THE BISCAYNE AQUIFER CONTAMINATION: CLEANUP AND PREVENTION1

ABSTRACT: The Biscayne Aquifer is the sole source of drinking water for approximately three million residents of southeast Florida. Nine hazardous waste sites on the EPA National Priority List overlie this aquifer. Extensive investigation of an 80 square-mile area in metropolitan Miami detected low to moderate levels of toxic contaminants in the ground water, with volatile organic chemicals the most prevalent. The Centers for Disease Control concluded that contamination of the aquifer within the study area poses a serious potential threat to public health. Recommendations for source control and cleanup have been partially carried out. The top few feet of soil at the Miami Drum site have been excavated and relocated; ground water encountered during excavation has been withdrawn and treated, and the Northwest 58th Street Landfill has been closed. Recovery and treatment of ground water from the contaminated area was the recommended cleanup measure and has been approved by EPA and state and local agencies. A preventive action program for the Biscayne Aquifer region was also recommended for implementation by local agencies. This program consists of regulations, waste management practices, construction and treatment guidelines, and public information activities and materials. Implementing this program will help keep the Biscayne Aquifer water drinkable far into the future.     

Deficit Irrigation Management of Maize in the High Plains Aquifer Region: A Review

Irrigated agriculture is a major economic contributor of the High Plains Region and it primarily relies on the High Plains Aquifer as a source of water. Over time, areas of the High Plains Aquifer have experienced drawdowns limiting its ability to supply sufficient water to sustain fully irrigated crop production. This among other reasons, including variable climatic factors and differences in state water policy, has resulted in some areas adopting and practicing deficit irrigation management. Considerable research has been conducted across the High Plains Aquifer region to identify locally appropriate deficit irrigation strategies. This review summarizes and discusses research conducted in Nebraska, Colorado, Kansas, and Texas, as well as highlights areas for future research. Editor's note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Hydrogeochemistry of the Coxilha das Lombas Aquifer, Brazil

The hydrogeochemical characterization of Coxilha das Lombas Aquifer, Brazil, was studied. Chemical characteristics from 23 groundwater samples and meteoric waters data from public registers were used. The ionic speciation and mineral dissolution/precipitation was calculated by EQ3/6 package software. The results showed low total dissolved solids (TDS) values and slightly acidic pH. The concentration of most abundant ions usually followed this trend Cl⁻>HCO₃ ⁺>SO₄ ²⁻>Na⁺. The characteristics of groundwaters and the chemistry similarity with the meteoric waters reflect their short residence time, due to high hydraulic conductivity, and low degree of water/rock interactions, due to sands composed mainly of quartz.     

Experimental study and steady-state simulation of biogeochemical processes in laboratory columns with aquifer material

Packed bed laboratory column experiments were performed to simulate the biogeochemical processes resulting from microbially catalyzed oxidation of organic matter. These included aerobic respiration, denitrification, and Mn(IV), Fe(III) and SO(4) reduction processes. The effects of these reactions on the aqueous- and solid-phase geochemistry of the aquifer material were closely examined. The data were used to model the development of alkalinity and pH along the column. To study the independent development of Fe(III)- and SO(4)-reducing environments, two columns were used. One of the columns (column 1) contained small enough concentrations of SO(4) in the influent to render the reduction of this species unimportant to the geochemical processes in the column.The rate of microbially catalyzed reduction of Mn(IV) changed with time as evidenced by the variations in the initial rate of Mn(II) production at the head of the column. The concentration of Mn in both columns was controlled by the solubility of rhodochrosite (MnCO(3(S))).In the column where significant SO(4) reduction took place (column 2), the concentration of dissolved Fe(II) was controlled by the solubility of FeS. In column 1, where SO(4) reduction was not important, maximum dissolved Fe(II) concentrations were controlled by the solubility of siderite (FeCO(3(S))). Comparison of solid-phase and aqueous-phase data suggests that nearly 20% of the produced Fe(II) precipitates as siderite in column 1. The solid-phase analysis also indicates that during the course of experiment, approximately 20% of the total Fe(III) hydroxides and more than 70% of the amorphous Fe(III) hydroxides were reduced by dissimilatory iron reduction.The most important sink for dissolved S(-II) produced by the enzymatic reduction of SO(4) was its direct reaction with solid-phase Fe(III) hydroxides leading initially to the formation of FeS. Compared to this pathway, precipitation as FeS did not constitute an important sink for S(-II) in column 2. In this column, the total reacted S(-II) estimated from the concentration of dissolved sulfur species was in good agreement with the produced Cr(II)-reducible sulfur in the solid phase. Solid-phase analysis of the sulfur species indicated that up to half of the originally produced FeS may have possibly transformed to FeS(2).     

Tools for Groundwater Protection Planning: An Example from McHenry County, Illinois, USA

/ This paper presents an approach for producing aquifer sensitivity maps from three-dimensional geologic maps, called stack-unit maps. Stack-unit maps depict the succession of geologic materials to a given depth, and aquifer sensitivity maps interpret the successions according totheir ability to transmit potential contaminants. Using McHenry County, Illinois, as a case study, stack-unit maps and an aquifer sensitivity assessment were made to help land-use planners, public health officials, consultants, developers, and the public make informed decisions regarding land use. A map of aquifer sensitivity is important for planning because the county is one of the fastest growing counties in the nation, and highly vulnerable sand and gravel aquifers occur within 6 m of ground surface over 75% of its area. The aquifer sensitivity map can provide guidance to regulators seeking optimal protection of groundwater resources where these resources are particularly vulnerable. In addition, the map can be used to help officials direct waste-disposal and industrial facilities and other sensitive land-use practices to areas where the least damage is likely to occur, thereby reducing potential future liabilities. KEY WORDS: Geologic mapping; Groundwater; Aquifers; Aquifer sensitivity; Land-use planning     

Recent Ogallala Aquifer Region Drought Conditions as Observed by Terrestrial Water Storage Anomalies from GRACE

Recent severe drought events have occurred over the Ogallala Aquifer region (OAR) during the period 2011–2015, creating significant impacts on water resources and their use in regional environmental and economic systems. The changes in terrestrial water storage (TWS), as indicated by the Gravity Recovery and Climate Experiment (GRACE), reveals a detailed picture of the temporal and spatial evolution of drought events. The observations by GRACE indicate the worst drought conditions occurred in September 2012, with an average TWS deficit of ~8 cm in the northern OAR and ~11 cm in the southern OAR, consistent with precipitation data from the Global Precipitation Climatology Project. Comparing changes in TWS with precipitation shows the TWS changes can be predominantly attributable to variations in precipitation. Power spectrum and squared wavelet coherence analysis indicate a significant correlation between TWS change and the El Nino‐Southern Oscillation, and the influence of equatorial Pacific sea surface temperatures on TWS change is much stronger in the southern OAR than the northern OAR. The results of this study illustrate the value of GRACE in not just the diagnosis of significant drought events, but also in possibly improving the predictive power of remote signals that are impacted by nonregional climatic events (El Nino), ultimately leading to improved water resource management applications on a regional scale. Editor’s note : This paper is part of the featured series on Optimizing Ogallala Aquifer Water Use to Sustain Food Systems. See the February 2019 issue for the introduction and background to the series.     

Fate of bulk and trace organics during a simulated aquifer recharge and recovery (ARR)-ozone hybrid process

The attenuation of bulk organic matter and trace organic contaminants (TOrCs) was evaluated for various aquifer recharge and recovery (ARR)-ozone (O₃) hybrid treatment process combinations using soil-batch reactor and bench-scale ozonation experiments as a proof of concept prior to pilot and/or field studies. In water reclamation and especially potable reuse, refractory bulk organic matter and TOrCs are of potential health concern in recycled waters. In this study, the role of biotransformation of bulk organic matter and TOrCs was investigated considering different simulated treatment combinations, including soil passage (ARR) alone, ARR after ozonation (O₃-ARR), and ARR prior to ozonation (ARR-O₃). During oxic (aerobic) ARR simulations, soluble microbial-like substances (e.g., higher molecular weight polysaccharides and proteins) were easily removed while (lower molecular weight) humic substances and aromatic organic matter were not efficiently removed. During ARR-ozone treatment simulations, removals of bulk organic matter and TOrCs were rapid and effective compared to ARR alone. A higher reduction of effluent-derived organic matter, including aromatic organic matter and humic substances, was observed in the ARR-O₃ hybrid followed by the O₃-ARR hybrid. An enhanced attenuation of recalcitrant TOrCs was observed while increasing the ozone dose slightly (O₃: DOC = 1). TOrC removal efficiency also increased during the post-ozone treatment combination (i.e., ARR-O₃). In addition, the carcinogenic wastewater disinfection byproduct N-nitrosodimethylamine (NDMA) was eliminated below the method reporting limit (<5 ng L⁻¹) both during ARR treatment alone and the ARR-ozone hybrid.     

Parameters that control the cleanup of fractured permeable aquifers

This study develops a modeling approach for simulating and evaluating entrapped light nonaqueous-phase liquid (light NAPL-LNAPL) dissolution and transport of the solute in a fractured permeable aquifer (FPA). The term FPA refers to an aquifer made of porous blocks of high permeability that embed fractures. The fracture network is part of the domain characterized by high permeability and negligible storage. Previous studies show that sandstone aquifers often represent FPAs. The basic model developed in this study is a two-dimensional (2-D) model of permeable blocks that embed oblique equidistant fractures with constant aperture and orientation. According to this model, two major parameters govern NAPL dissolution and transport of the solute. These parameters are: 1) the dimensionless interphase mass transfer coefficient, K(f0), and 2) the mobility number, N(M0). These parameters represent measures of heterogeneity affecting flow, NAPL dissolution, and transport of the solute in the domain. The parameter K(f0) refers to the rate at which organic mass is transferred from the NAPL into the water phase. The parameter N(M0) represents the ratio of flow through the porous blocks to flow through the fracture network in regions free of entrapped NAPL. It also provides a measure of groundwater flow bypassing regions contaminated by entrapped NAPL. In regions contaminated by entrapped NAPL our simulations have often indicated very low permeability of the porous blocks, enabling a significant increase of the fracture flow at the expense of the permeable block flow. Two types of constitutive relationships also affect the rate of FPA cleanup: 1) the relationship between the saturation of the entrapped NAPL and the permeability of the porous blocks, and 2) the relationships representing effects of the entrapped NAPL saturation and the permeable block flow velocity on rates of interphase mass transfer. This study provides basic tools for evaluating the characteristics of pump-and-treat cleanup of FPAs by referring to sets of parameters and constitutive relationships typical of FPAs. The numerical simulations carried out in this study show that at high initial saturation of the entrapped NAPL, during initial stages of the FPA cleanup the contaminant concentration increases, but later it decreases. This phenomenon originates from significant groundwater bypassing the NAPL entrapped in the permeable blocks via the fracture network.     

Discharge From the Edwards Aquifer Through the Leona River Floodplain,Uvalde, Texas1

Abstract: Analysis of results from an electrical resistivity survey, a magnetic survey, and an aquifer test performed on the Leona River floodplain in south‐central Texas indicates that ground‐water discharge from the Edwards Aquifer through the Leona River floodplain may be as great as 91.7 Mm³/year. When combined with an estimate of 8.8 Mm³/year for surface flow in the Leona River, as much as 100.5 Mm³/year could be discharged from the Edwards Aquifer through the Leona River floodplain. A value of 11,200 acre‐ft/year (13.82 Mm³/year) has been used as the calibration target in existing ground‐water models for total discharge from Leona Springs and the Leona River. Including ground water or underflow discharge would significantly increase the calibration target in future models. This refinement would improve the conceptualization of ground‐water flow in the western portion of the San Antonio segment of the Edwards Aquifer and would thereby allow for more accurate assessment and management of the ground‐water resources provided by the Edwards Aquifer.     

A GIS-based DRASTIC vulnerability and net recharge reassessment in an aquifer of a semi-arid region (Metline-Ras Jebel-Raf Raf aquifer, Northern Tunisia)

This paper aims to elaborate new generic DRASTIC aquifer vulnerability maps of the coastal aquifer of Metline-Ras Jebel-Raf Raf (Northeast of Tunisia) using the GIS technique, making the data analyses easier to handle and providing better capabilities of dealing with large spatial data. A similar study was carried out in 1999 in the same aquifer using a method based on the soil water balance equation to determine the net recharge parameter. Unfortunately, the lack of data in the study area made the results unsatisfactory. By applying the Williams and Kissel equation and the Rao relationship, we intend to demonstrate that we could correctly evaluate the net recharge parameter. Moreover, new data related to the aquifer hydraulic conductivity, the soil cover and the vadose zone lithology have become available, and allowed us to elaborate suitable DRASTIC maps.