削减量作为规划目标，对多种方案进行优化选择，建立了实现多目标规划的数学模型，对方案的产生组合，初选和优化等建模过程作了系统介绍，并以泾河水质规划为例，将模型予以应用。     

金属基复合材料及其超塑性技术的发展

颗粒或晶须增强铝基复合材料具有优良的性能。目前其制备工艺主要采用粉末冶金法和挤压铸造法。这类铝基复合材料已经有许多应用实例。铝基复合材料超塑性是近年来开发的新技术,可解决其成形性差的加工难题,扩大其应用领域。     

用传递矩阵法计算消声器插入损失的理论探讨

采用声电类比的传递矩阵法，本文对消声器插入损失进行了理论探讨，所推导的理论公式准确地反映了整个内燃机排气系统对消声器插入损失的影响，克服了其它学者在研究此问题中的不足，考虑了声源声阻抗对传递损失的影响，对消声器的整体优化设计具有重要的指导意义。