Application of a systemic approach to the study of pollution of the Tinto and Odiel rivers (Spain)

The province of Huelva in the SW of Spain presents high environmental contrasts: together with the great abundance of natural spaces, it shows the impacts of historical natural resources exploitation processes. In the Ria of Huelva, the effluents of the chemical industries must be added to the contaminating inputs of the Tinto and Odiel rivers, coming from the acid drainage of the mines located in the Iberian Pyrite Belt. This forced the Environmental Agency (AMA) to elaborate in 1987 an Effluent Remediation Plan in order to negate unacceptable environmental impacts. The application of a grey box systemic analysis to the AMD pollution, undergone by the Tinto and Odiel rivers has allowed to set a conclusive explanation of the sampling results observed for a period of 11 years, thus making available an overall view of the polluting process and, above all, an explanation of its partial aspects.     

Selecting Socio-Economic Metrics for Watershed Management

The selection of social and economic metrics to document baseline conditions and analyze the dynamic relationships between ecosystems and human communities are important decisions for scientists, managers, and watershed citizens. A large variety of social and economic data is available but these have limited use without theoretical frameworks. In this paper, several frameworks for reviewing social-ecosystem relations are offered, namely social sanctions, sense of place, civic structure, and cultural differences. Underlying all of these frameworks are attitudes, beliefs, values, and norms that affect which questions are asked and which indicators are chosen. Much work and significant challenges remain in developing a standard set of spatially based socio-economic metrics for watershed management.     

Extractive Spectrofluorometric Determination of Quinalphos Using Fluorescein in Environmental Samples

A simple, sensitive, convenient and low cost spectrofluorometric technique for determination of quinalphos is described. Quinalphos is decomposed with sodium ethoxide. Resultant sodium diethyl thiophosphate (Na-DETP) is extracted with a cationic fluorescein as ion pair complex into 1-chloro-2-nitrobenzene. The fluorescence of the ion pair, fluorescein-DETP is measured at 530 nm after excitation at 490 nm. This technique is applicable for the determination of quinalphos in water, food grains and vegetable samples up to ng level with Amberlite XAD-4.     

基于颗粒物浓度的沙尘天气分级标准研究

沙尘天气在近年对我国城市空气质量造成明显影响。目前我国沙尘天气分级仍然按照气象标准 ,主要是以水平能见度进行分级。文章参考国外的有关标准 ,通过统计近年来我国沙尘天气过程中的颗粒物浓度 ,结合我国沙尘天气的发生情况和特点 ,提出了基于沙尘浓度的沙尘天气分级标准     

烟尘测试中测孔位置和测点的合理布置

根据作者长期在监测第一线的实践经验及在烟尘采样中所遇到的一些具体问题,着重提出了诸多不规则烟道的烟尘采样方法及注意事项,既有理论依据,可操作性也强。     

乌鲁木齐市汽车尾气排污现状及防治对策探讨

对乌鲁木齐市在用车辆进行了路抽检调查，通过大量数据分析，得出乌鲁木齐市目前汽车尾气排放情况仍令人担忧，治理工作不容忽视。     

天然石材产品放射性水平及其防护管理

简介了我国天然石材产品中放射水平、分类控制使用的现状以及应用天然石材装饰室内所致辐射对人体健康产生的不良影响，提出了加强对天然石材产品使用过程中的监督、监测和管理的建议。     

A ten year summary of concurrent ambient water column and sediment toxicity tests in the Chesapeake Bay watershed: 1990-1999

The goal of this study was to identify the relative toxicity ofambient areas in the Chesapeake Bay watershed by using a suiteof concurrent water column and sediment toxicity tests at seventy-five ambient stations in 20 Chesapeake Bay rivers from1990 through 1999. Spatial and temporal variability was examinedat selected locations throughout the 10 yr study. Inorganicand organic contaminants were evaluated in ambient water andsediment concurrently with water column and sediment tests toassess possible causes of toxicity although absolute causalitycan not be established. Multivariate statistical analysis wasused to develop a multiple endpoint toxicity index (TOX-INDEX) at each station for both water column and sediment toxicity data. Water column tests from the 10 yr testing period showed that49% of the time, some degree of toxicity was reported. The mosttoxic sites based on water column results were located inurbanized areas such as the Anacostia River, Elizabeth River andthe Middle River. Water quality criteria for copper, lead,mercury, nickel and zinc were exceeded at one or more of thesesites. Water column toxicity was also reported in localizedareas of the South and Chester Rivers. Both spatial and temporalvariability was reported from the suite of water column toxicitytests. Some degree of sediment toxicity was reported from 62% of the tests conducted during the ten year period. The ElizabethRiver and Baltimore Harbor stations were reported as the most toxic areas based on sediment results.Sediment toxicity guidelines were exceeded for one or more of thefollowing metals at these two locations: arsenic, cadmium,chromium, copper, lead, nickel and zinc. At the Elizabeth Riverstations nine of sixteen semi-volatile organics and two of sevenpesticides measured exceeded the ER-M values in 1990. Ambientsediment toxicity tests in the Elizabeth River in 1996 showedreduced toxicity. Various semi-volatile organics exceeded the ER-M values at a number of Baltimore Harbor sites; pyrene anddibenzo(a,h)anthracene were particularly high at one of thestations (Northwest Harbor). Localized sediment toxicity was alsoreported in the Chester, James, Magothy, Rappahannock, andPotomac Rivers but the link with contaminants was not determined.Both spatial and temporal variability was less for sedimenttoxicity data when compared with water column toxicity data. Acomparison of water column and sediment toxicity data for thevarious stations over the 10 yr study showed that approximatelyhalf the time agreement occurred (either both suite of testsshowed toxicity or neither suite of tests showed toxicity).     

Simultaneous determination of parathion and p-nitrophenol in vegetable tissues by derivative spectrophotometry

A first derivative spectrophotometric method has been developedfor the determination of parathion and p-nitrophenol in vegetabletissues. Ethanol was used as solvent for extracting the compoundsfrom the tissues and subsequently the samples were evaluated against a vegetable tissue blank, directly by derivative spectrophotometry. The simultaneous determination of these compounds can be carried out using the zero-crossing approach for parathion at 253.0 nm and for p-nitrophenol at 273.1 nm. In the samples each analyte was determined in the presence of one another in the ranges between 4.9 to 3883.5 g g^-1 forparathion and 4.9 to 3285.3 g g^-1 for p-nitrophenol.The detection limits (3) were found to be 1.5 and 1.4 g g^-1 for parathion and p-nitrophenol, respectively. The relative standard deviations were in all instances less than1.8%. The proposed method was applied to the determination ofthe analytes in spiked leafs of corn. The results show a goodrecovery and they are in agreement with those obtained bypolarography.     

低浓度石油类监测与评价的问题探讨

分析表明,当地表水中石油类浓度很低时,受多方面因素影响,其监测结果的准确性和评价结论的可靠性会下降,应选用合适的监测方法,同时要注意引入污染问题。