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991.
992.
993.
Siedlecka EM Stepnowski P 《Environmental science and pollution research international》2009,16(4):453-458
Background, aim, and scope Ionic liquids are regarded as essentially “green” chemicals because of their insignificant vapor pressure and, hence, are
a good alternative to the emissions of toxic conventional volatile solvents. Not only because of their attractive industrial
applications, but also due to their very high stability, ionic liquids could soon become persistent contaminants of technological
wastewaters and, moreover, break through into natural waters following classical treatment systems. The removal of harmful
organic pollutants has forced the development of new methodologies known as advanced oxidation processes (AOPs). Among them,
the Fenton and Fenton-like reactions are usually modified by the use of a higher hydrogen peroxide concentration and through
different catalysts. The aim of this study was to assess the effect of hydrogen peroxide concentration on degradation rates
in a Fenton-like system of alkylimidazolium ionic liquids with alkyl chains of varying length and 3-methyl-N-butylpyridinium chloride.
Materials and methods The ionic liquids were oxidized in dilute aqueous solution in the presence of two different concentrations of hydrogen peroxide.
All reactions were performed in the dark to prevent photoreduction of Fe(III). The concentrations of ionic liquids during
the process were monitored with high-performance liquid chromatography. Preliminary degradation pathways were studied with
the aid of 1H NMR.
Results Degradation of ionic liquids in this system was quite effective. Increasing the H2O2 concentration from 100 to 400 mM improved ionic liquid degradation from 57–84% to 87–100% after 60 min reaction time. Resistance
to degradation was weaker, the shorter the alkyl chain.
Discussion The compound omimCl was more resistant to oxidation then other compounds, which suggests that the oxidation rates of imidazolium
ionic liquids by OH· are structure-dependent and are correlated with the n-alkyl chain length substituted at the N-1-position. The level of degradation was dependent on the type of head group. Replacing
the imidazolium head group with pyridinium increased resistance to degradation. Nonetheless, lengthening the alkyl chain from
four to eight carbons lowered the rate of ionic liquid degradation to a greater extent than changing the head group from imidazolium
to pyridinium. 1H-NMR spectra show, in the first stage of degradation, that it is likely that radical attack is nonspecific,
with any one of the carbon atoms in the ring and the n-alkyl chain being susceptible to attack.
Conclusions The proposed method has proven to be an efficient and reliable method for the degradation of imidazolium ionic liquids by
a Fenton-like reagent deteriorated with lengthening n-alkyl substituents and by replacing the imidazolium head group with pyridinium. The enhanced resistance of 1-butyl-3-methylpyridinium
chloride when the resistance of imidazolium ionic liquids decreases with increasing H2O2 concentration is probably indicative of a change in the degradation mechanism in a vigorous Fenton-like system. H-NMR spectra
showed, in the first stage of degradation, that radical attack is nonspecific, with any one of the carbon atoms in the ring
and the n-alkyl chain being susceptible to attack.
Recommendations and perspectives Since ionic liquids are now one of the most promising alternative chemicals of the future, the degradation and waste management
studies should be integrated into a general development research of these chemicals. In the case of imidazolium and pyridinium
ionic liquids that are known to be resistant to bio- or thermal degradation, studies in the field of AOPs should assist the
future structural design as well as tailor the technological process of these chemicals 相似文献
994.
Modelling land cover change from existing land cover maps is a vital requirement for anyone wishing to understand how the landscape may change in the future. In order to test any land cover change model, existing data must be used. However, often it is not known which data should be applied to the problem, or whether relationships exist within and between complex datasets. Here we have developed and tested a model that applied evolutionary processes to Bayesian networks. The model was developed and tested on a dataset containing land cover information and environmental data, in order to show that decisions about which datasets should be used could be made automatically. Bayesian networks are amenable to evolutionary methods as they can be easily described using a binary string to which crossover and mutation operations can be applied. The method, developed to allow comparison with standard Bayesian network development software, was proved capable of carrying out a rapid and effective search of the space of possible networks in order to find an optimal or near-optimal solution for the selection of datasets that have causal links with one another. Comparison of land cover mapping in the North-East of Scotland was made with a commercial Bayesian software package, with the evolutionary method being shown to provide greater flexibility in its ability to adapt to incorporate/utilise available evidence/knowledge and develop effective and accurate network structures, at the cost of requiring additional computer programming skills. The dataset used to develop the models included GIS-based data taken from the Land Cover for Scotland 1988 (LCS88), Land Capability for Forestry (LCF), Land Capability for Agriculture (LCA), the soil map of Scotland and additional climatic variables. 相似文献
995.
Evaluation of a classification method for biodegradable solid wastes using anaerobic degradation parameters 总被引:1,自引:0,他引:1
Wei Zheng Khamphe Phoungthong Fan Lü Li-Ming Shao Pin-Jing He 《Waste management (New York, N.Y.)》2013,33(12):2632-2640
We studied the biochemical and anaerobic degradation characteristics of 29 types of materials to evaluate the effects of a physical composition classification method for degradable solid waste on the computation of anaerobic degradation parameters, including the methane yield potential (L0), anaerobic decay rate (k), and carbon sequestration factor (CSF). Biochemical methane potential tests were conducted to determine the anaerobic degradation parameters of each material. The results indicated that the anaerobic degradation parameters of nut waste were quite different from those of other food waste and nut waste was classified separately. Paper was subdivided into two categories according to its lignin content: degradable paper with lignin content of <0.05 g g VS?1, and refractory paper with lignin content >0.15 g g VS?1. The L0, k, and CSF parameters of leaves, a type of garden waste, were similar to those of grass. This classification method for degradable solid waste may provide a theoretical basis that facilitates the more accurate calculation of anaerobic degradation parameters. 相似文献
996.
厌氧序批式反应器内挥发性脂肪酸积累特性研究 总被引:1,自引:0,他引:1
小试规模的厌氧序批式反应器(ASBR),通过人工配水,研究了启动3个月时间以及一个运行周期内反应器内挥发性脂肪酸(VFA)的积累情况,并通过分析期间产甲烷活性的变化说明了控制VFA积累的重要性。经过近120 d的运行,乙酸和丙酸的最大比产甲烷活性分别提高了1.8和2.2倍,说明反应器的启动过程即是微生物群落的优化和选择的过程,ASBR的抗冲击的能力较强说明随启动的进行和种群的优化,活性污泥凝聚性能增强,对VFA的降解能力增强。 相似文献
997.
本文介绍了可靠性标准体系与参数体系,可靠性的分析与设计方法,可靠性试验的发展趋势,指出可靠性管理是产品可靠性工作的核心,以及提高电子设备可靠性的发展策略。 相似文献
998.
999.
Li R. Gao Dan. Xia Hai Z. Tian Hai J. Zhang Li D. Liu Yi W. Wang 《Journal of environmental science and health. Part. B》2013,48(5):322-330
Organochlorine pesticides (OCPs) were analyzed in 26 surface sediment samples from the Liaohe River basin, and the distributions of and potential environmental risks posed by OCPs in the basin were evaluated. Eighteen OCPs listed in the Stockholm Convention were determined using isotope-dilution gas chromatography–high resolution mass spectrometry. This is the first study of hexachlorobenzene (HCB) in the Liaohe River basin sediments. The total OCP concentrations were 0.39–68.06 ng g?1 dry weight. The total α-, β-, γ-, and δ-hexachlorocyclohexane (HCH), the total dichlorodiphenyltrichloroethane (DDT – p,p′-dichlorodiphenyldichloroethane (DDD), p,p′-dichlorodiphenyldichloroethylene (DDE), o,p'-DDT, and p,p′-DDT), and the HCB concentrations in the sediment samples were 0.1–28.48 ng g?1 (mean 4.01 ng g?1), 0.08–6.52 ng g?1 (mean 3.07 ng g?1), and 0.18–24.8 ng g?1 (mean 4.38 ng g?1), respectively. The HCB concentrations were higher than the concentrations of the other OCPs, and the HCHs and HCB together were the dominant OCPs. β-HCH was the most abundant HCH isomer. The concentrations of DDTs and other OCPs were relatively low, and the (DDE+DDD)/DDT ratios (>0.5) and DDD/DDE ratios (<1) indicated that no recent DDT inputs had occurred in the Liaohe River system. The main sources of HCHs were probably the historical production and agricultural use of HCH in the study area. The DDT and HCH concentrations were generally below or similar to the concentrations that have been found in other parts of the world. An ecotoxicological evaluation indicated that HCHs in surface sediments pose slight risks to human and ecological health in the Liaohe River basin. 相似文献
1000.
超细粉煤灰基成型吸附剂的动态吸附实验 总被引:2,自引:1,他引:1
以粉煤灰为原料制备成型吸附剂,对水溶液中亚甲基蓝和Cr6+进行动态吸附研究,绘制穿透曲线,利用Origin软件对实验数据分析处理,得出穿透曲线的通式Ct=A1-A2〖〗1+(t/t0)p+A1。结果表明,初始浓度C0=25 mg/L,填料高度不同时,达到穿透点的时间随填料高度的增加而增加;填料高度h=200 mm,初始浓度不同时,达到穿透点的时间随初始浓度的增加而减小;该吸附剂对有机染料和重金属离子均有较好的吸附性能;穿透曲线通式的回归线性相关系数表明,该通式可很好地反映超细粉煤灰成型吸附剂的动态吸附过程。 相似文献