精对苯二甲酸生产企业挥发性有机物泄漏检测与排放估算

采用泄漏检测与修复(LDAR)技术分析了某精对苯二甲酸生产装置动静密封点的泄漏情况,共完成1 367个密封点的现场LDAR检测,测出28个泄漏点,总泄漏检出率为2.05%。其中储存单元的泄漏点数量较氧化单元和精制单元高,泄漏程度也较严重。泄漏点主要集中在法兰、开口管线和泵三类密封点;涉及轻液的泄漏密封点数量较多。依据LDAR检测结果,采用相关方程法估算设备动静密封点泄漏产生的挥发性有机物(VOCs)排放量约为4.999 t/a。法兰的VOCs泄漏排放量最大,约占63.89%,其次是泵和采样连接系统,占泄漏排放量的20.78%和7.89%。     

Effect of dietary factors and environmental chemicals on intestinal drug metabolizing enzymes

The liver is the major site of metabolism of foreign chemicals, but contribution from intestinal biotransformation can influence the overall disposition of chemicals. The intestinal drug‐metabolizing enzymes are located in the endoplasmic reticulum and they possess biochemical properties similar to those of the hepatic system. In general, the rate of in vitro metabolism of drug substrates in intestines is lower than in the liver. There seem to be differences in regulation and induction of hepatic and intestinal drug‐metabolizing enzymes. The in vitro intestinal metabolism of foreign chemicals is affected by several factors including the nutritional status of the animal. Dietary components such as vitamins, lipids and vegetables can modify the activities of intestinal drug‐metabolizing enzymes. Phenobarbital or 3‐methyl‐cholanthrene (3‐MC) pre‐treatment induces the hepatic metabolism of a wide variety of drug substrates in a number of species, while the stimulation of intestinal enzymes is both substrate and species specific. Rabbit intestinal drug‐metabolizing enzymes seem to be resistant to induction by foreign chemicals.     

Humic substances. Part III. sorptive interactions with environmental chemicals†

The formation of covalent binding to DNA of a carcinogen is now widely accepted to represent a classical mechanism of tumour induction in mammals. This mechanism does not operate with metals since no covalent binding of these agents to DNA does occur. Nevertheless, somatic mutations as typical consequences of DNA‐damage have been reported to be induced by metals in various model systems. Beside DNA‐alkylation such damages can be caused by changes in the conformation of DNA or in the fidelity of DNA‐repair. The activity of the repair enzymes DNA‐polymerases is indeed impaired by many metal ions at least in vitro. It is not yet established whether these mechanisms are also important in the intact mammalian organism. Much evidence has accumulated during the last years that a disturbance of the balance of cations and especially metal ions represents another possible mechanism of tumour induction. The tumours found with high doses of chelating agents such as nitrilo‐triacetic acid (NTA) have to be discussed in this context. Since most—if not—all of the speculative mechanisms of metal carcinogenesis resemble classical pharmacological reactions the existence of a threshold level is likely. So metal carcinogenesis will not be a problem of the environmental contamination at trace levels but a problem of occupational medicine.     

环氧树脂在玻璃钢设备及管道修补方面的改进应用

本文对玻璃钢设备存在的质量隐患原因进行了分析,指明运用玻璃钢（FRP）修补与加固相结合的措施,使修补后的玻璃钢与复合衬里的抗渗透性增强,防止强腐蚀性介质对金属的腐蚀作用;对脱硫系统的玻璃钢管道,添加了一些耐磨填料进行耐磨加固,使修补后的管道既能耐酸碱又能耐石灰浆液的冲击,修补后的效果明显。     

The effects of flooding upon buildings in developing countries

The genera] effects of flooding on buildings and structural materials in developing countries are comprehensively reviewed. The aim of the paper is to stimulate further field based research as to how and what type of building improvements can be introduced, given the prevailing economic and cultural constraints of many communities, and to examine the appropriateness of floodproofing measures in developing countries where there are often few floodplain management or large scale flood prevention schemes. Proposals are suggested as to the method and type of information which is required for detailed studies prior to developing new and more effective building designs.     

体外预应力索的破坏及其修复与更换

介绍了可换索体系对各组成部分的要求。分析了体外索在自然灾害环境下劣化破坏的原因：在腐蚀环境下，体外索腐蚀导致其力学性能发生变化，甚至发生应力腐蚀破坏和氢脆或疲劳腐蚀破坏；火灾环境下，钢筋力学性能劣化；动荷载作用下，体外索产生疲劳破坏。针对不同的情况，提出了相应的体外索修复、二次张拉和更换的方法。     

挥发性有机物泄漏检测与修复技术规范体系的设想研究

泄漏检测与修复技术对于控制工业企业无组织挥发性有机物排放效益明显,通过分析泄漏检测与修复技术的国内外发展状况,结合该技术在实际操作中的相关要求,提出建立和完善包括工业企业泄漏元件编码原则、泄漏检测与修复操作技术规范、泄漏检测与修复核查与评估方法、LDAR技术泄漏量核算方法以及LDAR技术信息管理系统接口规范在内的挥发性有机物泄漏检测与修复技术环境管理规范体系的整体设想,以促进挥发性有机物总量减排和环境空气质量改善.     

部队服役枪械外观快速修复研究

目的快速修复部队服役枪械的外观质量。方法基于部队的实际情况,通过对枪械表面处理常用的镀铬工艺、阳极氧化工艺、黑色磷化工艺和喷漆工艺的分析,提出了一套部队可用的枪械快速修复外观的方法,即铁件采用黑色磷化工艺处理,铝件和塑料件采用表面喷漆的工艺来处理。结果通过将该方法到部队实际应用,证明了该方法的可行性。结论该方法操作简单、快捷,达到了部队可自行快速修复的目的。     

UV light tolerance and reactivation potential of tetracycline-resistant bacteria from secondary effluents of a wastewater treatment plant

Tetracycline-resistant bacteria (TRB) are of concern as emerging microbial contaminants in reclaimed water. To understand the effects of UV disinfection on TRB, both inactivation and reactivation profiles of TRB, as well as 16 tetracycline-resistant isolates from secondary effluent, were characterized in this study. The inactivation ratio of TRB was significantly lower (3.0-log) than that of heterotrophic bacteria (> 4.0-log) in the secondary effluent. Additionally, the proportion of TRB significantly increased from 1.65% to 15.51% under 20 mJ/cm² ultraviolet (UV) exposure. The inactivation rates of tetracycline-resistant isolates ranged from 0.57/s to 1.04/s, of which tetracycline-resistant Enterobacter-1 was the most tolerant to UV light. The reactivation of TRB, tetracycline-resistant isolated strains, as well as heterotrophic bacteria commonly occurred in the secondary effluent even after 20 mJ/cm² UV exposure. The colony forming ability of TRB and heterotrophic bacteria reached 3.2-log and 3.0-log under 20 mJ/cm² UV exposure after 22 hr incubation. The final inactivation ratio of tetracycline-resistant Enterobacter-1 was 1.18-log under 20 mJ/cm² UV exposure after 22 hr incubation, which is similar to those of TRB (1.18-log) and heterotrophic bacteria (1.19-log). The increased proportion of TRB and the reactivation of tetracycline-resistant enterobacteria in reclaimed water could induce a microbial health risk during wastewater reuse.