首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   328篇
  免费   8篇
  国内免费   57篇
安全科学   7篇
废物处理   10篇
环保管理   27篇
综合类   97篇
基础理论   75篇
污染及防治   151篇
评价与监测   23篇
社会与环境   3篇
  2024年   1篇
  2022年   4篇
  2021年   5篇
  2020年   8篇
  2019年   11篇
  2018年   9篇
  2017年   13篇
  2016年   15篇
  2015年   14篇
  2014年   17篇
  2013年   123篇
  2012年   19篇
  2011年   18篇
  2010年   9篇
  2009年   14篇
  2008年   16篇
  2007年   14篇
  2006年   12篇
  2005年   14篇
  2004年   10篇
  2003年   11篇
  2002年   7篇
  2001年   4篇
  2000年   4篇
  1999年   2篇
  1998年   3篇
  1997年   5篇
  1996年   3篇
  1995年   1篇
  1994年   1篇
  1992年   2篇
  1991年   1篇
  1989年   2篇
  1983年   1篇
排序方式: 共有393条查询结果,搜索用时 15 毫秒
101.
农作物秸秆燃烧是大气中黑碳(black carbon,BC)气溶胶的主要来源之一。目前农作物秸秆燃烧排放黑碳的研究主要集中在通过离线样品分析获得的BC排放特征,缺少实时在线排放特征的研究。本研究收集了我国具有代表性的4种农作物秸秆(小麦秸秆、水稻秸秆、玉米秸秆和大豆秸秆),通过在实验室燃烧平台模拟农作物秸秆露天燃烧的过程,利用黑碳仪获得农作物秸秆燃烧过程中BC的实时浓度排放变化;利用质量重建,获得BC在线排放因子。结果表明:农作物秸秆在明燃过程中BC的排放因子较为稳定。通过平均排放因子的计算,获得小麦秸秆、水稻秸秆、玉米秸秆和大豆秸秆的BC排放因子分别为(0.32±0.05) g?kg~(-1)、(0.31±0.13) g?kg~(-1)、(0.31±0.09) g?kg~(-1)和(0.44±0.01) g?kg~(-1)。在排放因子的基础上,结合我国农作物秸秆露天燃烧量,最终建立了2015年我国省级(不含港澳台地区)典型农作物秸秆燃烧的BC排放清单。  相似文献   
102.
有机负荷对醋糟厌氧消化系统启动的影响   总被引:2,自引:2,他引:0  
戴晓虎  于春晓  李宁  董滨  戴翎翎 《环境科学》2017,38(3):1144-1150
本研究通过醋糟的中温产甲烷潜力测试实验,考察了有机负荷对醋糟厌氧消化反应器启动的影响.并通过对不同有机负荷条件下的甲烷产量、液相组分的对比分析,结合热重、X射线衍射和红外光谱学方法进行差异表征,结果发现:1较低的有机负荷有利于缓解醋糟中有机物水解酸化过程中VFAs的积累和pH的下降,保证产甲烷过程的稳定进行.当接种物与基质VS比为1∶1[即有机负荷(以VS计)为1.78 g·(L·d)~(-1),pH=7.60]时的累积甲烷产量最高,达2 249.7 m L.随着有机负荷的提高,VFAs的累积浓度随之升高,使产甲烷过程受到不同程度的抑制并相继终止,且在接种物与基质VS比为1∶4时[即有机负荷为7.12 g·(L·d)~(-1),pH=5.52]实现了乙酸和乳酸的同步发酵(分别可达到8 000 mg·L~(-1)和2 650 mg·L~(-1)).2醋糟中木质纤维素类物质为短程有序的微晶结构或非晶结构,与富含纤维素类晶体结构物质的玉米秸秆等相比,其VS的降解率更高.醋糟中的木质素、纤维素、半纤维素的降解率随着有机负荷的降低而逐渐升高.  相似文献   
103.
This paper analyses both the processes of adoption and diffusion of the practice of using the chopped residues of pruning as mulch in the olive orchards of the Southern Spanish province of Granada, one of the major olive-producing areas in the world. Many olive groves in the area are located on steep areas where the risk of soil erosion is high. A majority of farmers have adopted no tillage, as an alternative to traditional tillage, combined with either vegetation soil covers or, more frequently, using the chopped pruning residues as mulch. The data used comes from a survey carried out in 2005 to 215 olive farmers. From farmers' responses we estimate a binomial probit model to identify some socio-economic and institutional factors related to the decision to use the practice of mulching on a regular basis. We also estimate several diffusion models that describe the spatial and temporal spread of mulching among farmers. Our results show that mulching using the pruning residues is adopted by 43% of the surveyed farmers. The diffusion process of this practice has been very intense since the middle nineties, and seems to have been based on the interactions among farmers in the area of study rather than in other external source of information. Some of the relevant identified factors that affect the probability of adoption of this practice are farmer's experience, the level of soil degradation in the farm or the continuity of farming by some relative.  相似文献   
104.
冯雪  李剑  滕彦国  王金生 《环境化学》2011,30(9):1604-1610
选用GC/ECD分析吉林市松花江两岸土壤中17种有机氯农药(OCPs)残留情况,并探讨该区土壤中OCPs的残留特征及其可能的健康风险.研究结果表明,17种OCPs均有不同程度的检出,含量较高的组分为六六六(HCHs)、滴滴涕(DDTs)和七氯,总有机氯农药含量为133.15—1263.80 ng.g-1.研究区OCPs...  相似文献   
105.
Abstract

Agricultural residues can be converted to methane-rich gas mixture. Anaerobic biomethane production is an effective process for conversion of a broad variety of agricultural residues to methane to substitute natural gas and medium calorific value gases. Methane generating bacteria (methanogens) and other microbes that help digest dying plants in anaerobic conditions. Agricultural solid residues (ASR) represent a potential energy resource if they can be properly and biologically converted to methane.  相似文献   
106.
针对目前水体中MCPA检测灵敏度不够,缺乏一种无需前处理、可直接上机、简单便捷方法的问题,以超高液相色谱串联质谱仪,建立了一种以电喷雾离子源ESI-为电离模式、MRM为监测模式、可直接进样测定水体中MCPA残留的方法。结果表明,最优方法条件为定量离子对199.0/140.9(m/z),流动相乙腈和水梯度洗脱,色谱柱Acquity UPLC HSS T3。在MCPA质量浓度为0.1~100μg/L范围内线性良好(R2=99.99%),检出限为0.006μg/L,定量限为0.018μg/L,是现有直接进样法的23~83倍,完全满足水体中MCPA的检测要求(<0.1μg/L)。在添加水平为1~100μg/L时,回收率为94.30%~105.60%,相对标准偏差为1.05%~3.61%,具有前处理简单、准确性高、精密度好、灵敏度高等优点。  相似文献   
107.
The amount of sewage sludge generated in Europe is expected to surpass the 10 million tons/year in 2006 as a result of the waste water treatment process according to the Water Policy in European Union. Sewage sludge is what is left behind after water is cleaned in waste treatment plants and is characterized for this high content in nitrogen and phosphorous that could be of great importance in agriculture as fertilizer or soil conditioner. On the other hand, pollutants like metals and organic contaminants are usually removed from water and are accumulated in the sewage sludge, reaching the food chain if their concentrations are not below the safe limits established by the European legislation. The latter issue is of great concern nowadays and in this sense, different works alert against the use of the sewage sludge in agriculture arguing that serious illnesses, even resulting in death as well as adverse environmental impacts are associated to the application of sewage sludge. This work is a continuation of a former comprehensive survey on of priority organic pollutant in sludges for agricultural purposes carried out by our group in Catalonia and this time is focused on the polychlorinated dibenzo-p-dioxins and dibenzofurans (PCDD/F), one of the most toxic group of organic compounds listed in the Work Document on Sludge which is the reference tool in this field in Europe and is also included in the Stockholm Convention. Eighty eight samples were collected from the end of 2003 to April 2006 and the concentrations detected were lower than the 100 ng/kg I-TEQ limit recommended by the European legislation (EC, 2000). Thus, sewage sludges generated in Catalonia do not represent a threat to human health if they are used as fertilizers in agriculture.  相似文献   
108.
农业残留物燃烧温室气体排放清单研究:以江苏省为例   总被引:9,自引:2,他引:7  
刘丽华  蒋静艳  宗良纲 《环境科学》2011,32(5):1242-1248
通过问卷调查确定了江苏省农业残留物在不同时间阶段(1990~1995、1996~2000、2001~2005和2006~2008年)作为生活燃料和田间直接燃烧的比例,利用燃烧炉模拟秸秆燃烧试验确定了6种农业残留物(水稻、小麦、玉米、油菜、棉花和大豆)燃烧产生的CO2、CO、CH4和N2O的排放因子;基于此,结合江苏省不...  相似文献   
109.
为了探讨耐锰菌Fusarium sp.浸出锰离子的作用机制,对比分析了用Fusarium sp.与外加有机酸浸取后电解锰废渣的表征及锰离子浸出率的变化,重点考察了在Fusarium sp.浸取条件下锰离子浸出率、pH以及部分有机酸含量变化的关系.在锰离子的浸出过程中,当加入Fusarium sp.后,浸取后的电解锰废渣...  相似文献   
110.
This paper presents an environmental system study of the production of propionic acid in a biorefinery system based on agricultural by-products. Here, propionic acid is produced by fermentation of glycerol, a by-product from biodiesel production, as carbon source and potato juice, a by-product from starch production, as nitrogen source. Biomass-based propionic acid leads to a greenhouse gas reduction of 60% compared to propionic acid from fossil sources. However, the primary energy input is about twice as high for the biomass-based propionic acid. The choice of input energy and the efficiency of the process, as well as the technology applied, have high impacts on the environmental performance of the biorefinery concept. There is a potential for increased integration both on the input of substrates and the output of end products of the biorefinery system, which will further improve its environmental performance.  相似文献   
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号