Congener profile, occurrence and estimated dietary intake of dioxins and dioxin-like PCBs in foods marketed in the Region of Valencia (Spain)

During 2006-2008, a monitoring program was conducted on 29 target compounds, including PCDD/Fs and dl-PCBs, comprising 150 randomly collected individual food samples marketed in the Region of Valencia, Spain, grouped into 8 categories (vegetables, cereals, fats and oils, eggs, milk and dairy products, fish products, meat and meat products and fish oil). For PCDD/Fs, the highest frequency of detection corresponds to 1,2,3,4,6,7,8-HpCDD, OCDD, 2,3,4,7,8-PeCDF; and PCBs 118, 105 and 156 were the more frequent dl-PCBs. The food groups presenting higher contamination, expressed as toxic equivalents (WHO-TEQs), were fish oil (6.38 pg WHO-TEQ g⁻¹ fat), fish (1.21 pg WHO-TEQ g⁻¹ w.w.) and milk and dairy products (0.90 pg WHO-TEQ g⁻¹ fat). Of all analysed samples, only two fish oils presented levels higher than the EU limits for total WHO-TEQ. The average PCDD/Fs and dl-PCBs intakes were estimated as 2.86 pg WHO-TEQ kg⁻¹ b.w. d⁻¹ and 4.58 pg WHO-TEQ kg⁻¹ b.w. d⁻¹, for adults and children, respectively, using the deterministic method for chronic exposure. The main contributors to total intake for adults were fish (59%), milk and dairy products (19%), and fat and oils (9%). The average daily intake for adults (2.86 pg WHO-TEQ kg⁻¹ b.w. d⁻¹) is within range of TDI recommended by the WHO (1-4 pg WHO-TEQ kg⁻¹ b.w. d⁻¹), and slightly above the TWI and PTMI adopted by SCF and JECFA respectively.     

日本第四次修订《食品、农业和农村基本法》及启示

日本政府2015年推出了《食品、农业和农村基本法》的第四次修订,以保证粮食供应和食品安全;推动集约化农业经营,保障农业收入稳定;推动农产品出口和农业技术创新;改善补贴政策,稳定农村人口作为下一阶段日本兴农政策的核心内容。我国农业发展面临许多与日本相似的问题,如农业经营规模小、效率低,务农收入低、人口显著减少等。在我国城镇化和农村劳动力老年化加速的背景下,分析和借鉴日本最新的兴农政策,提出对我国农业政策的若干启示:1以我国近期最新颁布的《食品安全法》和农药残留、化肥实施等国家标准的落实、健全为法制保障基础,推进农业标准化生产和规范化经营管理、建立食品生产全程可追溯机制、加强省县乡三级农产品和食品监测检验能力建设,以尽快提升我国食品安全水平;以培育需求和引导兴趣、技术支持、市场协助建设为手段,激励农户和消费者自主投入生态农业发展。2重点完善国家层面的发展战略统筹和政治、经贸、投资谈判支持,依靠政府的强力支持推动已起步的"一带一路"食品与农业投资发展势头,以壮大我国农产食品出口和农业海外发展。3近期以加强土地流转监管法律政策和财政金融配套扶持政策的建设为主,使支持力度集中于土地实际经营者,以有效提升新型规模化农业经营主体的数量和质量。4将农业补贴由集中于农业生产补贴向兼顾农户收入保障和生态保护、农业发展转移,将农户收入保障形式由财政补贴向保险保障转变,以求农业补贴和保险更高效、长久地兼顾农户收入保障和支持引领农业发展。     

HPLC determination of chlorate metabolism in bovine ruminal fluid

Salmonella and Escherichia coli are two bacteria that are important causes of human and animal disease worldwide. Chlorate is converted in the cell to chlorite, which is lethal to these bacteria. An HPLC procedure was developed for the rapid analysis of chlorate (ClO₃ ^?), nitrate (NO₃ ^?), and nitrite (NO₂ ^?) ions in bovine ruminal fluid samples. Standard curves for chlorite, nitrite, nitrate, and chlorate were well defined linear curves with R² values of 0.99846, 0.99106, 0.99854, and 0.99138, respectively. Concentrations of chlorite could not be accurately determined in bovine ruminal fluid because chlorite reacts with or binds a component(s) or is reduced to chloride in bovine ruminal fluid resulting in low chlorite measurements. A standard curve ranging from 25 to 150 ppm ClO₃ ^? ion was used to measure chlorate fortified into ruminal fluid. The concentration of chlorate was more rapidly lowered (P < 0.01) under anaerobic compared to aerobic incubation conditions. Chlorate alone or chlorate supplemented with the reductants sodium lactate or glycerol were bactericidal in anaerobic incubations. In anaerobic culture, the addition of sodium formate to chlorate-fortified ruminal fluid appeared to decrease chlorate concentrations; however, formate also appeared to moderate the bactericidal effect of chlorate against E. coli. Addition of the reductants, glycerol or lactate, to chlorate-fortified ruminal fluid did not increase the killing of E. coli at 24 h, but may be useful when the reducing equivalents are limiting as in waste holding reservoirs or composting systems required for intense animal production.     

Sustainability, substance-flow management, and time, Part II: Temporal impact assessment (TIA) for substance-flow management

High-quality food and general good health are fundamental needs that have to be satisfied if society is to attain a high standard of living. Accordingly, a great deal of effort is expended in order to guarantee a high quality of food and ensure healthy living conditions. Among other things, these efforts entail massive substance flows. Significant substance flows are connected with the production and consumption of food and can be regarded from an economic, social, or environmental point of view. Substance flows are a part of both nature and the anthroposphere. This study demonstrates that food production at present is not linked to societal issues of production and sustainability; rather, it shows that a systematic approach and an analysis of issues and measures to be taken are required. This interconnectedness can be described as a timescape, in analogy to a landscape. For proper orientation in a landscape, a map is helpful, especially in combination with a compass. In the same way, we need a temporal orientation. Time scales serve as a compass to give orientation. A complete temporal analysis that includes all relevant temporalities provides the information that is encoded in a map. What has to be learned and exercised is the reading of such temporal maps. One method of doing this is temporal impact analysis (TIA). Temporal impact analysis brings issues that are not normally focused on into the foreground. It allows a better understanding of the implications of certain substance flows and the measures necessary for their management, and it provides an opportunity to develop a more sustainable management of substance flows.     

Assessment of human exposure to benzene through foods from the Belgian market

Benzene is a volatile organic compound known to be carcinogenic to humans (Group 1) and may be present in food. In the present study, 455 food samples from the Belgian market were analyzed for benzene contents and some possible sources of its occurrence in the foodstuffs were evaluated. Benzene was found above the level of detection in 58% of analyzed samples with the highest contents found in processed foods such as smoked and canned fish, and foods which contained these as ingredients (up to 76.21 μg kg⁻¹). Unprocessed foods such as raw meat, fish, and eggs contained much lower concentrations of benzene. Using the benzene concentrations in food, a quantitative dietary exposure assessment of benzene intake was conducted on a national representative sample of the Belgian population over 15 years of age. The mean benzene intake for all foods was 0.020 μg kg bw d⁻¹ according to a probabilistic analysis. These values are below the minimum risk level for oral chronic exposure to benzene (0.5 μg kg bw d⁻¹).     

Characteristics of chlorofluorocarbons (CFCs) emitted from a municipal waste treatment facility

The emission concentrations of several chlorofluorocarbons (CFCs) were measured from a municipal waste treatment facility (located in Seoul, Republic of Korea) to investigate the emission characteristics of CFCs in the urban environment. To this end, a total of five CFCs (CFC-10, CFC-11, CFC-20, CFC-30, and CFC-113) were analyzed by the thermal desorption-gas chromatography-mass spectrometry (TD-GC-MS) method. The results of this study indicate that the formation of CFC-11 (8.21 ± 1.68 ppb in spring) and CFC-20 (3.92 ± 3.93 ppb in spring) proceeded very actively within the facility. Moreover, CFC-113 was also found in relatively high concentrations (3.34 ± 1.31 ppb in spring) in the treatment facility. Unlike other CFCs, CFC-10 was observed mainly at ambient (and reference) locations and one point inside the treatment facility. In conclusion, emissions of some important CFCs are a prominent process, as they were measured either frequently or abundantly both in winter and spring. It is further indicated that certain CFCs (like CFC-11 and CFC-30) are subject to highly significant seasonal variations.     

Balancing Water Resources Development and Environmental Sustainability in Africa: A Review of Recent Research Findings and Applications

Sustainable development in Africa is dependent on increasing use of the continent’s water resources without significantly degrading ecosystem services that are also fundamental to human wellbeing. This is particularly challenging in Africa because of high spatial and temporal variability in the availability of water resources and limited amounts of total water availability across expansive semi-arid portions of the continent. The challenge is compounded by ambitious targets for increased water use and a rush of international funding to finance development activities. Balancing development with environmental sustainability requires (i) understanding the boundary conditions imposed by the continent’s climate and hydrology today and into the future, (ii) estimating the magnitude and spatial distribution of water use needed to meet development goals, and (iii) understanding the environmental water requirements of affected ecosystems, their current status and potential consequences of increased water use. This article reviews recent advancements in each of these topics and highlights innovative approaches and tools available to support sustainable development. While much remains to be learned, scientific understanding and technology should not be viewed as impediments to sustainable development on the continent.     

Energy efficiency and conservation for individual Americans

Americans make up only 4% of the world population, yet currently consume 25% of the world’s fossil fuels. The U.S. imports 63% of its oil and it is predicted that by 2020 the U.S. will be importing 95% of its oil resources. Over the past century, ample and affordable supplies of fossil fuels have powered the growth and prosperity of the economies of the US and other countries. Within this century, world oil supplies will decline while demand is projected to continue to increase, suggesting that we will have to transition to different fuels or become much more energy efficient or both. Looking ahead to the near decades, estimates are that consumers will have to reduce their energy use by at least 50%. This reduction will be necessary in large part due the decline in the availability of conventional oil and gas, but also because the U.S. population will continue to grow in number. Although government action is important, individuals too often discount their ability to make significant contributions to solving such major problems. This investigation identifies how informed and concerned individuals can collectively conserve fossil energy. Readers should send their comments on this paper to: BhaskarNath@aol.com within 3 months of publication of this issue. An erratum to this article can be found at     

Health and Environmental Implications of Rural Female Entrepreneurship Practices in Osun State Nigeria

In rural Nigeria, food processing is mostly engaged in by women and children. Most of these processes are done using outdated technologies that make use of traditional woodstoves. This article presents the health and environmental implications of the rural female entrepreneurs involved in food processing and proffer means of bettering the lot of these women to handle these hazards. A partially structured questionnaire and focus group discussion was used to capture data from respondents. The study revealed that about 73 % of women involved in direct production of garri and palm oil processing could be at risk of early death or disability-adjusted life years from the mentioned diseases. The article concludes that the rural female entrepreneur needs to be better positioned to handle these hazards, for her health, that of her children, as well as for the environment.     

Hydrothermal carbonization of food waste and associated packaging materials for energy source generation

Hydrothermal carbonization (HTC) is a thermal conversion technique that converts food wastes and associated packaging materials to a valuable, energy-rich resource. Food waste collected from local restaurants was carbonized over time at different temperatures (225, 250 and 275 °C) and solids concentrations to determine how process conditions influence carbonization product properties and composition. Experiments were also conducted to determine the influence of packaging material on food waste carbonization. Results indicate the majority of initial carbon remains integrated within the solid-phase at the solids concentrations and reaction temperatures evaluated. Initial solids concentration influences carbon distribution because of increased compound solubilization, while changes in reaction temperature imparted little change on carbon distribution. The presence of packaging materials significantly influences the energy content of the recovered solids. As the proportion of packaging materials increase, the energy content of recovered solids decreases because of the low energetic retention associated with the packaging materials. HTC results in net positive energy balances at all conditions, except at a 5% (dry wt.) solids concentration. Carbonization of food waste and associated packaging materials also results in net positive balances, but energy needs for solids post-processing are significant. Advantages associated with carbonization are not fully realized when only evaluating process energetics. A more detailed life cycle assessment is needed for a more complete comparison of processes.