基于重要性分析的甲烷/乙烯混合燃烧框架机理构筑

建立了基于重要性分析的详细化学机理分析平台,利用耦合组分化学存活时间和敏感性系数的重要性参数,确定详细机理中的准稳态组分,通过移除这些组分及其相关反应,得到了计算精度较高的框架机理。针对目前燃烧学界较为关注的混合燃烧问题,以甲烷、乙烯这两种典型低碳碳氢燃料为研究对象,对其详细化学反应机理进行了分析,利用重要性分析法构筑框架机理,并对甲烷/空气和甲烷/乙烯/空气预混火焰进行了数值计算。与详细机理相比,框架机理所涉及的组分数与基元反应数都得到了大幅度的降低,计算时间明显减少,但对火焰温度及反应物、生成物、中间组分浓度的预测与采用详细机理得到的结果吻合良好,证明了重要性分析法的有效性与可靠性。     

浅谈企业重大危险源的识别与控制

提高安全意识、保障安全发展已成为我国企业推动现代化管理和社会进步的重要标识。随着科技的进步和体制改革的深入,我国企业安全管理工作的系统和模式正在发生根本性变化。现代化的隐患监控系统溶于社会化的工业安全卫生监控体系之中。从方法上来说,由危险源辨识进阶到隐患辨识,必须通过普查、评价、认证的方式完成分级评估．确定隐患监控的实施基础、作为隐患监控的技术载体则越来越依托信息网络的发展。因此,企业开展对重大危险源及事故隐患的辨识、评价、监控、预警、应急预案的理论和技术研究,必然加快企业持续推动科学发展、安全发展的进程。     

石化企业的环境污染事故应急预案分析与建议

从环境污染角度分析了"吉化爆炸"、"大连原油泄漏"和"兰化系列爆炸"三个典型石化企业安全生产事故案例,论证了环境污染控制在应急预案中的重要地位和完善的应急预案对于避免环境污染事故或最大程度减少事故损失的重要作用。在此基础上,分析了目前石化企业的环境污染应急预案中存在的普遍性问题,并以天津某石化企业的环境污染事故应急预案为例,从应急能力、应急行动、应急培训、预案演练、预案修订和环境污染预防等方面提出了完善建议,增强其针对性、可操作性和科学合理性,以期在应急救援中发挥更好的功效,避免安全生产事故次生环境污染事故。     

危险化学品生产企业危险源辨识方法研究

随着经济社会的发展和化工行业投资规模快速增长,社会对危化品的关注日益增长,这就加大了企业安全生产压力。危化品生产企业往往存在着诸多危险源,其中化学性危害因素是在危险源辨识过程中需考虑的重点要素。为了正确辨识危险化学品企业的危险源,保障安全运营,本文梳理了危险源的几种分类,包括物理性危害因素、化学性危害因素、生物性危害因素、心理生理性危害因素、行为性危害因素等,并在此基础上重点研究了工作危害分析、安全检查表、危险与可操作性分析等危险源辨识方法。最后以两个危化公司为样本,介绍了危险源辨识方法的具体内容和操作流程,为企业选用正确方法,科学辨识危险源,顺利排查隐患提供依据。     

建筑企业员工职业病危害认知影响因素的调查分析

随着建筑行业的持续快速发展,建筑企业作业场所中的职业病危害呈现出高发性、复杂性和持续性等特点.通过针对建筑企业员工的实际状况设计调查问卷获取第一手资料,并运用SPSS17.0统计软件建立相关分析、回归分析等模型进行数据分析,可以得知建筑企业作业场所员工遭受职业病危害的可能性与对安全知识的了解程度、从业时间、性别及文化背景这四个因素的线性相关性.通过对建筑企业作业人员职业病危害的调查与分析,辨识出影响职业病危害的人为因素,提出相关的建议措施以改善建筑企业作业场所职业病危害严重的局面,提高建筑企业员工自我保护意识,增加其职业病危害防护知识,减少职业病危害事故的发生.     

浅议企业安全文化建设与安全标准化建设的关系

目前由于国内各企业正在开展企业安全标准化建设工作,很多企业对安全标准化建设与企业安全文化建设之间的关系感到困惑。本文首先介绍了企业安全文化的层次和各层次间的关系以及安全标准化建设的相关内容,然后分析了企业安全文化建设与安全标准化建设之间的关系,最后得出安全标准化建设是企业安全文化的重要组成这一结论。安全标准化建设是建设安全文化的重要措施之一,企业可以通过安全标准化的建设来完善其在安全文化建设中的不足。本文能为企业进行安全标准化建设和安全文化建设的实施提供参考依据。     

System dynamics research of non-adaptive evacuation psychology in toxic gas leakage emergencies of chemical park

Chemical industry park plays an important role in optimizing the allocation of resources, but an emergency may make a great deal of personnel casualty and property loss. Many casualties are not the result of accidents but are caused by extreme behavior because of the non-adaptive psychology of the evacuees. Panic is one of the non-adaptive psychological behaviors during an evacuation, which is influenced by a variety of factors. Based on the consideration of the disaster environment and the evolution of crowd emotion, a system dynamics model of panic spread is established by using Anylogic software, and simulation experiments are carried out for different disaster severity, visibility, and groups. The results show that the number of people with severe panic increase when visibility decreases or disaster diffuses. Besides, the appropriate proportion of groups can effectively reduce the cooling time of crowd and ease the fears. However, continue to increase the number of groups has no significant effect on the panic control. This work can provide some reasonable guidance for regional emergency evacuation in chemical park.     

Justice for Bhopal! And No More Bhopals! Three decades of national and international campaigning

Dissatisfaction with the responses of the responsible corporation, Union Carbide, and the Indian government to Bhopal resulted in a campaign by national and international NGOs (non-governmental organisations) over the past three decades. While initially the Indian and international campaigns were separate, over time greater international cooperation took place. In the immediate aftermath of the disaster local NGOs prioritised health, justice and rehabilitation issues, while international NGOs used Bhopal to question chemical industry process and environmental safety in their own countries, as well as internationally. Indian NGOs called on international NGO resources to gain legitimacy for their campaign, to use NGOs as proxies and to extend the geographical scope of the campaign, while international NGOs used Bhopal as an example to advance NGOs analyses and policies. Over the period of the campaign, Indian NGOs became more sophisticated in their campaigning. The international campaign has increasingly become an online campaign, involved in an image or reputational war with Dow Chemical, which took over Union Carbide, while the original campaign issues of justice and reparations over the process safety disaster were joined by similar issues related to environmental safety of abandoned toxic waste.     

Uncertainties in QRA: Analysis of losses of containment from piping and implications on risk prevention and mitigation

Quantitative Risk Assessment (QRA) is commonly used in the chemical industry to support decision-making. Common practices are based on standard methods, such as fault tree, event tree, etc.; in this frame, risk is a function of frequency of events (probability) and associated consequences (negative outcomes), but relevant uncertainties often are not properly taken into account in the derived results. This paper presents the application of an extended risk analysis of loss of containments for a case-study with the following aims: firstly, the uncertainties related to the results of the analysis, which derive from assumption in the application of the standard models, are qualitatively assessed; secondly the application allows evaluating the impact of the uncertainties on the trustworthiness of the results and, finally, commenting about their use in the risk prevention and mitigation.     

Survey-based analysis of evacuation preparation behaviors in a chemical leakage accident: A case study

Public evacuation preparation exerts an important impact on overall evacuation efficiency during regional evacuations. Early warnings often delay the occurrence of chemical accidents. Studying the characteristics of public evacuation preparation in such accidents will help develop better evacuation strategies considering the actual public response. In this work, the characteristics and factors influencing public evacuation preparation behaviors were analyzed by examining an evacuation case in China. The results indicated that the probability distribution of public's evacuation preparation time during a regional evacuation conforms to a Weibull distribution regardless of whether or not evacuation warnings were received. An estimation model of the traffic flow loading rate in a regional evacuation was then proposed on the basis of this finding. The results of this research can provide a reliable reference for evacuation modeling or logistics optimization for future incidents.